Synthesis and characterization of zeolite X obtained from kaolin for adsorption of Zn（Ⅱ）

This study deals with the synthesis and characterization of low-silica zeolite X, from calcined Kalabsha kaolin, for adsorption of Zn(Ⅱ) ions from aqueous solution. The synthesis processes is performed under hydrothermal treatment in alkaline solutions. The obtained zeolite samples are characterized using X-ray diffraction, grain size distribution, surface area, and SEM. The critical molar ratios of both SiO2/Al2O3 and K2O/Na2O are about 2.9 and 0.16, respectively. Those ratios are needed to give individual low silica zeolite X in a minimum reaction time. The adsorption capacity of the synthesized products is determined by adsorption of Zn(Ⅱ) ions from solution. The results suggest that the zeolite obtained could be converted to a beneficial product, which will be used in future as an ion exchanger in removing heavy metals from wastewaters.     

陕西黄陇煤田侏罗系煤层气开发关键技术

黄陵煤田侏罗纪煤层裂隙发育,渗透率高,煤层气开发的地质条件优越,即将成为我国煤层气开发一个重要的潜在接替领域,根据焦坪矿区和彬长矿区煤层气开发取得的成果,详细探讨了煤层气开发方式、井位部署、钻完井工艺、压裂工艺和排采工艺等关键技术,指出欠平衡钻进、基于储层保护的洞穴完井和分层控压联合排采将是该区煤层气开发技术发展的方向。     

吉林集安铅锌矿地球化学与分散元素

吉林集安铅锌矿床是我国最早报导的少数几个典型低温铅锌矿床之一。矿化具有多期次特点 ,富矿体都是多期次矿化叠加的产物。根据矿化先后和矿物生成顺序将矿化分为五个阶段 :①石英 黄铁矿矿化阶段 ;②重晶石 闪锌矿矿化阶段 ;③石英 方铅矿矿化阶段 ;④石英 黄铁矿矿化阶段 ;⑤碳酸盐 氧化矿物矿化阶段。用均一法和爆裂法测得石英、重晶石、闪锌矿包裹体成矿温度变化在 1 1 0℃～ 1 97℃之间。矿床中除含铅锌矿外 ,还有微量的Pt和Pd,并普遍含分散元素Cd、Ga、Tl、In、Se、Ge、Te,其中以Cd含量最高 ,闪锌矿中Cd含量最高可达 71 5 5× 1 0 6。分散元素主要呈类质同象形式赋存在各种矿物之中 ,未发现独立矿物。通过矿床地质和硫铅同位素研究表明该铅锌矿床属低温沉积 改造型层控矿床。     

辽西中侏罗世高Sr低Y型火山岩的成因及其地质意义

通过对辽西阜新地区中侏罗世蓝旗组火山岩的岩石地球化学研究,燕山地区存在着中侏罗世高Sr低Y型火山岩。这些高Sr低Y型火山岩为高铝高钠低镁(Al2O3>15％,Na2O≥3.37％,MgO≤1.33％,Mg＃≤0.35)的安山岩-英安岩,高Sr(≥541μg/g)低Y、Yb(Y≤19μg/g,Yb≤1.35μg/g)含量及高Sr/Y(≥40)比值,强烈的稀土元素分馏((La/Yb)N>17,(No/Yb)N>1.2)),Eu异常不明显(0.82～0.96),高场强元素(如Nb、Ta)相对亏损。这些特征与太古代英云闪长岩-奥长花岗岩-花岗闪长岩(TTG)岩套相似。我们认为这些火山岩起源于古老的下地壳玄武质岩石的部分熔融,其形成可能与玄武质岩浆的底侵作用有关。辽西中侏罗世蓝旗组高Sr低Y型火山岩对探讨燕山造山带岩浆起源及地球动力学具有重要意义。     

鄂尔多斯盆地上古生界碎屑岩相对高渗储集层成因及分布*

鄂尔多斯盆地上古生界发育 “粒间孔型石英砂岩”、“溶孔型石英砂岩”、“粒间孔—溶孔复合型长石砂岩”3类相对高渗储集层。结合鄂尔多斯盆地地质背景,分析了该地区上古生界3类相对高渗储集层的岩石结构、组分与物性等基本特征,详细探讨了沉积环境、成岩作用、构造活动对鄂尔多斯盆地上古生界各类相对高渗储集层形成的控制机理,并在此基础上,依据与物源的距离、沉积相类型及砂体分布、孔隙类型、颗粒成分及粒度粗细、杂基成分及含量、储集层最大埋深、后期构造运动等因素,对主力勘探层系山西组二段和下石盒子组八段进行了储集层优劣分级综合评价,认为受高石英含量母岩控制的沉积体系、辫状河高能沉积相带和强溶蚀、弱压实的有利成岩相带分布区是鄂尔多斯盆地上古生界碎屑岩相对高渗储集层的主要发育区域。     

黑龙江省塔河绿林林场一带兴华渡口群岩石地球化学特征

黑龙江省塔河西北绿林林场一带原划分的兴华渡口群的岩石地球化学成分可与太古宙绿岩带对比,该区的兴华渡口群为低级地体（火山沉积盆地）,ＳｍＮｄ模式年龄及单阶段演化年龄为（１２５２±２８～１４６３±２０）Ｍａ。     

永553低渗砂砾岩区块一体化(IPM)钻井技术

永安油田永553区块目的层为沙四段,以含砾砂岩、砾岩为主,为低孔低渗油藏。前期施工井存在钻进速度慢、开采程度低、经济效益差等特点。针对永553低渗区块开发现状及开发难点,对该区块进行了一体化(IPM)钻井方案设计,并对钻井设计进行了优化。通过优化钻井技术,钻井提速明显,提高了井身质量,延长了油井寿命。永553低渗区块IPM钻井项目的成功实施,说明IPM钻井模式对于提高油井质量、节约钻井成本、提高经济效益是行之有效的。     

黔西北威-赫-纳-织-水地区铅锌(铜)矿带上 重力异常反映的地质信息

研究黔西北威宁—赫章—纳雍—织金—水城地区,铅锌(铜)矿带上分布的1∶20万区域重力异常特征,及其与地质、构造、岩体、化探等异常的对应规律及其关系,能对该区此类矿产的成矿规律、成矿部位和成矿特点的研究有所帮助,提出下一步找矿方向上的参考建议。     

鄂尔多斯盆地浅层大位移水平井钻井液体系优选

针对鄂尔多斯盆地浅层水平井钻井过程中的井壁稳定、井眼清洁、润滑减阻和储层保护的技术难题,通过分析储层的地质特征,在该区原用聚合物钻井液基础上,选择性加入MC-VIS、ABSN、纳米乳液和复合屏蔽暂堵剂,形成纳米乳液封堵钻井液体系,在保证施工安全的前提下,可将岩心渗透率恢复提高至8350%。通过七平1井的应用表明,纳米乳液封堵钻井液体系能够满足低渗透油层大位移水平井的钻井施工需求,为高效开发鄂尔多斯盆地浅层油气藏提供技术支持。     

Geochemical Mapping: With Special Emphasis on Analytical Requirements

More than 40 national and regional geochemical mapping projects in the world carried out from 1973 to 1988 do not conform to common standards. In particular they have many analytical deficiencies. In the period 1988 to 1992, the International Geochemical Mapping project （Project 259 of UNESCO＇s IGCP Program） prepared recommendations designed to standardize geochemical mapping methods. The analytical requirements are an essential component of the overall recommendations. They included the following： 71 elements should be analyzed in future mapping projects; the detection limits of trace and ultratrace elements must be lower than the corresponding crustal abundances; and the Chinese GSD and Canadian STSD standard sample series should be used for the correlation of global data. A proposal was also made to collect 5000 composite samples, at very low sampling densities to cover the whole Earth＇s land surface. In 1997 an IUGS Working Group on Global Geochemical Baselines was formed to continue the work which began with IGCP 259. From 1997 up to now, new progress has been made especially in China and FOREGS countries under the aegis of this working group, including the study of suitable sampling media, development of a multi-element analytical system, new proficiency test for selection of competent laboratories and role of wide-spaced mapping in mineral exploration. One of the major problems awaiting solution has been the inability of many laboratories to meet the IGCP recommendations to generate high quality geochemical maps. Fortunately several laboratories in China and Europe have demonstrated an ability to meet the requirements and they will be well placed to render technical assistance to other countries.