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11.
12.
In a surface water screening, 30 representative surface water samples collected from rivers, canals, and lakes in Berlin were investigated for the presence of 22 substituted phenols. The phenols selected include the 11 phenols considered as “priority pollutants” by the US Environmental Protection Agency (US-EPA). Surface water samples were extracted applying solid-phase extraction with styrenedivinylbenzene adsorbent. The recoveries, determined in spiking experiments, were between 80 % and 103 %. After derivatization with N-(tert-butyldimethylsilyl)-N-methyl-trifluoroacetamide (MTBSTFA) the samples were analyzed by capillary gas chromatography-mass spectrometry (GC-MS). Phenol, cresols, 2-ethylphenol, 2-chlorophenol, 4-chloro-3-methylphenol, pentachlorophenol, 2-nitrophenol, and 4-nitrophenol were detected in the surface water samples at concentrations between 0.02 μg/L and 7.8 μg/L, respectively. The distribution of these residues in the Berlin surface waters showed that the phenolic residues, with the exception of pentachlorophenol and 2-ethylphenol, do not originate primarily from municipal sewage treatment plants discharges. Some of the phenols are formed naturally or occur as ubiquitous anthropogenic contaminants in the aquatic system. 相似文献
13.
普里兹湾及其邻近海域是中国南大洋调查研究的传统优势海域与重点区域。围绕夏季表层水、冬季水、陆架水、绕极深层水、南极底层水、普里兹湾底层水、冰架水等研究海区主要水团的特征和分布,总结了前人在南极普里兹湾及其邻近海域基于调查资料开展的水团研究中所取得的成果。研究表明,前人在对陆架水的示性指标界定上,将陆架水是否区分为高盐陆架水和低盐陆架水存在较大争议,在高盐陆架水和普里兹湾底层水的定义上存在重叠;目前尚没有证据表明绕极深层水向南可以伸展到普里兹湾的陆架区域,也没有发现在普里兹湾附近海域生成南极底层水的直接证据。 相似文献
14.
Two sets of radiosounding measurements, taken at different hours from some stations in the Po Valley area, were examined in order to obtain the values of precipitable waterw and determine the shapes of the vertical distribution curves of absolute humidity. From these curves, we calculated the bestfit values of scale heightsH
1 andH
2 in the 0÷5 km and 5÷10 km altitude intervals, respectively. The analysis of the radiosounding data clearly shows that parametersw andH
1 are closely related to the evolutionary features of the meteorological conditions on synoptic scale and are influenced, to a lesser extent, by the diurnal variations in the atmospheric ground layer. Seasonal average curves of temperature and absolute humidity, as functions of altitude, were also defined from the radiosounding measurements taken at various hours of the day. Moreover, interpolation methods in time (applied to a 12-hour range) and in space (range of about 300 km) were proposed for determining parametersw andH
1 from the radiosounding measurements taken at different hours from the same station or from different stations at the same hour. Reliability tests, made by comparing the same station or from different stations at the same hour. Reliability tests, made by comparing the values given by the interpolation methods with those directly obtained from the radiosounding measurements, show that these evaluations ofw andH
1 are affected by standard errors of estimate, which are comparable to the errors usually made in analyzing the radiosounding data. 相似文献
15.
Analysis of monthly mean river temperatures, recorded on an hourly basis in the middle reaches of the Loire since 1976, allows reconstruction by multiple linear regression of the annual, spring and summer water temperatures from equivalent information on air temperatures and river discharge. Since 1881, the average annual and summer temperatures of the Loire have risen by approximately 0.8?°C, this increase accelerating since the late 1980s due to the rise in air temperature and also to lower discharge rates. In addition, the thermal regime in the Orleans to Blois reach is considerably affected by the inflow of groundwater from the Calcaires de Beauce aquifer, as shown by the summer energy balance. To cite this article: F. Moatar, J. Gailhard, C. R. Geoscience 338 (2006). 相似文献
16.
Wave Energy Converters (WECs) have excellent potential as a source of renewable energy that is yet to be commercially realised. Recent attention has focused on the installation of Oscillating Water Column (OWC) devices as a part of harbor walls to provide advantages of cost–sharing structures and proximity of power generation facilities to existing infrastructure. In this paper, an incompressible three–dimensional CFD model is constructed to simulate a fixed Multi–Chamber OWC (MC–OWC) device. The CFD model is validated; the simulation results are found to be in good agreement with experimental results obtained from a scale physical model tested in a wave tank. The validated CFD model is then used for a benchmark study of 96 numerical tests. These investigate the effects of the PTO damping caused by the power take–off (PTO) system on device performance. The performance is assessed for a range of regular wave heights and periods. The results demonstrate that a PTO system with an intermediate damping can be used for all chambers in the MC–OWC device for most wave period ranges, except for the long wave periods. These require a higher PTO damping. An increased incident wave height reduces the device capture width ratio, but there is a noticeable improvement for long wave periods. 相似文献
17.
Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples. 相似文献
18.
Tidal mixing plays an important role in the modification of dense water masses around the Antarctic continent. In addition to the vertical (diapycnal) mixing in the near-bottom layers, lateral mixing can also be of relevance in some areas. A numerical tide simulation shows that lateral tidal mixing is not uniformly distributed along the shelf break. In particular, strong mixing occurs all along the Ross Sea and Southern Weddell Sea shelf breaks, while other regions (e.g., the western Weddell Sea) are relatively quiet. The latter regions correspond surprisingly well to areas where indications for cross-shelf exchange of dense water masses have been found. The results suggest that lateral tidal mixing may account for the relatively small contribution of Ross Sea dense water masses to Antarctic Bottom Water. 相似文献
19.
《Chemie der Erde / Geochemistry》2021,81(2):125748
Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals. 相似文献
20.
M.J Tucker 《Ocean Engineering》1998,25(6):481-496
The statistics of the horizontal component of the water particle velocity vector under random waves are considered. A spread in the directions of travel of the component wave trains does not affect the rms value of the modulus r but it affects the shape of its probability distribution in such a way that the pr3bability of extreme values is reduced. For small and moderate directional spreads the modulus for a given probability of exceedance is reduced by a factor which tends to Fs as the probability of exceedance tends to zero, where Fs is the spread factor (which is typically 0.9 in temperate storms). However, the convergence on this asymptote is not complete for probabilities of engineering importance, particularly for wide directional spreads. The standard deviation of the probability distribution of the direction of the vector is reduced roughly in inverse proportion to r. The same conclusions apply to particle accelerations. 相似文献