用双硫腙－泡沫塑料反相色层萃取原子吸收法测定废水中的微量银

本文研究了双硫腙负载的聚氨酯泡沫塑料对水溶液中银离子的反相色层萃取行为，试验了Ｐｈ，流速、洗脱液及洗脱方法的影响。回收率试验表明，该法能定量捕集废水中银离子，结果令人满意。     

小体积萃取-石墨炉原子吸收法测定高纯硝酸钡中纳克级重金属元素

本文研究了石墨炉原子吸收光谱法测定高纯硝酸钡中超痕量重金属元素的分析技术。提出在大量钡基体存在时,采用小体积萃取体系APDC-MIBK同时萃取纳克级的Fe、Cu、Co和Ni。该法具有灵敏度高、无干扰、操作方便和减少沾污等特点。方法检出限为:Fe 7.2ng/g、Cu 12.8ng/g、Co 4.4ng/g和Ni 6.7ng/g。应用于红外光纤原料硝酸钡、硝酸铝中痕量重金属的测定,效果良好。     

Parameterization of the Absorption of the H_2O Continuum,CO_2,O_2,and Other Trace Gases in the Fu-Liou Solar Radiation Program

The absorption properties of the water vapor continuum and a number of weak bands for H2O, O2, CO2, CO, N2O, CH4, and O3 in the solar spectrum are incorporated into the Fu-Liou radiation parameterization program by using the correlated k-distribution method (CKD) for the sorting of absorption lines. The overlap absorption of the H2O lines and the H2O continuum (2500-14500 cm-1) are treated by taking the two gases as a single-mixture gas in transmittance calculations. Furthermore, in order to optimize the computation efforts, CO2 and CH4 in the spectral region 2850-5250 cm-1 are taken as a new single-mixture gas as well. For overlap involving other absorption lines in the Fu-Liou spectral bands, the authors adopt the multiplication rule for transmittance computations under which the absorption spectra for two gases are assumed to be uncorrelated. Compared to the line-by-line (LBL) computation, it is shown that the errors in fluxes introduced by these two approaches within the context of the CKD method are small and less than 0.48% for the H2O line and continuum in the 2500-14500 cm-1 solar spectral region, -1% for H2O (line) H2O (continuum) CO2 CH4 in the spectral region 2850-5250 cm-1, and -1.5% for H2O (line) H2O (continuum) O2 in the 7700-14500 cm-1 spectral region. Analysis also demonstrates that the multiplication rule over a spectral interval as wide as 6800 cm-1 can produce acceptable errors with a maximum percentage value of about 2% in reference to the LBL calculation. Addition of the preceding gases increases the absorption of solar radiation under all sky conditions. For clear sky, the increase in instantaneous solar absorption is about 9%-13% (~12 W m~2) among which the H2O continuum produces the largest increase, while the contributions from O2 and CO2 rank second and third, respectively. In cloudy sky, the addition of absorption amounts to about 6-9 W m-2. The new, improved program with the incorporation of the preceding gases produces a smaller solar absorption in clouds due to the reduced solar flux reaching the cloud top.     

1117号强台风“纳沙”引发海南岛特大暴雨过程分析

利于MICAPS资料、NCEP资料和多普勒天气雷达资料分析了1117号强台风“纳沙”造成海南岛特大暴雨过程分析。结果表明,强盛的西南季风为其提高了充足的水汽和能量;双重“列车效应”是造成海南岛特大暴雨的主要原因．暖平流上叠加辐合风场有利于强降水的形成和维持,“逆风区”与强降水中心一致;地形对降水起到明显的增幅作用。     

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

凹凸棒石与Zn^2＋的长期作用研究

以凹凸棒石与Zn2＋为例研究粘土矿物与重金属离子长期作用过程,并运用高分辨透射电镜和X射线衍射分析粘土矿物与重金属离子长期作用的次生物相。结果表明：Zn2＋与凹凸棒石的长期作用是一个二阶段的过程,初始阶段为快速吸附作用,其后表现为慢速沉淀反应。高分辨透射电镜和X射线衍射分析表明,凹凸棒石与Zn2＋的长期作用过程中,具有纳米矿物特性的凹凸棒石表面快速水化,提高了悬浮液的pH值,诱导Zn2＋水解沉淀。而后,凹凸棒石缓慢溶解释放Al3＋和SiO44-与Zn（OH）2沉淀反应,形成Zn-A1双氢氧化物和异极矿。这一结果对认识土壤环境中重金属与粘土矿物的作用及重金属的归宿具有重要意义。     

高温炉燃烧-红外吸收法测定重铀酸盐中硫质量分数

建立了高温燃烧红外碳硫仪测定重铀酸盐中硫质量分数的分析方法。样品以五氧化二钒为助熔剂,在高温炉燃烧后,用红外吸收测定重铀酸盐中的硫,样品分析重现性好,精密度高,相对标准偏差为0.26%;样品加标回收率在97.1%~103%之间。     

CMIP5模式对东太平洋ITCZ偶极子模态模拟能力的评估

本研究利用第五次国际间耦合模式比较计划(Coupled Model Intercomparison Project phase 5, CMIP5)中的24个模式的工业革命前控制试验(Pre-industrial Control, picontrol)模拟结果, 结合观测资料, 评估了24个CMIP5 模式对东太平洋热带辐合带偶极子(Eastern Pacific ITCZ dipole, EPID)降水模态的模拟能力, 并建立了其与模式对热带太平洋气候态模拟之间的联系。结果表明: 1) 绝大多数模式在北半球春季(2—4月)对EPID模态模拟能力较差, 主要原因在于CMIP5模式对热带辐合带(Intertropical Convergence Zone, ITCZ)的模拟偏差, 其中模拟效果较差的模式在2—4月的气候态降水分布在赤道以南, 且降水普遍偏强; 2) 对各模式的EPID模态选取的季节按照技巧评分最高进行调整后, 大部分模式能较好地模拟出EPID模态的空间分布特点, 技巧评分在0.6以上, 其中模拟效果好的模式(技巧评分大于0.7)中EPID模态出现的月份同时在中东太平洋气候态表现出“双ITCZ”特征, 且多模式集合结果的模拟误差小于绝大多数模式。     

自适应换站算法及其在长距离机载GPS动态相对定位中的应用

提出采用＂自适应换站＂法来解决单基线处理模式难以满足长距离动态定位的问题。该方法的主要思想是：整个解算过程始终保持单基线的动态定位模式,当发现流动站与原参考站间的距离大于流动站与其他参考站间的距离时,自动更换周围最近的参考站作为新参考站;对换站前后的数据设置一定时间的重叠段,利用等价消参法将换站前后的数据进行严格的自适应融合,以保持整个解算过程的连续性。通过对实测机载数据的解算,证明该方法不仅可以克服因载体飞行距离过远而导致的定位精度下降,而且能够避免因换站所引起的前后解的不连续,计算结果表明该方法的定位精度约为2 cm。     

植被的微波散射与吸收特征

被动微波遥感中大尺度像元内植被种类多种多样并且分布不均匀，较低频率下像元尺度内的植被影响可以根据单个散射体的散射与衰减特性获得。本文讨论了任意朝向的各类植被散射体的计算问题。其中叶片和针叶的散射采用了一般化Rayleigh-Gans计算；杆的散射采用了无限长近似理论。关于各类散射体的衰减，本文比较了散射系数和吸收系数之和，与前向散射定理的结果，并对前向定理的适用性进行了讨论。