中国湖相碳酸盐岩时空分布与碳氧同位素特征*

湖相碳酸盐岩产状多样,多以夹层形式分布在碎屑岩剖面中,也见以结核或钙质微体化石等薄层赋存于泥岩、页岩等碎屑岩中,具有层数多、单层薄、呈韵律性变化等特点。受构造背景、物源输入和古环境等因素控制,中国湖相碳酸盐沉积最早出现于二叠纪,主要发育时段为古近纪,具有沉积时间跨度大、分布面积广的特征。湖相碳酸盐岩按成因可分为原生沉积型、成岩改造型和热液喷流型3类。中国湖相碳酸盐岩的碳氧同位素特征可揭示原生和成岩过程中水介质环境的差异性: (1)δ¹³C和 δ¹⁸O 密切相关,且δ¹³C多正偏,指示封闭型咸水、半咸水湖泊环境;(2)δ¹³C和 δ¹⁸O 无相关性,且δ¹³C多负偏,指示开放型湖泊环境;(3)δ¹³C严重正偏,指示成岩作用时发酵带的环境受到古细菌参与的甲烷生成作用的影响。     

油气藏微观不均一性及其意义

油气储集岩中不同孔隙类型（开放型与封闭型）中的油气组分、孔隙中自由状态的油气组分、矿物颗粒表面吸附（束缚状态）的油气组分、以及矿物内部油气包裹体之间常规生物标志化合物组成（甾、萜分布）存在明显的差异,反映了不同成藏阶段油气组成的地球化学特征,展示了油气充填过程,同时为油源对比提供了新方法。     

FGC－15型大直径单头潜孔锤钻具系统研制

大直径单头潜孔锤与三通道气水龙头、主动钻杆、三通道钻杆、加重导正器配套，可实现大直径潜孔锤碎岩钻进、泵吸反循环排渣、泥浆护壁、压气闭路循环等相结合的先进钻进工艺，是解决大直径硬质基岩及卵砾石钻进的有效机具。文中介绍了钻具研制过程及设计内容。     

封闭消解-阳离子交换分离-电感耦合等离子体质谱法测定铜铅锌矿石中的铼

阴离子交换树脂已被应用于酸法消解-电感耦合等离子体质谱(ICP-MS)测定铜铅锌矿石等地质样品中铼的分离富集,样品溶液中的ReO_4~-用树脂交换吸附后再用洗脱剂将ReO_4~-选择性洗脱,该方法流程长,影响其稳定性和准确性。本文以基体元素为吸附交换目标,用8 g的732强酸型阳离子交换树脂在2%硝酸介质条件下静态吸附1.5 h,可有效地消除基体元素的影响。用空矿(石英)稀释低含量铼的样品做空白试验,获得方法检出限为0.004μg/g,精密度(RSD)小于6%,加标回收率为96%~104%。本方法应用的732强酸型阳离子交换树脂在适宜酸度条件下,对矿石中除钨、钼以外的金属元素吸附率高达95%以上,降低了样品溶液离子强度和干扰元素浓度,实现了ICP-MS的直接测定,操作方法比阴离子交换吸附法简便。     

Quantifying and testing differences among means of compositional data suites

Commonly, geological studies compare mean values of two or more compositional data suites in order to determine if, how, and by how much they differ. Simple approaches for evaluating and statistically testing differences in mean values for open data fail for compositional (closed) data. A new parameter, an f-value, therefore has been developed, which correctly quantifies the differences among compositional mean values and allows testing those differences for statistical significance. In general, this parameter quantifies only therelative factor by which compositional variables differ across data suites; however for situations where, arguably, at least one component has neither increased nor decreased, anabsolute f-value can be computed. In situations where the compositional variables have undergone many perturbations, arguments based upon thef-values and the central limit theorem indicate that logratios of compositional variables should be normally distributed.     

厦门西港底质耗氧的测定

采用闭合循环实验方法,观测了厦门西港底质耗氧过程。结果显示底质耗氧随时间变化呈非线性,可用指数方程SOD=ρ·exp(—k/t)表示.计算得厦门西港底质耗氧速率均值为405.8mg/(m~2·d)。在底质耗氧过程中,底质释放出有机物质,底质释放COD 速率为93.6mg/(m~2·d),底质耗氧作用与底质有机物质的释放有关.     

基于本体的水系要素数据集成方法研究

简单论述了地理本体的基本概念、结构,介绍了地理本体的建模方法,提出了基于地理本体的空间数据集成框架,采用基于公共属性模板的多本体向标准本体集成的混合构架,以水系要素中的“干出滩”类为例,实现了基于地理本体的空间数据集成过程及其数据的转换,解决了数据语义异构性所带来的数据共享难题。     

Characteristics of δ13CDIC in lakes on the Tibetan Plateau and its implications for the carbon cycle

Dissolved inorganic carbon isotope (δ¹³C_DIC) is an important tool to reveal the carbon cycle in lake systems. However, there are only few studies focusing on the spatial variation of δ¹³C_DIC of closed lakes. Here we analyze the characteristics of δ¹³C_DIC of 24 sampled lakes (mainly closed lakes) across the Qiangtang Plateau (QTP) and identify the driving factors for its spatial variation. The δ¹³C_DIC value of these observed lakes varies in the range of ? 15·0 to 3·2‰, with an average value of ? 1·2‰. The δ¹³C_DIC value of closed lakes is close to the atmospheric isotopic equilibrium value, much higher than that in rivers and freshwater lakes reported before. The high δ¹³C_DIC value of closed lakes is mainly attributed to the significant contribution of carbonate weathering in the catchment and the evasion of dissolved CO₂ induced by the strong evaporation of lake water. The δ¹³C_DIC value of closed lakes has a logarithmic correlation with water chemistry (TDS, DIC and pCO₂), also suggesting that the evapo‐concentration of lake water can influence the δ¹³C_DIC value. The δ¹³C_DIC value shows two opposite logarithmic correlations with lake size depending on the δ¹³C_DIC range. This study suggests that the δ¹³C in carbonates in lacustrine sediments can be taken as an indicator of lake volume variation in closed lakes on QTP. Copyright © 2011 John Wiley & Sons, Ltd.     

边界问题及其对真空预压的影响

给出了真空预压区四周开敞式与封闭式边界定义、两者的不同,分析了开敞式边界加固效果优于封闭式边界的原因并以三个实例说明之,给出如何将封闭式转化为开敞式的方法;柔性与刚性密封膜同样可构成开敞式与封闭式边界,讨论了此时两种边界下差别;给出了密封墙和支挡墙的定义、功能、应用范围;讨论了水泥搅拌与旋喷桩单体墙与格栅墙的定义、功能、应用范围,前者只能作为密封墙,后者既可作密封墙也可作支挡墙.     

Complete Zonal Problem of the Artificial Satellite: Generic Compact Analytic First Order in Closed Form

This paper is a contribution to the Theory of the Artificial Satellite, within the frame of the Lie Transform as canonical perturbation technique (elimination of the short period terms). We consider the perturbation by any zonal harmonic J _n (n ≥ 2) of the primary on the satellite, what we call here the complete zonal problem of the artificial satellite. This is quite useful for primaries with symmetry of revolution. We give an analytical formula to compute directly the first order averaged Hamiltonian. The computation is carried out in closed form for all terms, avoiding therefore tedious expansions in the eccentricity or in any anomaly; this feature makes the averaging process, not only valid for all kind of elliptic trajectories but at the same time it yields the averaged Hamiltonian in a very short and compact way. The formula allows us to now skip the averaging process, which means an asymptotic gain of a factor 3n/2 regarding the computational cost of the n ^th zonal. Our analytical formulae have been widely checked, by comparison on one hand with published works (Brouwer, 1959) (which contained results for particular zonal harmonics, let’s say typically from J ₂ to J ₈), and on the other hand with the results of 3 symbolic manipulation software, among which the MM (standing for ‘Moon’s series Manipulator’), which has already been used and described in (De Saedeleer B., 2004). Additionally, the first order generator associated with this transformation is given into the same closed form, and has also been validated.