An Assessment of HOx Chemistry in the Tropical Pacific Boundary Layer: Comparison of Model Simulations with Observations Recorded during PEM Tropics A

Reported are the results from a comparison of OH,H₂O₂CH₃OOH, and O₃ observationswithmodel predictions based on current HO_x–CH₄reaction mechanisms. The field observations are thoserecorded during the NASA GTE field program, PEM-Tropics A. The major focus ofthis paper is on thosedata generated on the NASA P-3B aircraft during a mission flown in the marineboundary layer (MBL) nearChristmas Island, a site located in the central equatorial Pacific (i.e.,2° N, 157° W). Taking advantage of thestability of the southeastern trade-winds, an air parcel was sampled in aLagrangian mode over a significantfraction of a solar day. Analyses of these data revealed excellent agreementbetween model simulated andobserved OH. In addition, the model simulations reproduced the major featuresin the observed diurnalprofiles of H₂O₂ and CH₃OOH. In the case ofO₃, the model captured the key observational feature whichinvolved an early morning maximum. An examination of the MBL HO_xbudget indicated that the O(¹D) + H₂Oreaction is the major source of HO_x while the major sinks involveboth physical and chemical processes involving the peroxide species,H₂O₂ and CH₃OOH. Overall, the generally goodagreement between modeland observations suggests that our current understanding ofHO_x–CH₄ chemistry in the tropical MBL isquite good; however, there remains a need to critically examine this chemistrywhen both CH₂O and HO₂are added to the species measured.     

An Actively Controlled Wind Tunnel And Its Application To The Reproduction Of The Atmospheric Boundary Layer

An actively controlled wind tunnel equipped with multiple fansand airfoils has been developed, mainly for the purpose of reproducing the atmospheric boundary layer (ABL) for wind engineering applications. Various fluctuating flows can be achieved in this wind tunnel by altering the input data of the fans and airfoils through computer control. In this study, the ABL is physically simulated in this wind tunnel, and particular attention ispaid to the simulation of the profile of Reynolds stress. The method of generating the fluctuating flow and the experimental results of reproducing the ABL are presented. As the results show, the spatial distribution of Reynolds stress is satisfactorily simulated, and the profiles of other statisticalturbulent parameters, such as mean velocity, turbulent intensity, integral scale and power spectrum are successfully reproduced simultaneously.     

Isoprene and Its Oxidation Products Methyl Vinyl Ketone, Methacrolein, and Isoprene Related Peroxides Measured Online over the Tropical Rain Forest of Surinam in March 1998

Airborne measurements of volatile organic compounds (VOC) were performed overthe tropical rainforest in Surinam (0–12 km altitude,2°–7° N, 54°–58° W) using the proton transferreaction mass spectrometry (PTR-MS) technique, which allows online monitoringof compounds like isoprene, its oxidation products methyl vinyl ketone,methacrolein, tentatively identified hydroxy-isoprene-hydroperoxides, andseveral other organic compounds. Isoprene volume mixing ratios (VMR) variedfrom below the detection limit at the highest altitudes to about 7 nmol/molin the planetary boundary layer shortly before sunset. Correlations betweenisoprene and its product compounds were made for different times of day andaltitudes, with the isoprene-hydroperoxides showing the highest correlation.Model calculated mixing ratios of the isoprene oxidation products using adetailed hydrocarbon oxidation mechanism, as well as the intercomparisonmeasurement with air samples collected during the flights in canisters andlater analysed with a GC-FID, showed good agreement with the PTR-MSmeasurements, in particular at the higher mixing ratios.Low OH concentrations in the range of 1–3 × 10⁵molecules cm^-3 averaged over 24 hours were calculated due to lossof OH and HO₂ in the isoprene oxidation chain, thereby stronglyenhancing the lifetime of gases in the forest boundary layer.     

潍北凹陷中新生代层序地层的沉积模式

潍北凹陷是受郯庐断裂带直接控制而发育起来的一个小型中新生代富含油气沉积盆地。根据财震反射界面特征，在凹陷孔店组和沙四段（沙河街组四段）内鉴别出6个地震层序界面，进而划分为5个三级层序。在分析初始湖泛面和最大湖泛面的基础上，对层序内体系域和沉积特征进行了划分与分析。盆地沉积演化可划分为开裂期，早期沉降，再沉降，早期萎缩和晚期沉降五个阶段，并对凹陷内两种层地层的沉积模式进行了总结。     

Development of garnet porphyroblasts by multiple nucleation,coalescence and boundary misorientation‐driven rotations

Two types of garnet porphyroblast occur in the Schneeberg Complex of the Italian Alps. Type 1 porphyroblasts form ellipsoidal pods with a centre consisting of unstrained quartz, decussate mica and small garnet grains, and a margin containing large garnet grains. Orientation contrast imaging using the scanning electron microscope shows that the larger marginal garnet grains comprise a number of orientation subdomains. Individual garnet grains without subdomains are small (< 50 µm), faceted and idioblastic, and have simple zoning profiles with Ca‐rich cores and Ca‐poor rims. Subdomains of larger garnet grains are similar in size to the individual, small garnet grains. Type 2 porphyroblasts comprise only ellipsoidal garnet, with small subdomains in the centre and larger subdomains at the margin. Each subdomain has its own Ca high, Ca dropping towards subdomain boundaries. Garnet grains, with or without subdomains, all have the same Ca‐poor composition at rims in contact with other minerals. The compositional zonation patterns are best explained by simultaneous, multiple nucleation, followed by growth and amalgamation of individual garnet grains. The range of individual garnet and garnet subdomain sizes can be explained by a faster growth rate at the porphyroblast margin than in the centre. The difference between Type 1 and Type 2 porphyroblasts is probably related to the growth rate differential across the porphyroblast. Electron backscatter diffraction shows that small, individual garnet grains are randomly oriented. Large marginal garnet grains and subdomain‐bearing garnet grains have a strong preferred orientation, clustering around a single garnet orientation. Misorientations across subdomain boundaries are small and misorientation axes are randomly oriented with respect to crystallographic orientations. The only explanation that fits the observational data is that individual garnet grains rotated towards coincident orientations once they came into contact with each other. This process was driven by the reduction of subdomain boundary energy associated with misorientation loss. Rotation of garnet grains was accommodated by diffusion in the subdomain boundary and diffusional creep and rigid body rotation of other minerals (quartz and mica) around the garnet. An analytical model, in which the kinetics of garnet rotation are controlled by the rheology of surrounding quartz, suggests that, at the conditions of metamorphism, the rotation required to give a strong preferred orientation can occur on a similar time‐scale to that of porphyroblast growth.     

地球内部压力变化及其构造意义

地球内部的压力远比人们预想的要高得多，地心处的压强为无穷大，在重力分异过程中，地壳地幔减压膨胀（吸热），地核增压收缩（放热），核幔边界是热交换界面，热幔 核幔边界生成。     

GPS测量研究板块边界的地壳运动和变形

近些年来，ＧＰＳ（全球定位系统）测量取得的进展是其测量精度已可与ＶＬＢＩ及ＳＬＲ相媲美，由于这样的发展及ＧＰＳ具有使用方便经济的特点，作为强有力的工具而被用于研究全球大地测量学及地球动力学，ＧＰＳ测量监测全球板块运动，监视海平面上升，建立地球（参考）框架等等。     

Experiments with Higdon's absorbing boundary conditions for a number of wave equations

Simulation of wave propagation for seismic purposes is usually restricted to a small portion of the earth. Artificial boundary conditions are required where the subsurface model is truncated. Absorbing boundaries should ensure that waves hitting the artificial boundaries are not reflected. The vast amount of literature on the subject suggests that “good” conditions have not been found, and only “reasonable” solutions exist. A cursory overview of existing and a few new ideas is presented that may guide the construction of suitable boundary conditions. Because the intended application of the boundary conditions was a high-order finite-difference code that runs on a parallel computer, we have restricted our attention to local boundary conditions. A fundamental problem in the design of accurate local boundary conditions is pointed out: accuracy is required to keep the amount of reflected energy small, but at the same time allows for growing low-frequency modes. We have settled for Higdon’s boundary conditions. Higdon proposes to include some damping to suppress the growing low-frequency modes. We show that third-order conditions provide acceptable results for the simple scalar wave equation and the acoustic equation. In the elastic case, an additional low-frequency growing mode may occur. This mode can be suppressed by using a dissipative boundary scheme and by increasing the amount of damping. The increase in damping results in an increase in the amount of reflected energy, which is larger than in the scalar case. Numerical experiments exhibit a reasonable performance, although some improvement would be useful, particularly in the anisotropic elastic case. This revised version was published online in July 2006 with corrections to the Cover Date.