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161.
不同超富集、富集植物-玉米间作模式对玉米中镉吸收、转运的影响研究 总被引:1,自引:0,他引:1
为了研究Cd污染条件下,玉米分别与苋菜、黑麦草、龙葵间作对重金属Cd吸收和转运的特点,从而选择适宜与玉米间作的富集植物,同时达到修复重金属Cd污染土壤的目的。该文以镉(Cd)污染的河南棕壤黏土为供试土壤,通过盆栽试验,基于玉米各器官中Cd含量、富集系数、转运系数、土壤有效态Cd含量的变化,研究了间作苋菜、黑麦草、龙葵对玉米各器官Cd的积累特性的影响及其迁移转运机制。结果表明:(1)龙葵、苋菜、黑麦草间作使得玉米地上部Cd含量显著性降低(P<0.05),其中以籽粒中Cd含量的下降最为显著。间作苋菜、黑麦草、龙葵,玉米籽粒中Cd含量分别下降了67.6%、75.7%和79.9%。(2)间作苋菜、黑麦草、龙葵使得玉米的富集系数较单作处理下玉米的富集系数分别下降了49.3%、39.7%和68.5%,且差异达到显著水平。(3)与苋菜、黑麦草间作相比,间作龙葵的玉米转运系数分别下降了27.5%、24.2%,且差异均达到显著水平。通过对人体每天摄入Cd量的安全值计算得出间作后土壤中Cd全量应低于2.26 mg·kg-1,土壤有效态Cd含量低于0.88 mg·kg-1。该污染农田在间作模式下,食用玉米Cd暴露对居民健康不存在风险。间作苋菜、黑麦草、龙葵能够抑制玉米对Cd的吸收,同时阻控玉米地上部Cd向地上部的转移,尤其是向籽粒转移。通过间作苋菜、黑麦草、龙葵,不仅降低了主栽作物玉米的Cd累积量,实现玉米安全、优质种植,同时也达到了修复污染土壤的目的。 相似文献
162.
卷积完全匹配层(convolution perfectly matched layer,CPML)吸收边界是一种高效处理波动方程数值模拟中人工边界反射波的方法。本文基于传统的一阶系统CPML吸收边界条件推广并推导了新的二阶系统CPML边界条件(NCPML)。与常规二阶系统CPML边界条件不同,新边界条件推导的核心思想是在复数-频率域中忽略部分衰减因子空间变化特性,避免其在时间域产生复杂卷积算子,然后反变换至时间域得到基于CPML吸收条件的二阶标量波方程,并应用于二阶标量波方程数值模拟。均匀介质模型测试验证了NCPML吸收条件在内存使用上相对于常规二阶系统CPML与SPML(split PML)吸收条件更少。在对人工边界反射的吸收效果上,NCPML稍逊色于常规二阶系统CPML,但二者均相对于SPML优势明显。最后通过层状模型和Marmousi模型测试验证了NCPML的稳定性及其在效率上的优势。 相似文献
163.
Laštovička Jan Burešová Dalia Boška Josef Bremer Jurgen Märcz Ferenc 《Studia Geophysica et Geodaetica》1997,41(2):171-180
Data from four A3 radio wave circuits in central Europe are used to analyse the representativeness of the ionization and gravity wave activity pattern in the lower ionosphere (85 – 100 km) in the CRISTA experiment interval (3 – 12 November 1994) for the given conditions. It has been found that the CRISTA experiment interval was run under conditions, which are highly representative both of October – November 1994 and autumn, low-moderate solar activity, the descending phase of solar cycle conditions, i.e. CRISTA measurements may be considered to provide values identical with, or close to climatological values (at least for central Europe, h = 85 – 100 km). 相似文献
164.
Dehydration experiments on natural omphacites: qualitative and quantitative characterization by various spectroscopic methods 总被引:1,自引:0,他引:1
M. Koch-Müller I. Abs-Wurmbach D. Rhede V. Kahlenberg S. Matsyuk 《Physics and Chemistry of Minerals》2007,34(9):663-678
A series of natural omphacites from a wide range of P, T occurrences were investigated by electron microprobe (EMP), infrared (IR)-, Mössbauer (MS)- and optical spectroscopy in the UV/VIS spectral range (UV/VIS), secondary ion mass spectrometry (SIMS) and single crystal structure refinement by X-ray diffraction (XRD) to study the influence of hydrogen loss on valence state and site occupancies of iron. In accordance with literature data we found Fe2+ at M1 as well as at M2, and in a first approach assigned Fe3+ to M1, as indicated by MS and XRD results. Hydrogen content of three of our omphacite samples were measured by SIMS. In combination with IR spectroscopy we determined an absorption coefficient: ε i,tot = 65,000 ± 3,000 lmolH2O ?1 cm?2. Using this new ε i,tot value, we obtained water concentrations ranging from 60 to 700 ppm H2O (by weight). Hydrogen loss was simulated by stepwise heating the most water rich samples in air up to 800°C. After heat treatment the samples were analyzed again by IR, MS, UV/VIS, and XRD. Depending on the type of the OH defect, the grade of dehydration with increasing temperature is significantly different. In samples relatively poor in Fe3+ (<0.1 Fe3+ pfu), hydrogen associated with vacancies at M2 (OH bands around 3,450 cm?1) starts to leave the structure at about 550°C and is completely gone at 780°C. Hydrogen associated with Al3+ at the tetrahedral site (OH bands around 3,525 cm?1, Koch-Müller et al., Am Mineral, 89:921–931, 2004) remains completely unaffected by heat treatment up to 700°C. But all hydrogen vanished at about 775°C. However, this is different for a more Fe3+-rich sample (0.2 Fe3+ pfu). Its IR spectrum is characterized by a very intense OH band at 3,515 cm?1 plus shoulder at 3,450 cm?1. We assign this intense high-energy band to vibrations of an OH dipole associated with Fe3+ at M1 and a vacancy either at M1 or M2. OH release during heating is positively correlated with decrease in Fe2+ and combined with increase in Fe3+. That dehydration is correlated with oxidation of Fe2+ is indirectly confirmed by annealing of one sample in a gas mixing furnace at 700°C under reducing conditions keeping almost constant OH? content and giving no indication of Fe2+-oxidation. Obtained data indicate that in samples with a relatively high concentration of Fe2+ at M2 and low-water concentrations, i.e., at a ratio of Fe2+ M2/H > 10 dehydration occurs by iron oxidation of Fe2+ exclusively at the M2 site following the reaction: \( {\left[ {{\text{Fe}}^{{{\text{2 + [ M2]}}}}{\text{OH}}^{ - } } \right]} = {\left[ {{\text{Fe}}^{{{\text{3 + [ M2]}}}} {\text{O}}^{{{\text{2}} - }} } \right]} + {\text{1/2}}\;{\text{H}}_{{\text{2}}} \uparrow . \) In samples having relatively low concentration of Fe2+ at M2 but high-water concentrations, i.e., ratio of Fe2+ M2/H < 5.0 dehydration occurs through oxidation of Fe2+ at M1. 相似文献
165.
166.
167.
Chlorophyll-specific absorption coefficients and pigments of phytoplankton off Sanriku, northwestern North Pacific 总被引:4,自引:0,他引:4
Koji Suzuki Motoaki Kishino Kousei Sasaoka Sei-Ichi Saitoh Toshiro Saino 《Journal of Oceanography》1998,54(5):517-526
The variety in shape and magnitude of thein vivo chlorophyll-specific absorption spectra of phytoplankton was investigated in relation to differences in pigment composition
off Sanriku, northwestern North Pacific. Site-to-site variations of the absorption coefficients,a
ph
* (λ), and pigment composition were clearly observed. At warm-streamer stations, higher values ofa
ph
* (440) anda
ph
* (650) were found with relatively high concentrations of chlorophyllb (a green algae marker). At stations located in the Oyashio water (cold streamer),a
ph
* (440) values were lower and fucoxanthin (a diatom marker) concentrations were higher, compared to the other stations. The
peak in the absorption spectra at the Oyashio stations was shifted toward shorter wavelengths, which was probably due to the
presence of phaeopigments. In a Kuroshio warm-core ring, the magnitude ofa
ph
* (440) was in between those at the warm-streamer and Oyashio stations, and the diagnostic pigment was peridinin (a dinoflagellate
marker). These findings indicated that major differences in phytoplankton absorption spectra of each water mass were a result
of differences in the phytoplankton pigment composition of each water mass, which was probably related to the phytoplankton
community. 相似文献
168.
169.
170.
本研究利用吸收光谱和荧光激发-发射矩阵光谱-平行因子分析(EEMs-PARAFAC),研究了养马岛附近海域海水中有色溶解有机质(CDOM)的浓度、组成、来源和生物可利用性,并估算了浮游植物生长繁殖对CDOM及具有生物可利用性CDOM的贡献。结果表明,表、底层海水中CDOM浓度(以吸收系数a350计)平均值分别为1.62±0.42 m-1和1.30±0.47 m-1,光谱斜率(S275-295)平均值分别为0.022±0.003 nm-1和0.023±0.003 nm-1。利用PARAFAC模型识别出4种荧光组分,分别为陆源类腐殖酸C1、类色氨酸C2、类酪氨酸C3和微生物源类腐殖酸C4。荧光指数(FIX)、腐殖化指数(HIX)和生物指数(BIX)显示,CDOM受陆源输入和海洋自生源的综合影响。降解实验结果显示,表、底层海水中生物可利用性CDOM百分比(%△a350)平均值分别为(23.36%±17.94%)和(8.93%±20.30%)。C1、C2和C4组分的荧光强度在培养之后降低,而C3组分的荧光强度上升。各荧光组分生物可利用性依次递减的顺序为:%△C1(23.75%±8.96%)>%△C4(20.83%±11.71%)>%△C2(11.67%±38.87%)>%△C3(-29.61%±39.90%),显示培养之后CDOM的平均分子量和腐殖化程度降低。表层海水中a350、%△a350与Chl a之间存在显著线性相关关系,据此可以估算出浮游植物生长繁殖对CDOM的贡献为36.9%,对具有生物可利用性CDOM的贡献为85.0%。 相似文献