基于TC35的远程温度监测报警系统

针对日常生活中因对温度变化的忽视引起的各种问题,提出一种对温度进行远程监测并短信通知用户的系统,以达到向用户进行温度报警的目的.系统主要由STC89C52单片机,液晶显示器1602,温度传感器DS18B20,TC35模块4大部分构成,首先通过温度传感器DS18B20采集当前环境温度,然后利用液晶显示器1602将当前温度显示出来,与此同时单片机判断当前温度值,当前温度超过温度上限值时,单片机控制GSM模块向指定手机号发送一条短信.结果显示,当温度超过设定温度时,指定手机会收到一条报警短信,提醒用户当前的温度超过了温度上限.通过与传统的温度检测系统作对比,系统能够得到较准确的温度检测值其测温误差能够控制在0.4以下,并且通过发送短信来对温度进行远程实时监测.     

Impacts of Two Ice Parameterization Schemes on the Cloud Microphysical Processes and Precipitation of a Severe Storm in Northern China

A severe storm that occurred over Beijing in northern China on 23 June 2011 was simulated with two different ice crystal parameterization schemes(the DeMott scheme and Meyers scheme) by using the Regional Atmospheric Modeling System. Compared with the DeMott scheme, the simulation results with the Meyers scheme have the following characteristics:(1) Updrafts are stronger and more numerous;(2) The cloud is better organized and contains a greater peak of ice-phase hydrometeor mixing ratios;(3) Cloud water and hail mixing ratios increase while graupel mixing ratios decrease;(4) The surface precipitation is initially greater. However, at the end of the simulation, less precipitation is produced. In short, the differences between the two schemes are not obvious, but the De Mott scheme has a relatively more reasonable result.     

Molecularly imprinted polymers for selective extraction of crystal violet from natural seawater coupled with high-performance liquid chromatographic determination

Molecularly imprinted polymers(MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Systematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction(MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200 μg L-1(R2 0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation(n=3) being in the range of 2.89%-5.96%.     

四川盆地震旦系灯影组葡萄状白云岩成因

四川盆地震旦系灯影组发育巨厚的白云岩,其中灯影组二段和四段发育大量具有各种形态的葡萄状白云岩,其直径最长可达75cm,有的平行于层面,有的穿层。剖面资料表明,葡萄状白云岩发育多期等厚环边胶结物,中部残留大量未充填的不规则洞穴,这成为与岩溶喀斯特作用相关的地下溶蚀作用的证据。围岩泥晶白云石为早期海水中原生结晶的产物,后来的胶结物可划分为4期: (1)自泥晶化白云石(部分样品中可见)作为最早的一期胶结物,由于各种生物化学作用和生物作用的影响而紧贴着围岩发育;(2)第2期胶结物纤维状白云石可能为海水中直接沉淀的产物,经历后期成岩作用后,具有完全有序的结构,晶胞参数接近理想值;(3)细—中晶白云石为第3期胶结物,包含纤维状白云石溶蚀残余,形成于构造抬升之后的近地表大气淡水环境;(4)第4期胶结物中—粗晶白云石为埋藏环境下直接结晶的产物,充填了孔洞中心,残留部分未充填孔洞。灯影组受到了岩溶喀斯特作用、胶结作用以及白云石化作用等成岩作用的影响,其中与葡萄状白云岩有关的岩溶喀斯特作用对于灯影组储集层的发育至关重要。对灯影组葡萄状白云岩的研究,不仅有助于深入探讨灯影组储集层成因和演化及灯影组白云岩的成因,而且有助于指导四川盆地前寒武系油气勘探。     

SCATTERING PHASE MATRICES OF ICE CRYSTALS WITH HEXAGONAL PRISM AND TRIANGULAR PYRAMID FORM—A VECTOR RAY TRACING METHOD

The work presented previously by the authors(Cai and Liou,1982)has been extended in this paper.By making use of our improved model the calculations on scattering phase matrices of hexagonal prismice crystals(HPIC)have been conducted for monodisperse and polydisperse systems.Compared with themodel of Cai and Liou,the required computational quantity is decreased by about two orders of magni-tude and the errors of results are less for the new model.Meanwhile,the scattering phase matrices of triangularpyramid ice crystals(TPIC)are also computed in the paper,and the comparison between the scatterings of thetwo forms of ice crystals is performed.     

The Upper Crustal Evolution of a Large Silicic Magma Body: Evidence from Crystal-scale Rb Sr Isotopic Heterogeneities in the Fish Canyon Magmatic System, Colorado

Batholith-sized bodies of crystal-rich magmatic ‘mush’are widely inferred to represent the hidden sources of manylarge-volume high-silica rhyolite eruptive units. Occasionallythese mush bodies are ejected along with their trapped interstitialliquid, forming the distinctive crystal-rich ignimbrites knownas ‘monotonous intermediates’. These ignimbritesare notable for their combination of high crystal contents (35–55%),dacitic bulk compositions with interstitial high-silica rhyoliticglass, and general lack of compositional zonation. The 5000km³ Fish Canyon Tuff is an archetypal eruption deposit of thistype, and is the largest known silicic eruption on Earth. Ejectafrom the Fish Canyon magmatic system are notable for the limitedcompositional variation that they define on the basis of whole-rockchemistry, whereas 45 vol. % crystals in a matrix of high-silicarhyolite glass together span a large range of mineral-scaleisotopic variability (microns to millimetres). Rb/Sr isotopicanalyses of single crystals (sanidine, plagioclase, biotite,hornblende, apatite, titanite) and sampling by micromillingof selected zones within glass plus sanidine and plagioclasecrystals document widespread isotopic disequilibrium at manyscales. High and variable ⁸⁷Sr/⁸⁶Sr_i values for euhedral biotitegrains cannot be explained by any model involving closed-systemradiogenic ingrowth, and they are difficult to rationalize unlessmuch of this radiogenic Sr has been introduced at a late stagevia assimilation of local Proterozoic crust. Hornblende is theonly phase that approaches isotopic equilibrium with the surroundingmelt, but the melt (glass) was isotopically heterogeneous atthe millimetre scale, and was therefore apparently contaminatedwith radiogenic Sr shortly prior to eruption. The other mineralphases (plagioclase, sanidine, titanite, and apatite) have significantlylower ⁸⁷Sr/⁸⁶Sr_i values than whole-rock values (as much as –0·0005).Such isotopic disequilibrium implies that feldspars, titaniteand apatite are antecrysts that crystallized from less radiogenicmelt compositions at earlier stages of magma evolution, whereashighly radiogenic biotite xenocrysts and the development ofisotopic heterogeneity in matrix melt glass appear to coincidewith the final stage of the evolution of the Fish Canyon magmabody in the upper crust. Integrated petrographic and geochemicalevidence is consistent with pre-eruptive thermal rejuvenationof a near-solidus mineral assemblage from 720 to 760°C (i.e.partial dissolution of feldspars + quartz while hornblende +titanite + biotite were crystallizing). Assimilation and blendingof phenocrysts, antecrysts and xenocrysts reflects chamber-wide,low Reynolds number convection that occurred within the last10 000 years before eruption. KEY WORDS: Fish Canyon Tuff; Rb–Sr isotopes; microsampling; magmatic processes; crystal mush     

The crystal structure of (Fe<Subscript>4</Subscript>Cr<Subscript>4</Subscript>Ni)<Subscript>9</Subscript>C<Subscript>4</Subscript>

(Fe4Cr4Ni)9C4 is a metal carbide mineral formed by combination of Fe, Cr and Ni with C. It occurs in a chromite deposit in the Luobusha ophiolite, Tibet. Based on the determination of its crystal structure, the empirical formula is (Fe4.12Cr3.84Ni0.96)8.92C3.70 and the simplified formula is (Fe4Cr4Ni)4C9. The mineral is hexagonal with a = 1.38392(2) nm, c = 0.44690(9) nm, pace group P63 m c, Z=6 and the calculated specific gravity Dx = 7.089 g/cm3. Fe, Cr and Ni occupy different crystallographic sites and their coordination numbers are approximately 12, forming an alternate stacking sequence of flat and puckered layers along the c axis. Some metallic atoms have a defect structure. The interatomic distances of Fe, Cr and Ni are 0.2525-0.2666 nm, and the distances between Fe, Cr, Ni and C are 0.1893-0.2169 nm. The coordination number of carbon is 6. It occurs in interstices of the metallic atoms Fe, Cr and Ni to form trigonalprismatically coordinated polyhedra. These coordination polyhedra are linked with each other via shared corners or shared edges into a new type of metal carbide structure.     

Geometric selection in two-dimensional crystal aggregates

The simultaneous growth of randomly oriented crystals nucleated at a surface rapidly produces a coarsely crystalline radial or columnar aggregate possessing a strong preferred shape and lattice orientation. Such textures are common in natural crystalline aggregates and are considered to arise because those crystals having their fastest growth direction normal to the initial substrate outdistance and eventually eliminate their less favorably oriented neighbors. In its simplest form the process of elimination is a purely geometric phenomenon. Detailed analysis and computer simulation of textural changes accompanying geometric selection in random two dimensional needlelike crystal aggregates demonstrate that selection initially proceeds exceedingly rapidly but slows drastically once roughly 90 percent of the crystals originally present are eliminated. Subsequent decrease in crystal density is inversely proportional to the square root of the distance from the initial substrate. Increases in crystal size larger than one or two orders of magnitude are thus unlikely to arise in natural crystalline aggregates in which only simple geometric selection is involved.     

New data of typomorphic features of diamonds from placers in North Timan

The morphological and spectral-optical properties of diamond crystals from placers in North Timan rivers have been studied with IR-spectroscopy and cathode luminescence methods. As a result, correlation between external characteristics of diamonds (size and degree of mechanical damage) and number of optically active centers has been revealed. The habit and the type of distribution of structural defects in diamond crystals studied are comparable with those in diamonds from the Archangelsk Region and North Timan’s placers. Based on the obtained data, origin issues and possible primary sources of diamonds from North Timan’s placers are discussed.     

The biogenic origin of needle fibre calcite

Needle fibre calcite is one of the most ubiquitous habits of calcite in vadose environments (caves deposits, soil pores, etc.). Its origin, either through inorganic, indirect or direct biological processes, has long been debated. In this study, investigations at 11 sites in Europe, Africa and Central America support arguments for its biogenic origin. The wide range of needle morphologies is the result of a gradual evolution of the simplest type, a rod. This rod is the elementary brick which, by aggregation and welding, builds more complex needles. The absence of cross‐welded needles implies that they are welded in a mould, or under a longitudinal and unidirectional constraint, before being released inside the soil pores. The difference between the lengthening of the needles and the c axis can be explained by the existence of needles observed under a scanning electron microscope in organic sleeves, which can act as a mould during rod growth. Complex morphologies with epitaxial outgrowths on straight rods cannot have grown entirely inside organic microtubes; they must result from soil diagenesis after the release of straight rods in a soil‐free medium. Whisker crystals are interpreted as the result of growth and coalescence of euhedral crystals on a rod. Rhomb chains are considered to be the consequence of successive epitaxial growth steps on a needle during variations in growth conditions. Isotopic signatures for needle fibre calcite vary from ?16·63‰ to +1·10‰ and from ?8·63‰ to ?2·25‰ for δ¹³C and δ¹⁸O, respectively. The absence of high δ¹⁸O values for needle fibre calcite precludes a purely physicochemical origin (evaporative) for this particular habit of calcite. As epitaxial growth cannot precipitate in the same conditions as initial needles, needle fibre calcite stable isotopic signatures should be used with caution as a proxy for palaeoenvironmental reconstructions. In addition, it is suggested that the term needle fibre calcite should be kept for the original biogenic form. The other habit should be referred to as epitaxial forms of needle fibre calcite.