煤矿酸性矿井水主动式生物修复中铁的行为与归宿

酸性条件下Fe(II)的生物氧化过程可以被有效应用于煤矿酸性矿井水修复中,但是Fe行为与归宿的不确定性增加了应用难度。本研究通过对某煤矿酸性矿井水场地发生的生物地球化学过程进行监测,富集培养场地沉积物嗜酸微生物群落,进行室内恒化生物反应器连续流实验,探究微生物作用下Fe及其他金属离子的行为与归宿。研究表明,Fe的形态转化是场地和反应器中最主要的生物地球化学过程。当pH<2.7时,反应更倾向于产生溶解性Fe(III);当2.7相似文献   

降水井改造为原位生产井的工艺设计及应用

为有效地扩大油页岩原位开采区域和节约油页岩原位开采的成本,需将废置的降水井改造成为原位生产井。根据降水井与原位生产井井身结构的相似性,对农安油页岩原位开采先导试验工程基地的降水井改造工艺进行了设计和优化。同时研发了偏心轮式套管割管装置及三爪式套管打捞装置用于拔管施工。工程实践证明,该工艺具有步骤简单、合理、高效以及价格低廉等特点。偏心轮式套管割管装置及三爪式套管打捞装置应用在降水井改造中,均取得理想的效果。     

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

Downstream patterns of bed sediment-borne metals,minerals and organic matter in a stream system receiving acidic mine effluent: A preliminary study

Different downstream variation patterns were observed for a range of bed sediment-borne metals (aqua regia-extractable fraction) in a subtropical stream system receiving acid mine drainage. Mine-originated Fe tended to be deposited in the acidic (mean pH < 4.9) upstream reach in forms of goethite and/or hematite. In contrast, other metals tended to be transported farther downstream and settled in a low-gradient reach with high pH (mean pH > 5.6). The peak of sediment-borne Al, Be, Ca, Cd, Co, Cu, La, Mn, Ni and Zn corresponded very well with the peak of the sediment-borne organic matter, suggesting a close association between the water-borne organic colloids and the inorganic metal oxides/hydroxides during their transport. The marked increase in the sediment-borne Al and Pb started more upstream than the other metals, suggesting that the water-borne Al and Pb were more susceptible to pH rise-induced precipitation, as compared to the other metals. It appeared that the organic colloids played no important role in Pb transport and settlement. The iron precipitates had a limited role to play in affecting the transport and fates of other metals since they were predominantly formed and deposited in the acidic reach, which made them incapable of scavenging cationic metals by co-precipitation or adsorption.     

某天然气井场填方滑坡治理过程分析及效果评价

某天然气井场坐落于一填方平台,由于土体填方施工时未达固结,致使该天然气井场3次发生滑坡灾害,并3次进行治理。采用的治理方案依次为地面排水 注浆加固 抗滑桩、抗滑桩 挡土墙加固、微型组合抗滑桩。在阐述该天然气井场填方滑坡特点的基础上,对治理工程及其效果进行了分析。     

复合加筋排水褥垫加固路基有限元计算

复合加筋排水褥垫是针对沿海缺砂地区开发的,具有水平排水与加筋作用的一项新型专利技术,可取代软基加固中的排水砂垫层。采用二维平面应变Biot固结有限元模型对复合加筋排水褥垫软土路堤进行了数值模拟,结果表明复合加筋排水褥垫可以满足水平排水要求,另外与传统的水平排水砂垫层相比,该技术可降低地基附加正应力和超孔隙水压力,有效抑制路基侧向变形的发展,减小路基沉降与不均匀沉降,提高路基稳定性,加筋效果显著。     

疏勒河流域中游生态环境变化及成因分析

近三十年来,疏勒河流域中游地区生态环境不断恶化,主要表现为绿色生产严重退化,湿地面积缩小,盐碱地,沙地迅速增加。通过不同时段的遥感解译,分析了不同生态景观的定量变化及成因。恶劣的地理环境加上人类活动对水资源利用量的不断增加是造成该区生态环境日趋恶化的主要因素。保护地下水平衡和合理用水结构,实行水资源优化管理,提高水的利用率是社会经济,环境可持续发展的有力保证。     

若尔盖沼泽湿地的萎缩机制

1960年以来,若尔盖沼泽湿地的快速萎缩严重影响黄河上游水量补给和当地湿地生态系统,但其机制尚不清晰。基于2010—2013年野外调查、气象水文资料和遥感影像,分析若尔盖沼泽退化的主要原因与机制。尽管气温的缓慢升高,但降水量并未减少,考虑到沼泽的季节性特征,气候变暖对沼泽萎缩影响相当有限,但不是主要原因。经遥感判读和统计,共识别现有920 km的人工渠道,其疏干的沼泽面积约648.3 km2,占总萎缩面积的27%。人工开渠作为强烈的人类活动干扰,是若尔盖沼泽快速萎缩的重要原因。自然水系的溯源侵蚀长期疏干沼泽、降低地下水水位和放射状地向沼泽内部切穿是沼泽萎缩的重要机制。人工开渠连通自然水系强化沼泽内河床下切和排水作用。     

某上游法尾矿坝抗滑稳定性浅析

通过某上游法尾矿坝抗滑稳定性分析,对比分析了坝体加高、浸润线条件、排渗系统运行状况和透镜体简化对尾矿坝抗滑稳定性的影响。结果表明该尾矿坝抗滑稳定性随坝体加高而降低;排渗系统运行状况对尾矿坝抗滑稳定性的影响超过坝体加高对尾矿坝抗滑稳定性的影响;根据一定简化原则减少透镜体,从而简化剖面形状和计算复杂程度,是一种能反映工程实际但比较保守的分析方法。拟静力法并非适合于所有的尾矿堆积坝抗震稳定性分析,即便采用其所得结果也可能会出现较大偏差。