Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

The mid-depth circulation of the northwestern tropical Atlantic observed by floats

A comprehensive analysis of velocity data from subsurface floats in the northwestern tropical Atlantic at two depth layers is presented: one representing the Antarctic Intermediate Water (AAIW, pressure range 600–1050 dbar), the other the upper North Atlantic Deep Water (uNADW, pressure range 1200–2050 dbar). New data from three independent research programs are combined with previously available data to achieve blanket coverage in space for the AAIW layer, while coverage in the uNADW remains more intermittent. Results from the AAIW mainly confirm previous studies on the mean flow, namely the equatorial zonal and the boundary currents, but clarify details on pathways, mostly by virtue of the spatial data coverage that sets float observations apart from e.g. shipborne or mooring observations. Mean transports in each of five zonal equatorial current bands is found to be between 2.7 and 4.5 Sv. Pathways carrying AAIW northward beyond the North Brazil Undercurrent are clearly visible in the mean velocity field, in particular a northward transport of 3.7 Sv across 16°N between the Antilles islands and the Mid-Atlantic Ridge. New maps of Lagrangian eddy kinetic energy and integral time scales are presented to quantify mesoscale activity. For the uNADW, mean flow and mesoscale properties are discussed as data availability allows. Trajectories in the uNADW east of the Lesser Antilles reveal interactions between the Deep Western Boundary Current (DWBC) and the basin interior, which can explain recent hydrographic observations of changes in composition of DWBC water along its southward flow.     

Using δN values in algal tissue to map locations and potential sources of anthropogenic nutrient inputs on the island of Maui, Hawai‘i, USA

Macroalgal blooms of Hypnea musciformis and Ulvafasciata in coastal waters of Maui only occur in areas of substantial anthropogenic nutrient input, sources of which include wastewater effluent via injection wells, leaking cesspools and agricultural fertilizers. Algal δ¹⁵N signatures were used to map anthropogenic nitrogen through coastal surveys (island-wide and fine-scale) and algal deployments along nearshore and offshore gradients. Algal δ¹⁵N values of 9.8‰ and 2.0-3.5‰ in Waiehu and across the north-central coast, respectively, suggest that cesspool and agricultural nitrogen reached the respective adjacent coastlines. Effluent was detected in areas proximal to the Wastewater Reclamation Facilities (WWRF) operating Class V injection wells in Lahaina, Kihei and Kahului through elevated algal δ¹⁵N values (17.8-50.1‰). From 1997 to 2008, the three WWRFs injected an estimated total volume of 193 million cubic meters (51 billion gallons) of effluent with a nitrogen mass of 1.74 million kilograms (3.84 million pounds).     

南水北调中线工程不同调水规模对汉江中下游影响分析

南水北调中线工程是解决我国北方地区水资源紧缺的重大战略措施。但调水将给汉江中下游的水文情势及用水带来一定的影响。文章分析了丹江口水库不同调水方案对汉江中下游水位、流量及灌溉和航运的影响,并提出补偿工程措施。调水６０×１０８ｍ３对汉江中下游的影响较小,可基本不予补偿;调水１５０×１０８ｍ３的影响稍重,但对航运和灌溉用水的影响不大,适当补偿可以解决;调水２３０×１０８ｍ３对汉江中下游水位流量及用水的影响十分严重,必须全部渠化并修建江汉运河。     

Using live vegetation volume to analyze the effects of plot Pinus massoniana Lamb on water and soil conservation under natural rainfall events

The 3-D spatial distributions of vegetation are of great significance for water and soil conservation but are rarely concerned in literatures. The live vegetation volume （LVV） was used to relate to water/soil loss under 144 natural erosive rainfall events from 2007 to 2010 in a typical water-eroded area of southern China. Quadratic polynomial regression models were established for five pure tree （Pinus massoniana Lamb） plots between LVV and water （rtmoff）/soil conservation effects （RE/SE）. RE/SE corresponds to the ratios of runoff depth/soil loss of the pure tree plots to that of the control plot under each rainfall event. Increasing LVV exhibits descending （DS）, descending-ascending （DA）, ascending-descending （AD）, and ascending （AS） trends in the LVV-RE and LVV-SE curves. The effects of soil conservation on the plots were generally more noticeable than the effects of water conservation, and most of the RE and SE values reflected the positive effects of water and soil conservation. The effects were mainly positive under heavy rains （e.g., rainfall erosivity, R = 140 MJ mm ha-l h, maximum 30 min intensity, I30 = 16 mm h-l）, whereas the effects were mainly negative under light rains （e.g., R = 45 MJ mm ha-1 h, I30 = 8 mm h-l）. The trees＇ water/soil conservation effects notably transformed when rainfall erosivity and intensity were lower than the positive or negative effects to a certain threshold. About 50% rainfall events led to obvious transform effects when LVVs were near 0.5 or 0.6. These results are able to aid in the decision making on the forest reconstruction in water-eroded areas.     

Deconstructing the best case scenario: lessons from water politics in La Paz-El Alto, Bolivia

For nearly a decade the La Paz-El Alto concession in Bolivia was heralded by donor organizations, the state and the commercial water industry alike as an emblematic ‘pro-poor’ water concession under the private sector model. Managed by one of the largest water multinationals in the world (the French company Suez), the network was extended beyond the new connections required by the original ‘pro-poor’ contract, acclaimed as a pioneer of new pro-poor technologies and frequently disseminated internationally as an example of best practice. This paper analyses the La Paz-El Alto concession’s pro-poor image focusing on issues of social exclusion and network extension, contract negotiation, participation and transparency. It documents the rise of social protest about the concession and critiques the failure of neoliberal regulatory systems to promote accountability to the poor. In the context of the continued transnationalisation of the water industry the paper highlights the need for new mechanisms and delivery models to ensure greater national control over private companies and the development of a framework for international water governance.     

Water pollution in gold mining industry: a case study in Roşia Montană district, Romania

The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd, Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004, November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L; for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample of drinking water from the mining district was also collected.     

Remotely sensed assessment of water quality levels in the Pearl River Estuary, China

In this paper, a method of assessing water quality from satellite data is introduced. The composite pollution index (CPI) was calculated from measured chemical oxygen demand (COD) and nutrient concentration. The relationships between CPI and 240 band combinations of SeaWiFS water-leaving radiance were analyzed and the optimal band combination for estimating CPI was chosen from the 240 band combinations. An algorithm for retrieval of CPI was developed using the optimal band combination, (L₄₄₃ × L₅₁₀)/(L₄₁₂ + L₄₉₀). The CPI was estimated from atmospherically corrected SeaWiFS data by employing the algorithm. Furthermore, the CPI value range for each water quality level was determined based on data obtained from 850 samples taken in the Pearl River Estuary. The remotely sensed CPIs were then transferred to water quality levels and appropriate maps were derived. The remotely sensed water quality level maps displayed a similar distribution of levels based on in situ investigation issued by the State Ocean Administration, China. This study demonstrates that remote sensing can play an important role in water quality assessment.     

Vertical distribution of dissolved organic carbon (DOC) in the Western Mediterranean Sea in relation to the hydrological characteristics

Vertical profiles of dissolved organic carbon (DOC) from eight hydrological stations in the Tyrrhenian Sea, Sardinia Channel and Algerian Sea, are reported. DOC exhibits concentrations ranging from 58 to 88 μM in surface water, 43–57 μM in the intermediate layer and 49–63 μM in deep waters. The assessment of the hydrological characteristics allows different water masses in the study area to be identified; moreover, different hydrological processes are observed in the Tyrrhenian and Algerian basins. DOC exhibits different values in the different water masses. The lowest DOC concentrations (43–46 μM) were found in the Tyrrhenian Levantine Intermediate Water (LIW). Correlations between DOC and apparent oxygen utilization (AOU), investigated within each water mass, exhibit different behaviors in the intermediate and deep waters, suggesting the occurrence of different processes of oxygen consumption in the different water masses.     

Assessing selected natural and anthropogenic impacts on freshwater lens morphology on small barrier Islands: Dog Island and St. George Island, Florida, USA

Abstract The freshwater lens morphologies of the barrier islands Dog Island and St. George Island on the panhandle coast of Florida (FL), USA, are controlled to varying degrees by both natural and anthropogenic factors. Variable-density groundwater flow models confirm that spatial variability of recharge values can account for the observed lens asymmetry on these islands. The depth to the base of the lens does not vary significantly seasonally. Human development has altered recharge patterns in some areas, locally thinning the freshwater lens. Aqueduct water supply to St. George Island represents 7–25% of natural recharge; higher recharge rates are required to simulate the lens on St. George Island than on Dog Island. On both islands, coastal erosion rates are sufficiently rapid that the freshwater lens may not be in equilibrium with current boundary conditions.

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Resumen Las morfologías de los lentes de agua dulce en las islas de barrera: Islas Dog y St. George, en la costa alargada y estrecha de Florida, EUA, están controladas en diferentes grados por factores antropogénicos y naturales. Los modelos de flujo con densidad variable del agua subterránea, confirman que la variabilidad espacial de los valores de recarga, pueden ser la causa de la asimetría observada en los lentes de estas islas. La profundidad hasta la base de los lentes no varía significativamente con las estaciones climáticas. El desarrollo humano ha alterado las tendencias de recarga en algunas áreas, causando adelgazamiento local de los lentes de agua dulce. El abastecimiento de agua del acueducto en la Isla St. George, representa entre 7% y 25% de la recarga natural; por otro lado se necesitan cantidades mayores de recarga para simular los lentes en la Isla St. George que en la Isla Dog. En ambas islas, las tasas de erosión costera son tan rápidas, que las lentes de agua dulce podrían no estar en equilibrio con las condiciones actuales de frontera.

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Résumé La morphologie des lentilles deau douce des îles de Dog et de St. George, situés dans le district côtier de Florida-Etats Unis est contrôlé dans une mesure variable par des facteurs naturelles et humaines. Les modèles découlement à densité variable des eaux souterraines confirment que la variation spatiale de la recharge peut expliquer les asymétries observées des lentilles des cettes îles. La profondeur des lentilles ne présente pas des variations saisonnières importantes. Les activités humaines ont modifié la recharge dans certaines zones en amincissant localement les lentilles deau douce. Lalimentation en eaux de lîle de St. George représente 7–25% de la recharge naturelle; pour simuler les lentilles de lîle de Dog il a été nécessaire dintroduire des valeurs plus élevées de la recharge par rapport aux ceux utilisés pour lîle de St. George. Pour les deux îles lérosion côtière est assez rapide ainsi que les lentilles de eau douce ne sont pas en équilibre avec les conditions à la frontière.