岩溶关键带水文地球化学研究进展

岩溶关键带处于岩石、水、土壤、大气、生物五圈交汇地带。正确认识岩溶关键带的结构、特点及其水文地球化学过程是当前地球关键带与岩溶水科学研究的重点问题。本文基于对国内外相关研究成果的归纳整理,剖析了岩溶关键带水文地球化学内涵、岩溶关键带水动力垂向分带、岩溶关键带框架下的水文地球化学过程与机制, 探寻变化环境下岩溶关键带水文地球化学过程演变的规律与驱动机制。指出了当前研究中存在的薄弱环节:目前工作仅停留在传统岩溶地下水科学工作范畴,未从岩溶关键带框架体系的角度考虑植物冠层至岩溶含水层之间水文地球化学过程及其耦合关系,未考虑新污染物持续输入、地球大数据科学工程深入实施、全球碳排放路径逐渐改变等时代因素对岩溶水文地球化学研究的潜在影响。进一步的研究可以从以下方面开展:基于岩溶关键带框架体系的新污染物水文地球化学研究,基于大数据框架体系的岩溶水文地球化学研究,“双碳战略”下的岩溶水文地球化学研究,岩溶关键带水文地球化学驱动的物质转化与能量迁移过程及其耦合以及高分辨率监测、评估与模拟手段的综合应用。     

中全新世云南寻甸地区气候演化过程及其驱动机制初步研究

通过对云南寻甸仙人洞XR1石笋进行TIMS-U系测年、氧碳同位素、有机碳含量分析,重建了寻甸地区中全新世季风气候演化模式:(1)8.0～6.0kaB.P.为温暖湿润期;(2)6.0～5.1kaB.P.为气候突变期,气候由温湿变为冷干;(3)5.1～2.1kaB.P.为凉干期。通过石笋有机碳含量与石笋δ18O记录对比,认为石笋有机碳可以反映气候变化,但是存在滞后效应。最后,利用XR1石笋δ18O记录与北半球33°N太阳辐射量,本文初步分析了云南寻甸地区中全新世气候变化的驱动因素:寻甸地区中全新世气候的整体变化趋势受33°N太阳辐射量控制,同时受中全新世火山活动的影响。      

30ka以来南海东北部陆坡坡底沉积有机质的长链正构烷烃特征及其古植被意义

为探寻南海深海平原区的有机质组成特征、来源及其所反映的古气候/环境演化信息, 对南海东北部深水区的ZSQD289沉积柱状样品进行了正构烷烃组成及其单体稳定碳同位素的相关分析, 结合孢粉鉴定结果, 重点探讨该沉积区末次冰期以来陆源输入变化、源区的古植被演化及其气候响应因素。结果表明:30ka以来, 南海东北部深海陆坡坡底的沉积有机质以洋/陆混源为特征, 且以海洋自生生产力贡献为主, 其生源贡献存在明显的冰期/间冰期旋回变化特征, 冰期时陆源有机质输入明显高于全新世间冰期; 其陆源有机质应该主要由台湾南部河流输入, 在低海平面时通过海底峡谷搬运至此, 其过程中可能受到西太平洋底流和黑潮的影响。该沉积源区植被演化经历了C3/C4植物互为消长的变化过程, 但30ka以来主要还是以C3植物占优势, 由此推测末次冰期以来源区(台湾岛南部)不存在明显的干旱化, 冰期虽然温度较低但气候比较湿润。     

Incorporation of a dynamic root distribution into CLM4.5: Evaluation of carbon and water fluxes over the Amazon

Roots are responsible for the uptake of water and nutrients by plants and have the plasticity to dynamically respond to different environmental conditions. However, most land surface models currently prescribe rooting profiles as a function only of vegetation type, with no consideration of the surroundings. In this study, a dynamic rooting scheme, which describes root growth as a compromise between water and nitrogen availability, was incorporated into CLM4.5 with carbon–nitrogen(CN) interactions(CLM4.5-CN) to investigate the effects of a dynamic root distribution on eco-hydrological modeling. Two paired numerical simulations were conducted for the Tapajos National Forest km83(BRSa3) site and the Amazon, one using CLM4.5-CN without the dynamic rooting scheme and the other including the proposed scheme. Simulations for the BRSa3 site showed that inclusion of the dynamic rooting scheme increased the amplitudes and peak values of diurnal gross primary production(GPP) and latent heat flux(LE) for the dry season, and improved the carbon(C) and water cycle modeling by reducing the RMSE of GPP by 0.4 g C m~(-2)d~(-1), net ecosystem exchange by 1.96 g C m~(-2)d~(-1), LE by 5.0 W m~(-2), and soil moisture by 0.03 m~3m~(-3), at the seasonal scale, compared with eddy flux measurements, while having little impact during the wet season. For the Amazon, regional analysis also revealed that vegetation responses(including GPP and LE) to seasonal drought and the severe drought of 2005 were better captured with the dynamic rooting scheme incorporated.     

新疆准噶尔—东天山地区产于韧性剪切带中的金矿床成矿流体与碳、硫、铅同位素

韧性剪切带型金矿床是新疆准噶尔-东天山地区重要金矿类型。本文以科克萨依、康古尔、红石金矿为典型矿床,研究它们的流体包裹体均一温度、爆裂温度、包裹体成分、包裹体水的来源等,并进行了硫、铅同位素及近矿围岩碳同位素、矿体石英包裹体中CO2、CH4气体的碳同位素分析。结果表明,硫、铅为深源,暗示了本区金成矿物质的地幔来源。部分碳为有机碳,反映了本区年轻碳质沉积地层中有机碳参与了金的迁移与成矿作用。综合研究表明,在本区特定的后碰撞地质背景下,在构造挤压与伸展作用中形成的韧性剪切带中的金矿床金成矿物质源于深源,成矿流体主要是变质水。岩浆作用、变质作用、碳质围岩地层有机碳参与成矿,变质流体与岩浆热液及天水等流体的不同程度的混合与叠加,形成本区特征的韧性剪切带型金矿床。     

全球主要河流流域碳酸盐岩风化碳汇评估

碳酸盐岩风化吸收的大气CO₂主要以HCO₃ ^-形式连续地经由河流从大陆输送到海洋,成为陆地生态系统的重要碳汇。目前主要河流流域的碳酸盐岩风化碳汇估算存在不确定性,分布格局尚不清晰。基于GEMS-GLORI全球河流数据库提供的全球10万km ²以上主要河流流域多年平均监测数据,利用水化学径流法估算出全球主要河流流域碳酸盐岩对CO₂的吸收速率为0.43±0.15 Pg CO₂ yr ^-1,平均CO₂吸收通量为7.93±2.8 t km ^-2 yr ^-1。CO₂吸收通量在不同气候带下差异显著,热带和暖温带CO₂年吸收速率占全球主要河流流域年吸收速率的62.95%。冷温带CO₂年吸收速率占全球主要河流流域的33.05%,仅次于热带地区。本文划分出全球CO₂吸收通量的9个关键带,关键带的交汇处CO₂吸收通量较高。喀斯特出露流域碳酸盐岩对CO₂吸收通量的均值为8.50 t km ^-2 yr ^-1,约为非喀斯特流域的3倍。全球喀斯特出露流域碳酸盐岩风化碳汇在全球碳循环、水循环及碳收支平衡估算研究方面占据重要地位。     

沉积地层中成矿作用的碳同位素特征和含矿缺氧盆地成因新观点

沉积盆地内地层中碳的来源 ,根据其碳、氧同位素特征可归纳为 :海洋沉积碳酸盐碳、生物碳、热解非生物成因碳、大气淡水方解石碳和热卤水系统中的无机碳。热水成因的金矿及喷气 沉积矿床中的碳都具有深源成因的无机碳。深部含无机碳的热流体喷溢到海洋底部可以解释为扩张盆地底部形成的缺氧环境和含矿黑色页岩的主导原因     

Shallow-Water Gasohydrothermal Vents of Ushishir Volcano and the Ecosystem of Kraternaya Bight (The Kurile Islands)

Abstract. A marine ecosystem in the crater of the Ushishir Volcano (Kraternaya Bight, Yankich Island, the Kuriles) showing gasothcrmal activity was studied for hydrographical, hydrochemical, and biological characteristics. Maximal changes in chemical and biological characteristics were observed in the surface water layer of 0–5 m. This layer had higher water temperature, was saturated with volcanogcnic carbon dioxide (up to 2000 10^-6 torr), ovcrsaturatcd with oxygen (up to 200 %), and contained high concentrations of chlorophyll a. Hydrogen sulfide was found in the surface water layer and at a depth of 15 m in the area of maximal effect of volcanic effluents.
The planktonic community is characterized by high rates of production and destruction of organic matter only in the 0–5 m layer. Daily vertical migrations of the ciliatc Mesodinium rubrum were observed, which caused "red tides".
Bacterial, algobacterial, and diatom mats developed on the bottom of the bight in the zone of gasohydrothermal vents and in areas of volcanic water seeping. The rate of organic matter production in algobacterial mats reached 33.4g C-rrr²-d^-l, chcmolithotrophy predominating. Bottom settlements had high population density and great animal biomass, which reached 10 kg m^-2 in gasohydrothermal fields. They obtain sufficient energy from primary production of microphy-tobenthos, algobacterial, and bacterial mats. Bcnthic species dominant in the bight were not found off the Ushishir Islands.
Some species of macrobenthos inhabiting the Kraternaya Bight differ markedly in size and biomass from the same species found beyond the bight.     

河南省鲁山县背孜矿区石墨矿床地质特征及其成因探讨

河南省鲁山县背孜石墨矿床地处华北地台南缘灵宝-鲁山-舞阳石墨成矿带。矿区主要含矿岩石为太华群水底沟组片麻岩及大理岩。该区断裂构造较为发育,构造活动对矿体起到了一定的破坏作用,同时造成了本区石墨的局部富集。矿石类型主要为片麻岩型石墨矿,石墨呈晶质鳞片状。通过野外观察,室内矿石组分研究以及碳同位素分析认为该石墨矿床成因类型应为沉积变质矿床,并具有后期热液叠加富集特征,成矿物质来源主要为有机碳与无机碳两种类型,且不同含矿岩石中碳质来源具有差异性特征。     

广西柳桥深水相二叠系/三叠系界线剖面有机碳同位素地层学对比研究及事件响应

研究了广西柳桥地区东攀剖面有机碳同位素的组成,并和浙江煤山剖面进行了对比。结果表明东攀剖面在1δ3Corg变化趋势上,既具有全球PTB剖面普遍存在的共性,又具有其独特性。在东攀剖面一个显著的1δ3Corg负漂移出现在事件界线(EB)之上和二叠系/三叠系界线(PTB)之下,这与煤山剖面具有相似性。显著的1δ3Corg负漂移指示了P/T之交生物绝灭后海水表层水原始生产率的降低以及大气和海水中CO2含量的增加,并得到放射虫绝灭事件、火山事件和海退事件的响应。煤山剖面1δ3Corg负漂移从第27层就开始向13C富集的方向恢复,而东攀剖面1δ3Corg在下Induan阶仍持续亏损,表明东攀剖面早三叠世的生物复苏明显滞后于煤山剖面的。