浙江东钱湖底泥污染物分布特征与评价

对东钱湖底泥做了全面调查,测定了底泥粒度组成、有机质、TN、TP及重金属含量,分析了底泥沉积特性及污染物分布特征,分别采用潜在生态危害指数(RI)法和相对背景值法对重金属污染风险和有机污染及营养盐污染进行了评价.研究结果表明:东钱湖底泥组成以细颗粒为主,重金属含量除镉污染达到中等生态危害程度外,其余均处于较低水平,湖区底泥中有机污染和氮污染问题非常突出.为有效治理东钱湖内源污染,有必要开展包括生态疏浚在内的内源污染治理措施.研究为进一步开展东钱湖水环境治理提供了理论依据.     

中国东部平原土壤生态地球化学基准值

土壤生态地球化学基准值是衡量和评价由人为扰动产生的微观地球化学效应的参比基准。在区域生态地球化学调查、评价以及环境地球化学研究等工作中均具有重要意义。笔者以中国东部平原区的土壤为研究对象．采用切实可行的试验研究方法，提出了土壤生态地球化学基准值，并提供了相应基准值的土壤物质组成信息。进一步研究结果表明，土壤物质组成特性在宏观上控制了基准值的区域性分布特征。     

2016年3月12日运城MS4.4地震地磁谐波振幅比异常分析

利用山西省临汾地磁台记录的数字化FHD分钟值数据,采用地磁谐波振幅比方法,分析2016年3月12日山西运城M_S 4.4地震前后地磁异常数据。结果显示：2015年1月—2016年2月,在周期10—60 min内,Y_ZHx和Y_ZHy方向出现反向异常变化,Y_ZHx和Y_HxHy出现准同步的“下降—转折—恢复”过程;运城M_S 4.4地震前,Y_ZHx和Y_HxHy处于由高转低再上升的转折点,震前异常持续时间约1年3个月。结合山西南部地区GPS基线时间序列、重力场和临汾地震台地电阻率变化,根据震磁机理和电磁感应理论等,更好地解释了临汾地磁谐波振幅比异常。     

承德伊逊河钒钛磁铁矿小流域土壤重金属地球化学基线及生态风险累积效应

以承德市伊逊河红旗钒钛磁铁矿小流域为例,通过参比元素标准化法、垂向剖面似背景值法确定小流域矿集区土壤12种重金属的地球化学基线,并与不同空间尺度流域的重金属地球化学基线进行对比;采用确定的基线值结合地累积指数法、地统计学、生态风险指数法和GIS叠加法对流域土壤重金属潜在生态风险和累积程度进行了评价。结果表明:钒钛磁铁矿矿致异常元素地球化学基线值具有明显的流域尺度效应,其值随着流域空间尺度的缩小而升高;在已开采矿集区小流域土壤重金属污染生态风险评价时,可选取其上一级流域地球化学基线值作为标准。伊逊河红旗矿集区小流域V、Ti、Co、Ni和Cr元素基线值高于滦河流域,As、Pb、Zn和Cd元素基线值与滦河流域相近,Mn和Hg元素基线值略低于滦河流域,Cu元素基线值略高于滦河流域。表层土壤重金属污染累积程度由强至弱为:Cu>Cr>Ti>Cd>Co>V>Ni>Zn>As>Hg>Mn>Pb;表层土壤重金属综合潜在生态风险指数RI范围为65.89～237.70,总体生态风险水平属低风险水平。深层土壤重金属总体污染累积程度和综合潜在生态...     

THE ESTIMATION OF VARIANCE AND COVARIANCE COMPONENTS FOR GPS BASELINE NETWORK BY MINQUE METHOD

This paper studies the estimation of variance and covariance compo-nents for GPS baseline network by MINQUE method.The fundamental rule forselecting variance-covariance model has been presented,and the alternative algo-rithm which simultaneouly estimates fixed variance components and scalled vari-ance components of the distance,azimuth and geodetic height difference for a GPSbaseline vector has been developed.     

Identification of Regional Sources of Methyl Bromide and Methyl Iodide from AGAGE Observations at Cape Grim,Tasmania

There are large uncertainties in identifying and quantifying the globally significant sources and sinks of methyl bromide (CH₃Br) and methyl iodide (CH₃I). Long-term, quasi-continuous observations can provide valuable information about their regional sources, which may be significant in the global context. We report 3 years of in situobservations of these trace gases from the AGAGE (Advanced Global Atmospheric Gas Experiment) program at Cape Grim, Tasmania (41 °S, 145 °E). The average background levels of CH₃Br and CH₃I during March 1998–March 2001 were 8.05 and 1.39 ppt (dry air mole fractions expressed in parts per 10¹²), respectively. The CH₃Br background data showed little seasonal variability. Trajectory analyses reveal that air masses showing elevated CH₃Br levels at Cape Grim have had significant contact with coastal-terrestrial and/or coastal-seawater and/or urban source regions. The CH₃I background data showed a seasonal cycle with a 3-year average amplitude of 0.47 ppt and maximum concentrations in summer, suggesting that the Southern Ocean is a significant source.Trajectory analyses reveal that air masses showing highly elevated CH₃I levels at Cape Grim have had significant contact with coastal-terrestrial and/or coastal-seawater regions and/or the open-ocean regions of Bass Strait and the Tasman Sea.     

Intercalibration of benthic flux chambers I. Accuracy of flux measurements and influence of chamber hydrodynamics

The hydrodynamic properties and the capability to measure sediment-water solute fluxes, at assumed steady state conditions, were compared for three radically different benthic chamber designs: the “Microcosm”, the “Mississippi” and the “Göteborg” chambers. The hydrodynamic properties were characterized by mounting a PVC bottom in each chamber and measuring mixing time, diffusive boundary layer thickness (DBL thickness) shear velocity (u∗), and total pressure created by the water mixing. The Microcosm had the most even distribution of DBL thickness and u∗, but the highest differential pressure at high water mixing rates. The Mississippi chamber had low differential pressures at high u∗. The Göteborg chamber was in between the two others regarding these properties. DBL thickness and u∗ were found to correlate according to the following empirical formula: DBL=76.18(u∗)−0.933. Multiple flux incubations with replicates of each of the chamber types were carried out on homogenized, macrofauna-free sediments in four tanks. The degree of homogeneity was determined by calculating solute fluxes (of oxygen, silicate, phosphate and ammonium) from porewater profiles and by sampling for porosity, organic carbon and meiofauna. All these results, except meiofauna, indicated that there were no significant horizontal variations within the sediment in any of the parallel incubation experiments. The statistical evaluations also suggested that the occasional variations in meiofauna abundance did not have any influence on the measured solute fluxes. Forty-three microelectrode profiles of oxygen in the DBL and porewater were evaluated with four different procedures to calculate diffusive fluxes. The procedure presented by Berg, Risgaard-Petersen and Rysgaard, 1989 [Limnol. Oceanogr. 43, 1500] was found to be superior because of its ability to fit measured profiles accurately, and because it takes into consideration vertical zonation with different oxygen consumption rates in the sediment. During the flux incubations, the mixing in the chambers was replicated ranging from slow mixing to just noticeable sediment resuspension. In the “hydrodynamic characterizations” these mixing rates corresponded to average DBL thickness from 120 to 550 μm, to u∗ from 0.12 to 0.68 cm/s, and to differential pressures from 0-3 Pa. Although not directly transferable, since the incubations were done on a “real” sediment with a rougher surface while in the characterizations a PVC plate simulated the sediments surface, these data give ideas about the prevailing hydrodynamic condition in the chambers during the incubations. The variations in water mixing did not generate statistically significant differences between the chamber types for any of the measured fluxes of oxygen or nutrients. Consequently it can be concluded that, for these non-permeable sediments and so long as appropriate water mixing (within the ranges given above) is maintained, the type of stirring mechanism and chamber design used were not critical for the magnitude of the measured fluxes. The average measured oxygen flux was 11.2 ± 2.7 (from 40 incubations), while the diffusive flux calculated (from 43 profiles using the Berg et al., 1989 [Limnol. Oceanogr. 43, 1500] procedure) was 11.1 ± 3.0 mmol m⁻² day⁻¹. This strongly suggests that accurate oxygen flux measurements were obtained with the three types of benthic chambers used and that the oxygen uptake is diffusive.     

Monitoring moored instrument motion by optimal estimation

Many oceanographic applications require the positioning of the underwater sensor at measurement times. We consider here the case of subsurface moored tomographic instruments, where the distance between source and receiver must be known within a few meters. For that purpose, a long baseline array is deployed: this system includes a navigator, attached to the mooring element and an array of three transponders set on the ocean bottom. To process the navigation data collected with such system, we have developed a method based on optimal estimation. The triangulation problem is not a basic spherical constraints one and the specificity of deep underwater positioning, related to the variability of the ocean sound speed profile are pointed out. Correcting terms are proposed and introduced into the system. Simultaneous inversion of all data, defining an overconstrained problem allows to estimate biases and errors. The algorithm is applied here to a dataset collected in the Azores-Canary basin during CAMBIOS experiment.     

GPS导航的技术改进

在完善ＧＰＳ导航方式的过程中，引入重要目标点的概念，并以此为思想指导，修改原导航程序，使之多个目标点明确、直观地显示于驾驶台及船上各实验室的计算机显示屏幕上。从而提高船舶停靠站位的精度，并使船舶停靠原站位具可重复性。这样，满足了海上地质勘测和石油化探中多点间歇采样的需要，同时，亦提高了工作效率并有利于船舶航行安全。     

GNSS测站速度估计模型重建

获取准确的GNSS测站速度对于研究全球板块运动、地壳形变、地震活动及其地球动力学过程至关重要。为此,以GNSS基线解算后的基线向量作为观测值,重建了最小二乘综合速度解算模型和卡尔曼滤波速度估计模型。模型中,考虑了测站坐标、运动速度、年、半年周期项一同作为参数,在基线解网平差的同时,一并求解获取速度估值。同时,利用坐标时序分析的方法,顾及白噪声和幂律噪声的影响,对单日解坐标时间序列重建了时序速度拟合估计模型,以获取长期趋势项作为速度值。基于3种模型,对川滇地区中国地壳运动观测网络2010—2014年21个GPS基准站的观测数据进行了速度估计与对比分析。结果表明:3种模型所估计测站速度非常接近,差异基本处于0~1mm/a范围之内;速度估值中误差均在亚毫米水平。由此得出,3种速度估计模型具有本质的一致性,均可正确估计测站运动速度,能够满足高精度地壳形变研究的需要。