中原城市群城市引力范围界定及演变格局

通过构建反映城市综合实力的指标体系,运用熵值法对中原城市群30个城市2005,2010,2015年的综合实力分别进行测算与评定,运用基于扩展断裂点模型的加权Voronoi图方法对中原城市群各城市引力范围进行划分并展示了城市间引力界线的变化趋势,揭示了中原城市群30个城市3个年份的城市引力范围时空演变特征和变化规律。结果表明:3个年份,综合实力较高的地区基本分布在中原城市群中部和北部,东南部城市综合实力较弱,排名靠后,呈现出中北高、东南低两极化的发展规律;目前中原城市群城市引力范围格局中,郑州市的引力范围最大,其次是洛阳市、邯郸市,已经形成了以郑州为城市群核心的空间格局;3个年份,中原城市群的城市影响范围演变格局总体较为稳定,局部地区空间吸引范围变化较为明显,中、北部城市发展态势良好,影响范围有向北扩大的趋势;城市引力范围与其综合实力不完全呈正相关关系。     

玄武岩类形成的大地构造环境的Th／Hf—Ta／Hf图解判别

Th,Ta,Hf是一组耐熔强亲岩浆元素，由于地球化学性质的相似性，其相互之间的比值关系能将深部作用的地球化学过程较好地恢复出来，玄武岩类，是原始玄武岩浆形成的岩石的Ta/Hf及Th/Hf比值，能较好地反映其源区的Th,Ta,Hf之间的分异特征，在一般情况下，这一特征与某种确定的大地构造环境有密切关系和确定的因果联系，可用来判别玄武岩类形成的大地构造环境及其源区Th,Ta,Hf分异特征，本文根据典型大地构造环境玄武岩类的Th,Ta,Hf数据，提出了玄武岩类形成的大地构造环境判别的Th/Hf-Ta/Hf双对数图及判别方法。     

锂光卤石X-ray衍射标准图谱

盐湖卤水提锂过程中需了解与掌握锂元素结晶析出与赋存状态,锂光卤石(LiCl·MgCl_2·7H_2O)作为重要的中间产物,其结构与种类均需鉴别,但由于缺乏锂光卤石的X-ray衍射标准图谱,使得常见的Xray衍射方法无法应用。利用相图原理,通过湿固相法制备高纯锂光卤石,然后对其进行X-ray衍射分析,从而提供锂光卤石X-ray衍射的标准图谱,为高镁锂比盐湖卤水提锂过程分析提供可靠的理论支撑。     

Investigation of upper crust anisotropy in Ghaen-Birjand region, east-central Iran

IntroductionWhenpropagatingthroughananisotropicmedium,ashearwavesplitsintotwo(quasi)shearwaveswithdifferentpropagationspeedsandpolarizedorthogonally.Owingtotherecentdevel-opmentofseismicobservationsystem,detectionofshearwavessplittingwithverysmalldelaytimesbetweenfasterandslowershearwavesbecameavailableandprovidedpowerfulapproachfordetectionofcrustalanisotropy.Crampin(1978)emphasizedtheroleofalignedmicrocracksasacauseofcrustalanisotropyandpointedoutthatforverticallyalignedmicrocracksthedirecti…     

干湿循环作用下膨胀土裂隙演化规律试验研究

对南阳膨胀土在反复干湿循环作用下的裂隙演化规律进行了室内试验研究。试验中采用烘干法模拟脱湿过程,采用抽气饱和法模拟饱和过程。在脱湿过程中,定时对土样进行称重、定点拍照,以记录裂隙发育状况。利用矢量图技术对裂隙照片进行矢量化处理,以提取裂隙的各种几何要素,继而进行裂隙度计算。裂隙度变化规律分析结果表明,影响裂隙张开程度的关键因素并非土体含水率,而是含水率梯度,而脱湿速率的空间分布、土块渗透特性以及土块尺寸大小则是决定含水率梯度大小的关键因素;膨胀土裂隙在干湿循环的作用下会逐步发育,主要体现在裂隙总面积与总长度的增加,但此作用有限,裂隙的发育达到一定程度以后便会因为土块尺寸过小而停止;反复干湿循环会使土体产生范性变形,该范性变形与完整土块的胀缩特性并无直接联系,其主要成因是裂隙的发育与土体完整性的破坏,裂隙越发育,土体范性变形量越大     

New stellar and substellar candidate members of the Coma Berenices open star cluster

We present the results of a survey of the open star cluster Melotte 111 in Coma Berenices, undertaken using the USNO‐B1.0 and 2MASS Point Source catalogues. On the basis of their astrometric and photometric properties, we have identified 60 new candidate members with masses in the range 1.007 < M < 0.269 M_⊙. We estimate a membership probability for each by extracting control clusters from the proper motion vector diagram. All 60 are found to have greater than 60 per cent probability of being cluster members, which if they are confirmed as members, more than doubles the number of known cluster members. We also have I and Z photometry for 100 low mass candidate members of the cluster, 13 of which we suggest may be brown dwarfs. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Computing Lippmann Diagrams from Direct Calculation of Mixing Properties of Solid Solutions: Application to the Barite-Celestite System

The Lippmann diagram for the system(Ba, Sr)SO₄-H₂O was computed at 25 °Cby determining the solid-phase activity coefficientsfrom first principles calculations. Directcalculations of the mixing properties of thebarite-celestite series indicate this solid solutionbehaves as non-ideal and non-regular. At 25 °C,the enthalpy of mixing shows a minimum around 50 mole% SrSO₄ due to an ordering tendency. Thefree energy of mixing shows two minima that delimit awide and symmetric miscibility gap (from 2.1 to 97.9 mole% SrSO₄) at this temperature. The excessfree energy of mixing requires a Guggenheim expansionseries of 5 terms to be described, where the termswith odd exponents are null as a consequence of thesymmetric distribution of the mixing properties withcomposition. The Lippmann diagram shows a peritecticpoint that corresponds to the composition of an aqueoussolution which is simultaneously at equilibrium withthe two extremes of the miscibility gap. The largedifference between the solubility products of theendmembers involves a strong preferential partitioningof the less soluble endmember towards the solid phase,which explains the extremely Ba-poor composition ofthe aqueous solution (aqueous activity fraction forBa²⁺ = 0.000446 ) at the peritectic point.     

从岩石化学特点看板溪群的沉积大地构造背景

将板溪群和冷家溪群杂砂岩全岩岩石化学分析结果在SiO_2-K_2O/Na_2O图解、SiO_2/Al_2O_3-K_2O/(Na_2O+CaO)图解、Na_2O-K_2O图解以及(K_2O+Na_2O)—Al_2O_3图解上投点,发现多数板溪群杂砂岩样品点落在被动大陆边缘区,而冷家溪群杂砂岩样品点则多落入活动大陆边缘区。因此认为,板溪群沉积于被动大陆边缘,而冷家溪群沉积于活动大陆边缘,它们形成于不同的地质演化阶段。     

关于A型花岗岩判别过程中若干问题的讨论

自A型花岗岩提出(1979年)30年来,其内涵和外延相对于原始定义而言已发生了很大的变化.主要针对A型花岗岩的各种判别方法(尤其是判别图解)的有效性和局限性进行了讨论.这些判别方法对于A型花岗岩的判定并不总是奏效,所以在实践过程中不能过于依赖判别图解,否则就很容易得出错误的结论.实际上,A型花岗岩最本质的特征很可能在于它是一种高温花岗岩(相时于I型争S型花岗岩),因此较高地温梯度下的各种地球动力学背景均有利于这一类型花岗岩的发育.