Reanalysis of the Atmospheric Flux of Nutrient Elements to the Southern Yellow Sea and the East China Sea

Based on the recent research results on dry and wet deposition of nutrient elements and sulphate,we estimate the atmospheric flux of nutrient elements and sulphate to the southern Yellow Sea and the East China Sea in each season.The results suggest that the concentrations of nutrient elements and sulphate in aerosol and precipitation show an apparent seasonal cycle with the maximum values in winter and the minimum values in summer.Depositions of nitrate and sulphate are dominated by wet deposition,while the deposition for phosphate is mainly dry deposition.Moreover,compared with the riverine inputs,the atmospheric deposition may be the main source of dissolved inorganic nutrients in the southern Yellow Sea and the East China Sea.     

Metal binding by humic acids in recent sediments from the SW Iberian coastal area

The concentrations of Cu, Zn, Cr, Ni, Pb, As, Mn and Co were determined by Inductively Coupled Plasma–Mass Spectrometry both in recent sediments from different locations of the Huelva littoral (SW Iberian Peninsula) and in their humic acid (HA) fractions in order to evaluate distribution and binding capacity of those trace elements to HAs. In addition, elemental composition (C, N, S) and δ¹³C values were determined to appraise the sources of organic matter in the area. This study involved the comparison of selected samples taken from different environments including the estuary of the Guadiana River, the main fluvial system of the region, the Tinto and Odiel estuary system and the proximal shelf. Significant positive correlations were found among Cu, Zn, As and Pb in bulk sediments, suggesting a common origin of all of those elements: the mining activities and pyrite deposits located hinterland. On the other hand, results for Cr, Co and Ni pointed to the basic rocks from the low basin of the Guadiana River as their main source. Elemental (C, N) and isotopic (δ¹³C) composition of sediments indicated a significant contribution of autochthonous plankton in coastal shelf sediments, whereas estuarine and riverine sediments showed a major contribution of terrestrial biomass. Geochemical values for their corresponding HAs suggested a greater terrestrial contribution in the sedimentary OM of the coastal shelf sediments than in bulk sediments, which evidenced the influence of coastal currents and sediment fluxes. Humic acids sequester considerable amounts of Cu and Zn contributing to reduce the bioavailability of these contaminants.     

卫星轨道预报的一种分析方法

人造地球卫星的轨道预报是空间环境监测和实时跟踪测量中一个重要环节，由于监测对象众多，要求精度也不太高，通常采用分析法预报．在已有分析法得到t时刻平均根数的基础上给出一种轨道预报方法，由t时刻的平均根数给出该时刻卫星的位置和速度，在此基础上将地球非球形引力摄动的周期项直接用卫星直角坐标的位置和速度分量表示，这样可以避免在计算轨道根数变化的周期项时出现的奇点问题，从而对根数的选择无特殊要求，可适用于各种轨道，简化预报程序和相应的软件，提高预报效率。     

Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary

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Random wave-current interactions in water of varying depth

Refraction of incoherent random gravity waves with currents and bottom topography results in spatial variations in the spectral characteristics of the free surface. Prediction of such variations based on the radiation transfer equation is in a simple analytic form for the case of one dimensional inhomogeneities in currents and topography. This analytic form is examined in terms of two-dimensional wave number- and polar frequency-direction spectra along the associated dynamic and kinematic constraints relevant to wave breaking and reflection. Results are specialized to the simplest case of horizontal shear currents in deep and shallow water with explicit examples to illustrate the relative and combined effects of currents and topography on free surface spectra.     

湖相介形类壳体微量元素在古环境重建中的应用

湖相介形类壳体微量元素（本文主要指Mg和Sr）是重建古环境的重要指标之一,可以定性或定量地反映湖水信息。自20世纪80年开始应用以来,经过30余年的发展取得了很大进展。在古环境重建过程中主要存在两类影响因素：（1）其宿生水体中M/Ca比值（M主要指Mg和Sr）的影响因素：季节变化、微环境差异和湖泊演化过程,这类因素通过对宿生水体中M/Ca比值来影响介形虫壳体中的M/Ca比值,进而造成古环境重建结果的误差增大或可靠性降低;（2）介形类壳体微量元素分配系数的影响因素：宿生水体中M/Ca比值、温度、碱度等,这类因素能够直接影响介形类壳体分泌、钙化的生命-化学过程的因素,是定量重建的重要影响因素。加强现代介形类生活习性和微量元素组成变化过程的研究可以消除或减小以上影响因素对古环境重建的影响,提高介形类壳体化石中微量元素组成在古环境重建研究中的精度和可靠性。     

Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.     

2004–2005 Analytical Developments in Secondary Ion Mass Spectrometry

This review of the literature from 2004 and 2005 concerning secondary ion mass spectrometry (SIMS) highlights the contribution the technique has made in the fields of petrology, geochronology, cosmochemistry and material sciences. In petrology, much research was devoted to the measurement of stable isotopes and trace elements by developments in multicollection acquisition, with emphasis on low atomic mass number elements. Elements studied in particular were S (in sulfides), O (in garnets), C (in sedimentary organic matter), Cl (in glasses) and Si. Novel applications of SIMS to geochronology have included the measurement of young zircon grains by the U-Pb and U-Th decay methods. An increasing number of studies have combined U-Pb geochronology with the measurement of trace elements or stable isotopes in zircon.     

无锡马山抽水蓄能电站地面厂房边坡稳定性分析

以无锡马山抽水蓄能电站地面厂房建筑过程中形成的人工边坡为例,在对其工程地质剖面分析并找出可能的滑动模式后,利用极限平衡法和有限元法分析了4个典型地质剖面的稳定性安全系数以及应力应变关系。结果表明,通过对该边坡的极限平衡法得到了2-2剖面的安全系数和通过有限元法得到的计算结果比较接近,且都满足相关规范的要求;坡体的最大位移发生在高程为－20 m和－5.0 m附近,其值为－22 mm;最大主应力位于高程－45.0 m处,值为0.134 MPa;最小主应力位于坡内深处,其值为－6.22 MPa。同时,提出了下一阶段应考虑时间效应,对边坡的变形进行分析。     

不同氧化还原条件下铅锌矿尾砂中重金属元素活化迁移规律

以广西大厂镇鲁塘铅锌矿尾砂为研究对象,通过淋滤实验研究了不同氧化还原条件下尾砂中Cu、Cd、Zn、Pb和As等元素的活化和迁移规律。结果表明：经高浓度氧化、高浓度还原条件处理的尾矿表现为pH<7的酸性环境,经低浓度氧化环境条件处理的尾砂呈现pH>7的弱酸性至弱碱性环境;尾砂中Cu、Cd元素活化迁移受pH值的影响明显,即高浓度还原和高浓度氧化条件可以促进Cu和Cd元素的迁移,酸性条件对Cu和Cd元素的迁移起到促进作用;Zn与Cd元素存在竞争吸附关系,但二者仍有明显差别;Pb和As元素受到还原条件的影响,能有效促进Pb和As元素的释放迁移。在淋滤实验前期,铅锌矿的表面阻力较小,由于环境酸碱性的改变,初始尾砂对重金属元素的吸附位能发生变化,重金属元素初期迁移能力得到加强;淋滤后期,矿物颗粒表面由于发生氧化还原反应,促使颗粒表面的阻力增加,重金属元素的溶出量减少,迁移能力受到抑制。