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???t??????????ó?????????С????????????????????????????????1????????????????????????2????????????????????????????????????????????Э????????????????1??Э??????????????????????????????????????????????????????????????????????????????????????????????????????????????Ч???     

中国东部气温异常型与海表温度异常模关系的诊断

基于国家气候中心整编的160站常规观测气温资料和HADLEY中心的海表温度资料,应用最大协方差分析方法,诊断了中国东部各季节气温异常型和前期海表温度异常(SSTA)模的关系,并重点分析冬季气温与SSTA模的最佳耦合模态及海温异常对大气环流的影响。结果表明:中国东部四季气温异常型与前期海盆SSTA模的显著耦合关系表现出不同的特征。超前6个月的热带太平洋第二模和南印度洋第二模与东部地区冬季气温一致变化型耦合关系最佳。西南冷东北暖的气温异常型与超前4个月热带大西洋一致增暖模有最佳耦合关系。大气环流对与全区气温一致偏冷型对应的SSTA模的回归表现为:西伯利亚高压和阿留申低压增强,东亚大槽加深,中纬度西风加强。对与气温西南冷东北暖型对应的SSTA模的回归表现为:西伯利亚高压和阿留申低压略有增强,东亚大槽槽区附近位势升高,大槽变浅,槽线偏向西南,东部40°N以北风速加强,以南风速减弱。     

EMD方法在广西夏季降水量预测中的应用

对广西夏季降水量进行EMD分解后,利用均生函数相关法,比较不同IMF分量组合建模的预测,不同组合试验预测显示,用前二个IMF分量组合建模预测是最佳的组合方案。经对2001—2010年共10年广西夏季降水量实际预测检验表明,趋势预测准确率达70%以上,对夏季降水量预测较有参考价值。为基层台站的气候预测及服务提供一个客观预测方法。     

基于三维荧光光谱-平行因子技术联用的浮游藻化学分类学技术研究

An in vivo three-dimensional fluorescence method for the determination of algae community structure was developed by parallel factor analysis(PARAFAC) and CHEMTAX. The PARAFAC model was applied to fluorescence excitation-emission matrix(EEM) of 60 algae species belonging to five divisions and 11 fluorescent components were identified according to the residual sum of squares and specificity of the composition profiles of fluorescent. By the 11 fluorescent components, the algae species at different growth stages were classified correctly at the division level using Bayesian discriminant analysis(BDA). Then the reference fluorescent component ratio matrix was constructed for CHEMTAX, and the EEM–PARAFAC–CHEMTAX method was developed to differentiate algae taxonomic groups. The correct discrimination ratios(CDRs) when the fluorometric method was used for single-species samples were 100% at the division level, except for Bacillariophyta with a CDR of 95.6%. The CDRs for the mixtures were above 94.0% for the dominant algae species and above 87.0% for the subdominant algae species. However, the CDRs of the subdominant algae species were too low to be unreliable when the relative abundance estimated was less than 15.0%. The fluorometric method was tested using the samples from the Jiaozhou Bay and the mesocosm experiments in the Xiaomai Island Bay in August 2007. The discrimination results of the dominant algae groups agreed with microscopy cell counts, as well as the subdominant algae groups of which the estimated relative abundance was above 15.0%. This technique would be of great aid when low-cost and rapid analysis is needed for samples in a large batch. The fluorometric technique has the ability to correctly identify dominant species with proper abundance both in vivo and in situ.     

熔融制样波长色散X射线荧光光谱法测定白云石中钙镁硅铁铝

白云石属碳酸盐矿物,应用熔融制样X射线荧光光谱法测定其中主次量组分钙、镁、硅、铁、铝时,由于白云石灼烧减量大,在试料片制备过程中,如果以干基试料制备试料片,除灼烧减量外还有少量其他组分被分解出的大量CO₂带走,导致试料损失,测定结果偏低;如果以灼烧基试料制备试料片,由于灼烧后的试料极易吸收空气中的水分和CO₂,同样使测定结果偏低。基于质量守恒原理,本文直接以灼烧减量测量后的灼烧基试料质量作为试料量(即灼烧减量测定所称量的干基试料量扣除灼烧减量的量),以四硼酸锂为熔剂,5%碘化铵溶液为脱模剂,试料与熔剂的稀释比为1:10,于1050℃熔融15 min以上制备的试料片透彻、玻璃化程度高。以白云石标准物质和标准样品作为标准试料,制作各组分的标准曲线的相关系数在0.9940~0.9994之间;方法检出限为0.011%~0.48%;标准物质和标准样品的测定值与认定值基本一致,各组分的相对标准偏差(RSD,n=11)在0.5%~1.7%之间,方法具有较好的重现性。本方法以1050℃灼烧后的试样作为试料制备XRF分析样片,最大限度地降低了灼烧减量因素(空气中的水分和CO₂)对测定结果的影响,适用于白云石及其煅烧物中钙、镁、硅、铁、铝等组分的同时测定。     

山东金亭岭金矿矿床地球化学异常分带模型

通过对山东金亭岭金矿各类微量元素和烃类组分在该矿床不同中段的含量变化以及在纵向上的异常展布和富集规律进行分析和总结,建立了该矿床的地球化学叠加异常分带理想模型,得出矿床地球化学异常轴向分带序列确定为:甲烷、乙烷、丙烷、正丁烷、异丁烷、乙烯、丙烯、Sb(前缘晕)→As、Hg(矿头晕)→Au、Ag、Pb、Zn、Cu、Mn(矿中晕)→Co、Ni、Mo、Bi(矿尾晕),并总结了找矿预测标志,为其深部找矿预测提供了一定的科学借鉴依据。     

基于SWH模型的青藏高原高寒草甸蒸散发及其组分变化分析

基于Shuttleworth-Wallace Hu（SWH）双源蒸散模型对青藏高原那曲、纳木错、藏东南站蒸散发进行估算,在结果验证良好基础上,对青藏高原蒸散发变化特征及各站主要影响因素进行了分析。结果表明：SWH模型在青藏高原3个草甸站适用性良好;年蒸散发介于388~732 mm之间,年内分布呈先增大后减小特征;3站蒸散发组分差异较大,那曲站和纳木错站土壤蒸发对蒸散总量的贡献分别为53%和56%,藏东南站蒸散发则几乎全部由植被蒸腾贡献,占比高达95%;植被叶面积指数为3站蒸散发最主要的影响因素,饱和水汽压差对藏东南站蒸散发影响也较大。研究结果可对青藏高原蒸散发及其组分时空格局与水循环过程研究提供科学依据。     

航空矢量重力测量水平分量的带限直接地形影响

基于第二类Helmert凝聚法的级数展开式,独立推导了航空矢量重力测量水平分量带限直接地形影响的计算公式。在中国西部山区选取了两条沿纬圈方向4000m航线高度上的航线,采用 的数字高程模型基于解析核计算了水平分量的直接地形影响,经低通滤波后与基于带限公式计算的地形影响进行了比较。数值计算结果表明,二者吻合较好,本文给出的带限地形影响公式可用于航空矢量重力测量水平分量的地形归算。     

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Simulation of evapotranspiration and carbon dioxide flux in the wheat‐maize rotation croplands of the North China Plain using the Simple Biosphere Model

The North China Plain, which is critical for food production in China, is encountering serious water shortage due to heavy agricultural water requirement. The accurate modelling of carbon dioxide flux and evapotranspiration (ET) in croplands is thus essential for yield prediction and water resources management. The land surface model is powerful in simulating energy and carbon dioxide fluxes between land and atmosphere. Some key processes in the Simple Biosphere Model (Version 2, SiB2) were parameterized based on the observations. The simulated fluxes were tested against the eddy covariance flux measurements over two typical winter wheat/maize double cropping fields. A simple diagnostic parameterisation of soil respiration, not included in SiB2, was added and calibrated using the observations to model the carbon budget. The Ball‐Berry stomatal conductance model was calibrated using observed leaf gas exchange rate, showing that the original SiB2 could significantly underpredict the ET in the wheat field. SiB2 significantly underpredicted soil resistance at the Weishan site, leading to overpredict the ET. Overall, there was a close agreement between the simulated and observed latent heat fluxes and net CO₂ exchange using the re‐parameterized SiB2. These findings are important when the model is used for the regional simulation in the North China Plain. Copyright © 2011 John Wiley & Sons, Ltd.