Formation of radical species in photolyzed CH4:N2 ices

We report photochemical studies of thin cryogenic ice films composed of N₂, CH₄ and CO in ratios analogous to those on the surfaces of Neptune’s largest satellite, Triton, and on Pluto. Experiments were performed using a hydrogen discharge lamp, which provides an intense source of ultraviolet light to simulate the sunlight-induced photochemistry on these icy bodies. Characterization via infrared spectroscopy showed that C₂H₆ and C₂H₂, and HCO are formed by the dissociation of CH₄ into H, CH₂ and CH₃ and the subsequent reaction of these radicals within the ice. Other radical species, such as C₂, , CN, and CNN, are observed in the visible and ultraviolet regions of the spectrum. These species imply a rich chemistry based on formation of radicals from methane and their subsequent reaction with the N₂ matrix. We discuss the implications of the formation of these radicals for the chemical evolution of Triton and Pluto. Ultimately, this work suggests that , CN, HCO, and CNN may be found in significant quantities on the surfaces of Triton and Pluto and that new observations of these objects in the appropriate wavelength regions are warranted.     

Relative molar mass distributions of chromophoric colloidal organic matter in coastal seawater determined by Flow Field-Flow Fractionation with UV absorbance and fluorescence detection

A new method for the characterization of chromophoric colloidal organic matter in seawater has been applied to samples from the Baltic Sea, Kattegatt and Skagerrak seas. Size fractionation of the sample by Flow Field-Flow Fractionation and measurement of the fluorescent and UV absorbing properties of the individual size fractions result in a relative molar mass distribution (RMM) of the optical properties. The RMM distributions have been used to estimate number and weight average relative molar masses, and polydispersity indices. At least two sources of coloured organic matter were identified from the ratio of fluorescence to UV: the Baltic surface water and the Skagerrak deep water. The dominating processes were mixing and dilution, but processes such as photo bleaching of fluorescence are also believed to be important. The RMM distribution derived from UV detection (1150–1300 Dalton) increased with increasing salinity while that derived for fluorescence (1500–1250 Dalton) decreased with increasing salinity. The specific UV absorbance taken as a proxy of the aromaticity of the chromophoric organic material showed decreasing trend with both increasing salinity and increasing UV derived weight average relative molar mass. Increasing polydispersity of the colloidal material was also observed as a function of salinity.     

太阳大气中氢原子的赖曼谱线

氢是太阳大气中最主要的元素。氢原子的赖曼(Lyman)谱线,尤其是赖曼阿尔法(Ly-α)谱线的辐射,是太阳色球和低过渡区能量损失的主要形式。在太阳的赖曼α像中,网络组织的辐射比较强,而辐射最强的地方是活动区。由于存在辐射转移效应,在宁静区,低阶赖曼谱线的谱形中央一般会形成一个凹陷,而在中央两侧则形成两个峰,两峰往往呈现出一定的不对称性。数值模拟和观测研究表明,赖曼谱线双峰的不对称性与高层大气中各种系统性流动有关。在太阳活动区,赖曼谱形在谱斑区与在宁静区类似;而在黑子区,赖曼谱形几乎没有中央凹陷。赖曼谱形也可用于诊断日珥、耀斑和日冕物质抛射等结构和现象的等离子体特性。该文回顾了赖曼谱线的观测历史,阐明了观测与模拟结果所揭示的物理过程,并结合笔者的认识进行了相应的评论。     

Study of the dependence of the star formation rate in the nuclear regions of 39 Kazarian galaxies on their integral parameters

A statistical study of the dependence of the star formation rate in the nuclear regions of 39 Kazarian galaxies on the integral parameters of these galaxies is carried out on the basis of spectra from SDSS DR6. The value of SFR/kpc² for our sample lies in the range 0.013÷2.04M _⨀ year⁻¹kpc⁻² (with the maximum value of 2.04 corresponding to the Kaz 98 (merger)). It is found that the surface density of the rate of star formation correlates positively with the bar structure parameter and EW(Hα), and that, for spiral galaxies of early morphological types, SFR/kpc² is greater than for the later types. It is shown that the color B-R for the galaxies and the color (u − g) _nucl for the nuclear region correlate positively with the total absorption A(Hα) in the Ha line for the nuclear region. The average value of A(Hα) for our samples is found to be A(Hα)=1.3±0.09 magnitudes. Translated from Astrofizika, Vol. 52, No. 2, pp. 211–224 (May 2009).     

新20号井水位异常特征分析

运用mapsis软件前兆异常分析中的差分、从属函数和变差对新20号井水位进行异常识别,结果认为:(1)差分、从属函数和变差异常形态均为高值异常;(2)差分和变差对近场M<,s>≥5地震漏报率较高,但有异常出现时,后续往往有地震对应,而从属函数对近场M<,s>≥5映震率为66.7%,对远场M<,s>≥7映震率为71.4%...     

Europa’s disk-resolved ultraviolet spectra: Relationships with plasma flux and surface terrains

The full set of high-resolution observations from the Galileo Ultraviolet Spectrometer (UVS) is analyzed to look for spectral trends across the surface of Europa. We provide the first disk-resolved map of the 280 nm SO₂ absorption feature and investigate its relationship with sulfur and electron flux distributions as well as with surface features and relative surface ages. Our results have implications for exogenic and endogenic sources. The large-scale pattern in SO₂ absorption band depth is again shown to be similar to the pattern of sulfur ion implantation, but with strong variations in band depth based on terrain. In particular, the young chaos units show stronger SO₂ absorption bands than expected from the average pattern of sulfur ion flux, suggesting a local source of SO₂ in those regions, or diapiric heating that leads to a sulfur-rich lag deposit.While the SO₂ absorption feature is confined to the trailing hemisphere, the near UV albedo (300-310 nm) has a global pattern with a minimum at the center of the trailing hemisphere and a maximum at the center of the leading hemisphere. The global nature of the albedo pattern is suggestive of an exogenic source, and several possibilities are discussed. Like the SO₂ absorption, the near UV albedo also has local variations that depend on terrain type and age.     

太阳紫外光谱及NO2光解系数的观测

本文讨论了利用自动太阳光谱仪测量地面的紫外辐射光谱,并进一步计算了NO_2的光分解系数.光谱测量范围为310—375nm.测量结果表明,在北京地区秋季NO_2的光解系数变化在(1—4)×10~(-3)S~(-1),有明显的日变化.     

Combined experimental and theoretical studies on methane photolysis at 121.6 and 248 nm—implications on a program of laboratory simulations of Titan’s atmosphere

Methane is, together with N₂, the main precursor of Titan’s atmospheric chemistry. In our laboratory, we are currently developing a program of laboratory simulations of Titan’s atmosphere, where methane is intended to be dissociated by multiphotonic photolysis at 248 nm. A preliminary study has shown that multiphotonic absorption of methane at 248 nm is efficient and leads to the production of hydrocarbons such as C₂H₂ (Romanzin et al., 2008). Yet, at this wavelength, little is known about the branching ratios of the hydrocarbon radicals (CH₃, CH₂ and CH) and their following photochemistry. This paper thus aims at investigating methane photochemistry at 248 nm by comparing the chemical evolution observed after irradiation of CH₄ at 248 and at 121.6 nm (Ly-α). It is indeed important to see if the chemistry is driven the same way at both wavelengths in particular because, on Titan, methane photolysis mainly involves Ly-α photons. An approach combining experiments and theoretical analysis by means of a specifically adapted 0-D model has thus been developed and is presented in this paper. The results obtained clearly indicate that the chemistry is different depending on the wavelength. They also suggest that at 248 nm, methane dissociation is in competition with ionisation, which could occur through a three-photon absorption process. As a consequence, 248 nm photolysis appears to be unsuitable to study methane neutral photochemistry alone. The implications of this result on our laboratory simulation program and new experimental developments are discussed. Additional information on methane photochemistry at 121.6 nm are also obtained.