Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.     

Upper Cretaceous marine‐continental transition (Leonese Area,NW Spain) defined from integrated outcrop and seismic stratigraphy

The Upper Cretaceous succession of the Leonese Area (NW Spain) comprises mixed clastic and carbonate sediments. This succession is divided into two lithostratigraphic units, the Voznuevo Member and the Boñar Formation, which represent fluvial, shoreface, intertidal, subtidal and open‐shelf sedimentary environments. Regional seismic interpretation and sequence stratigraphic analysis have allowed the study of lateral and vertical changes in the sedimentary record and the definition of third‐order levels of stratigraphic cyclicity. On the basis of these data, the succession can be divided into two second‐order depositional sequences (DS‐1 and DS‐2), incorporating three system tracts in a lowstand to transgressive to highstand system tract succession (LST–TST–HST). These sequences are composed of fluvial systems at the base with palaeocurrents that flowed westward and south‐westward. The upper part of DS‐1 (Late Albian–Middle Turonian) shows evidence of intertidal to subtidal and offshore deposits. DS‐2 (Late Turonian–Campanian) comprises intertidal to subtidal, tidal flat, shallow marine and lacustrine deposits and interbedded fluvial deposits. Two regressive–transgressive cycles occurred in the area related to eustatic controls. The evolution of the basin can be explained by base‐level changes and associated shifts in depositional trends of successive retrogradational episodes. By using isobath and isopach maps, the main palaeogeographic features of DS‐1 and DS‐2 were constrained, namely coastline positions, the existence and orientation of corridors through which fluvial networks were channelled and the location of the main depocentres of the basin. Sedimentation on the Upper Cretaceous marine platform was mainly controlled by (i) oscillations of sea level and (ii) the orientation of Mesozoic faults, which induced sedimentation along depocentres. Copyright © 2013 John Wiley & Sons, Ltd.     

月球构造新认识：基于60m高精度全月月形图的月球构造形态学研究

一直以来月球上都没有发现像地球上一样的全球板块构造现象,被认为是属于单板块构造的行星体并且是不活动的。随着月球地形探测精度的提高,人们逐渐发现了一些地质现象表明月球并不像之前想象的一样是不活动的。高精度的月形数据显示出了月球上除了存在众所周知的(撞击作用产生的)复杂的撞击构造外,仍然存在许多可能由内生作用产生的构造特征:如裂谷、山脊、火山群等。本文利用最新高精度月球激光高度数据(LOLA数据)建立了全月60m(相当于7秒网格)高精度月形图。由于数据量超大(TB级别),作者编写了基于并行架构的集群计算处理代码,其计算效率提高了近300倍。基于这些图件,作者在全球范围内找出许多重要的构造现象,并根据其构造及地质特征进行分类研究。研究结果表明并不像之前认识一样,月球上的确存在许多地质构造体是由月球的内生地质作用所产生,并建立对于月球结构和构造的新认识。此外,通过对比发现,像地球上全球尺度的线性山脉只是板块构造运动的结果;另一方面,在无板块构造的行星上,就像月球一样,会产生大面积的高地(月陆)和低地(月海地区),这种地质现象很有可能是行星地壳岩浆演化的直接结果。在文章最后,作者还将制作出的60m分辨率的全月月形系列图件附后并公开,以方便其他科研人员进一步开展相关研究;并以此敬献中国地质科学院60周年庆典。     

Use of cartographic images by expert and novice field geologists in planning fieldwork routes

Topographic maps and aerial photographs are particularly useful when geoscientists are faced with fieldwork tasks such as selecting paths for observation, establishing sampling schemes, or defining field regions. These types of images are crucial in bedrock geologic mapping, a cognitively complex field-based problem-solving task. Geologic mapping requires the geologist to correctly identify rock types and three-dimensional bedrock structures from often partial or poor-quality outcrop data while navigating through unfamiliar terrain. This paper compares the walked routes of novice to expert geologists working in the field (n = 66) with the results of a route planning and navigation survey of a similar population of geologists (n = 77). Results show clearly that those geologists with previous mapping experience make quick and decisive determinations about field areas from available imagery and maps, regardless of whether they are or not physically present in the field area. Recognition of geologic features enabled experts to form and verbalize a specific plan for travel through a landscape based on those features. Novices were less likely to develop specific travel route plans and were less likely to identify critical landscape cues from aerial photographs.     

Computer-aided design of bus route maps

The bus route map is a diagram that aims to convey necessary information for map readers to find an appropriate way of moving from an origin to a destination. Design of bus route map is a complicated and time-consuming task that requires careful consideration of readability and aesthetics. This paper proposes a new computational method for designing bus route maps. The method helps us to reduce six types of undesirable elements in bus route maps, i.e., gap, shift, crossing, overlap, misalignment, and acute bend. The method consists of two phases: line layout phase determines the relative order of bus routes on each road segment and map layout phase calculates the actual position of bus routes drawn on a map. This paper applies the method to the design of bus route maps of Chiba City, Japan. The result supports the effectiveness of the method as well as reveals open topics for future research.     

High Precision Sr‐Nd‐Hf‐Pb Isotopic Compositions of USGS Reference Material BCR‐2

The Lamont‐Doherty Earth Observatory radiogenic isotope group has been systematically measuring Sr‐Nd‐Pb‐Hf isotopes of USGS reference material BCR‐2 (Columbia River Basalt 2), as a chemical processing and instrumental quality control monitor for isotopic measurements. BCR‐2 is now a widely used geochemical inter‐laboratory reference material (RM), with its predecessor BCR‐1 no longer available. Recognising that precise and accurate data on RMs is important for ensuring analytical quality and for comparing data between different laboratories, we present a compilation of multiple digestions and analyses made on BCR‐2 during the first author's dissertation research. The best estimates of Sr, Nd and Hf isotope ratios and measurement reproducibilities, after filtering at the 2s level for outliers, were ⁸⁷Sr/⁸⁶Sr = 0.705000 ± 11 (2s, 16 ppm, n = 21, sixteen digestions, one outlier), ¹⁴³Nd/¹⁴⁴Nd = 0.512637 ± 13 (2s, 25 ppm, n = 27, thirteen digestions, one outlier) and ¹⁷⁶Hf/¹⁷⁷Hf = 0.282866 ± 11 (2s, 39 ppm, n = 25, thirteen digestions, no outliers). Mean Nd and Hf values were within error of those reported by Weis et al. (2006, 2007) in their studies of RMs; mean Sr values were just outside the 2s uncertainty range of both laboratories. Moreover, a survey of published Sr‐Nd‐Hf data shows that our results fall within the range of reported values, but with a smaller variability. Our Pb isotope results on acid leached BCR‐2 aliquots (n = 26, twelve digestions, two outliers) were ²⁰⁶Pb/²⁰⁴Pb = 18.8029 ± 10 (2s, 55 ppm), ²⁰⁷Pb/²⁰⁴Pb = 15.6239 ± 8 (2s, 52 ppm), ²⁰⁸Pb/²⁰⁴Pb = 38.8287 ± 25 (2s, 63 ppm). We confirm that unleached BCR‐2 powder is contaminated with Pb, and that sufficient leaching prior to digestion is required to achieve accurate values for the uncontaminated Pb isotopic compositions.     

Exploring the spatial distribution patterns of South African Cape hakes using generalised additive models

We developed delta generalised additive models (GAMs) to predict the spatial distribution of different size classes of South African hakes, Merluccius capensis and M. paradoxus, using demersal trawl survey data and geographical (latitude and longitude) and environmental features (depth, temperature, bottom dissolved oxygen and sediment type). Our approach consists of fitting, for each hake size class, two independent models, a binomial GAM and a quasi-Poisson GAM, whose predictions are then combined using the delta method. Delta GAMs were validated using an iterative cross-validation procedure, and their predictions were then employed to produce distribution maps for the southern Benguela. Delta GAM predictions confirmed existing knowledge about the spatial distribution patterns of South African hakes, and brought new insights into the factors influencing the presence/absence and abundance of these species. Our GAM approach can be used to produce distribution maps for spatially explicit ecosystem models of the southern Benguela in a rigorous and objective way. Ecosystem models are critical features of the ecosystem approach to fisheries, and distribution maps constructed using our GAM approach will enable a reliable allocation of species biomasses in spatially explicit ecosystem models, which will increase trust in the spatial overlaps and, therefore, the trophic interactions predicted by these models.     

Measured and perceived visual complexity: a comparative study among three online map providers

We present a study on human perception of map complexity, with the objective of better understanding design decisions that may lead to undesirable levels of complexity in web maps. We compare three complexity metrics to human ratings of complexity obtained through a user survey. Specifically, we use two algorithmic approaches published by others, which measure feature congestion (FC) and subband entropy (SE), as well as our own approach of counting object types rather than individual objects. We compare these metrics with each other as well as with human complexity ratings for three maps of the same area from map providers Google Maps, Bing Maps, and OpenStreetMap. Each map design is assessed at three different scales (levels of detail). We find that (1) the FC and SE metrics appear to be adequate predictors of what humans consider complex; (2) object-type counts are slightly less successful at predicting human-rated complexity, implying that clutter is more important in perceived complexity than diversity of symbology; and (3) generalization choices do impact human complexity ratings. These findings contribute to our understanding of what makes a map complex, with implications for designing maps that are easy to use.     

Design principles for origin-destination flow maps

Origin-destination flow maps are often difficult to read due to overlapping flows. Cartographers have developed design principles in manual cartography for origin-destination flow maps to reduce overlaps and increase readability. These design principles are identified and documented using a quantitative content analysis of 97 geographic origin-destination flow maps without branching or merging flows. The effectiveness of selected design principles is verified in a user study with 215 participants. Findings show that (a) curved flows are more effective than straight flows, (b) arrows indicate direction more effectively than tapered line widths, and (c) flows between nodes are more effective than flows between areas. These findings, combined with results from user studies in graph drawing, conclude that effective and efficient origin-destination flow maps should be designed according to the following design principles: overlaps between flows are minimized; symmetric flows are preferred to asymmetric flows; longer flows are curved more than shorter or peripheral flows; acute angles between crossing flows are avoided; sharp bends in flow lines are avoided; flows do not pass under unconnected nodes; flows are radially distributed around nodes; flow direction is indicated with arrowheads; and flow width is scaled with represented quantity.     

WRF模式中不同土地利用数据对新疆一次高温天气模拟的影响

本研究在WRF(v3.8.1)中分别使用MODIS 21类和USGS 24类土地利用类型数据,模拟了新疆2017年7月9日的极端高温天气,并在对模拟温度进行了高度订正的基础上,对比了两种土地利用数据对2 m温度预报的影响。结果表明:(1)MODIS和USGS在新疆地区的土地利用差异主要在阿尔泰山、天山以及南疆西部的昆仑山北部海拔3000 m以上的高山带,相应地,使用USGS模拟的这些高山带2 m气温明显高于使用MODIS的模拟值,最高偏高12 K左右,是全疆范围内两者偏差的极大值。(2)就新疆区域而言,使用USGS模拟的2 m气温整体优于使用MODIS的模拟值,且USGS模拟的2 m温度整体低于MODIS模拟的2 m温度。两者与实况的偏差多在2 K以内。(3)在伊犁河谷,MODIS土地利用类型主要为"旱地/草地",USGS为"草地"和"农田/林地马赛克"。伊犁河谷代表站点2 m温度模拟多以高温偏低、低温偏高为主。(4)与MODIS相比,USGS中哈密地区"农田/林地马赛克"所占比重明显增大。哈密地区多数代表站点高、低温均以偏低为主。(5)站点温度的高度订正多以调低为主,调低幅度最大值为1.9 K,出现在伊犁河谷的尼勒克站。站点2 m温度的调整幅度整体上明显大于MODIS和USGS模拟2 m温度的差值,由此可见温度高度订正的必要性。