Grain coarsening in contact metamorphic carbonates: effects of second-phase particles, fluid flow and thermal perturbations

Under contact metamorphic conditions, carbonate rocks in the direct vicinity of the Adamello pluton reflect a temperature‐induced grain coarsening. Despite this large‐scale trend, a considerable grain size scatter occurs on the outcrop‐scale indicating local influence of second‐order effects such as thermal perturbations, fluid flow and second‐phase particles. Second‐phase particles, whose sizes range from nano‐ to the micron‐scale, induce the most pronounced data scatter resulting in grain sizes too small by up to a factor of 10, compared with theoretical grain growth in a pure system. Such values are restricted to relatively impure samples consisting of up to 10 vol.% micron‐scale second‐phase particles, or to samples containing a large number of nano‐scale particles. The obtained data set suggests that the second phases induce a temperature‐controlled reduction on calcite grain growth. The mean calcite grain size can therefore be expressed in the form D = C₂ e^Q*/RT(d_p/f_p)^m*, where C₂ is a constant, Q* is an activation energy, T the temperature and m* the exponent of the ratio d_p/f_p, i.e. of the average size of the second phases divided by their volume fraction. However, more data are needed to obtain reliable values for C₂ and Q*. Besides variations in the average grain size, the presence of second‐phase particles generates crystal size distribution (CSD) shapes characterized by lognormal distributions, which differ from the Gaussian‐type distributions of the pure samples. In contrast, fluid‐enhanced grain growth does not change the shape of the CSDs, but due to enhanced transport properties, the average grain sizes increase by a factor of 2 and the variance of the distribution increases. Stable δ¹⁸O and δ¹³C isotope ratios in fluid‐affected zones only deviate slightly from the host rock values, suggesting low fluid/rock ratios. Grain growth modelling indicates that the fluid‐induced grain size variations can develop within several ka. As inferred from a combination of thermal and grain growth modelling, dykes with widths of up to 1 m have only a restricted influence on grain size deviations smaller than a factor of 1.1. To summarize, considerable grain size variations of up to one order of magnitude can locally result from second‐order effects. Such effects require special attention when comparing experimentally derived grain growth kinetics with field studies.     

Fuzzy set approaches to classification of rock masses

Rock mass classification is analogous to multi-feature pattern recognition problem. The objective is to assign a rock mass to one of the pre-defined classes using a given set of criteria. This process involves a number of subjective uncertainties stemming from: (a) qualitative (linguistic) criteria; (b) sharp class boundaries; (c) fixed rating (or weight) scales; and (d) variable input reliability. Fuzzy set theory enables a soft approach to account for these uncertainties by allowing the expert to participate in this process in several ways. Hence, this study was designed to investigate the earlier fuzzy rock mass classification attempts and to devise improved methodologies to utilize the theory more accurately and efficiently. As in the earlier studies, the Rock Mass Rating (RMR) system was adopted as a reference conventional classification system because of its simple linear aggregation.

The proposed classification approach is based on the concept of partial fuzzy sets representing the variable importance or recognition power of each criterion in the universal domain of rock mass quality. The method enables one to evaluate rock mass quality using any set of criteria, and it is easy to implement. To reduce uncertainties due to project- and lithology-dependent variations, partial membership functions were formulated considering shallow (<200 m) tunneling in granitic rock masses. This facilitated a detailed expression of the variations in the classification power of each criterion along the corresponding universal domains. The binary relationship tables generated using these functions were processed not to derive a single class but rather to plot criterion contribution trends (stacked area graphs) and belief surface contours, which proved to be very satisfactory in difficult decision situations. Four input scenarios were selected to demonstrate the efficiency of the proposed approach in different situations and with reference to the earlier approaches.     

合理设计岩屑规程保证正常钻进条件——金刚石钻进技术专题之一

论述了正常钻进的条件，提出了合理岩屑规程是保证正常钻进的关键和设计钻头的主要依据之一，讨论了岩屑规程与金刚石钻头唇面工作状态、孔底表面粗糙度和岩屑粒度的关系，提出了相应的建议。     

基于SuperMap的图形处理技术

本文首先阐述了SuperMap DeskPro的基本功能，然后对利用SuperMap DeskPro进行常规图形处理的技巧进行了详细介绍，具体包括地图配准、地图拼接、数据集重新整合、对象标注、文本数据集到属性字段的转换和地图格网生成。通过这些技巧的运用，可以有效提高数据的处理能力。     

Texture and petrology of modern river, beach and shelf sands in a volcanic back-arc setting, northeastern Japan

Abstract The focus in the present study is on characterizing spatial patterns of textural and petrological variabilities, and on evaluating mechanisms influencing the textural and petrological components of modern river, beach and shelf sands in a volcanically active back‐arc tectonic setting. Abashiri Bay and the surrounding area in eastern Hokkaido, Japan, has volcanic source land within a back‐arc region associated with subduction of the Pacific Plate beneath the Okhotsk (North American) Plate. A total of 41 river, beach and shelf sands were obtained for grain‐size and modal composition analyses. Multivariate analytical techniques of hierarchical cluster and principal component analyses were performed on the textural and petrological data for investigating relations among quantitative variables. On the basis of grain‐size data, four sedimentary zones were identified: zone I, palimpsest zone; zone II, relict zone; zone III, modern (proteric) zone; zone IV, coastal sedimentary zone. All sands are feldspatholithic and quartz‐deficient. The framework (quartz, feldspar and rock fragment) modal compositions were also classified into four clusters, A–D. The characteristic components of each cluster are as follows: cluster A, felsic volcanic rock fragments; cluster B, andesitic–basaltic volcanic rock fragments; cluster C, mixed or plagioclase; cluster D, sedimentary rock fragments. Almost all sands in western and central Abashiri Bay belong to cluster A, where the original compositions are influenced by Kutcharo pyroclastic flow deposits. Andesitic–basaltic lava and Neogene volcaniclastic and sedimentary rocks have a major influence on the compositions of shelf sands in eastern Abashiri Bay. The modal compositions are basically controlled by the source lithology. Compositional maturity (percentage of quartz to feldspar and rock fragments; Q/FR%) slightly increased, in order, from river (1.2), zone IV (coastal, 1.7), zone II (relict, 2.2), zone I (palimpsest, 3.6), to zone III (modern proteric, 7.0). Greater maturity in the recycled sediments is indicative of weathering under the sea or abrasion by transportation induced by sea‐level fluctuations, waves, or sea currents. Several controlling factors – (i) source lithological; (ii) mineralogical; (iii) climatic; and (iv) geomorphological controls – might still cause low maturity through all sedimentary zones other than the continental margin sands previously reported.     

Testing a statistical curve‐fitting procedure for quantifying sediment populations within multi‐modal particle‐size distributions

This paper describes a series of tests designed to evaluate the capacity of a personal computer (PC) based statistical curve‐fitting program called MIX to quantify composite populations within multi‐modal particle‐size distributions. Three natural soil samples were analysed by a Coulter Multisizer, and their particle‐size distributions analysed using MIX software to identify the modes, standard deviations and proportions of their composite populations. The particle‐size distributions of the three natural soil samples were then numerically combined in equal proportions using a spreadsheet program to create synthetic particle‐size distributions of known populations. MIX was then tested on the synthetic particle‐size distributions to see if the modes and proportions it identified were similar to those modes and proportions known to characterize the synthetic particle‐size distributions. The main outcome is that MIX can very accurately describe the modal particle size and proportions of the major composite populations within a particle‐size distribution. However MIX has difficulty in identifying small populations (those contributing <10 per cent of a total particle‐size distribution), particularly when they are located in the central sections of particle‐size distributions, overlain by larger populations, or when positioned in the fine tails of distributions. Despite these minor shortcomings, MIX is a valuable tool for the examination and interpretation of particle‐size data. Copyright © 2005 John Wiley & Sons, Ltd.     

Kinetic energy–rainfall intensity relationship for Central Cebu, Philippines for soil erosion studies

In the study of soil erosion, specifically on detachment of soil particles by raindrop impact, kinetic energy is a commonly suggested indicator of the raindrop's ability to detach soil particles from the soil mass. Since direct measurement of kinetic energy requires sophisticated and costly instruments, the alternative approach is to estimate it from rainfall intensity. The present study aims at establishing a relationship between rainfall intensity and kinetic energy for rainfalls in Central Cebu, Philippines as a preface of a wider regional investigation.

Drop size distributions of rainfalls were measured using the disdrometer RD-80. There are two forms of kinetic energy considered here. One is kinetic energy per unit area per unit time (KE_R, J m⁻² h⁻¹) and the other is kinetic energy per unit area per unit depth (KE, J m⁻² mm⁻¹). Relationships between kinetic energy per unit area per unit time (KE_R) and rainfall intensity (I) were obtained using linear and power relations. The exponential model and the logarithmic model were fitted to the KE–I data to obtain corresponding relationships between kinetic energy per unit area per unit depth of rainfall (KE) and rainfall intensity (I). The equation obtained from the exponential model produced smaller standard error of estimates than the logarithmic model.     

Penny-shaped fractures revisited

All methods of seismic characterization of fractured reservoirs are based on effective media theories that relate geometrical and material properties of fractures and surrounding rock to the effective stiffnesses. In exploration seismology, the first-order theory of Hudson is the most popular. It describes the effective model caused by the presence of a single set of thin, aligned vertical fractures in otherwise isotropic rock. This model is known to be transversely isotropic with a horizontal symmetry axis (HTI). Following the theory, one can invert the effective anisotropy for the crack density and type of fluid infill of fractures, the quantities of great importance for reservoir appraisal and management.Here I compute effective media numerically using the finite element method. I deliberately construct models that contain a single set of vertical, ellipsoidal, non-intersecting and non-interconnected fractures to check validity of the first-order Hudson’s theory and establish the limits of its applicability. Contrary to conventional wisdom that Hudson’s results are accurate up to crack density e ≈ 0.1, I show that they consistently overestimate the magnitudes of all effective anisotropic coefficients ε^(V), δ^(V), and γ^(V). Accuracy of theoretically derived anisotropy depends on the type of fluid infill and typically deteriorates as e grows. While the theory gives | ε^(V)|, |δ^(V)|, |γ^(V)| and close to the upper bound of the corresponding numerically obtained values for randomly distributed liquid-filled fractures, theoretical predictions of ε^(V), δ^(V) are not supported by numerical computations when the cracks are dry. This happens primarily because the first-order Hudson’s theory makes no attempt to account for fracture interaction which contributes to the final result much stronger for gas- than for liquid-filled cracks. I find that Mori-Tanaka’s theory is superior to Hudson’s for all examined crack densities and both types of fluid infill.The paper was presented at the 11th International Workshop on Seismic Anisotropy (11IWSA) held in St. John’s, Canada in 2004.     

Temporal variability in the maternal environment and its effect on seed size and seed quality in Flourensia cernua DC. (Asteraceae).

The biological phenomenon commonly referred to as maternal effect occurs whenever the environment exerts an influence upon the mother that is later expressed in characteristics of her offsprings. For example, the environmental conditions experienced by a mother plant during flowering and fruiting can modify the quality of her descendants (seeds), and even interrupt their development. Between-year variation in minimum temperature and the classic, between-year variation in precipitation represent an unpredictable environment for winter blooming plants in arid zones. In this study, we investigated the effect of maternal environment (temperature and precipitation) on seed size and seed quality in F. cernua, over a 5-year period. Results indicated that the proportion of filled seeds, as well as their size, increased with higher absolute minimum temperatures during seed formation, and that, to a lesser extent, both the precipitation occurred during the same period and the annual precipitation also have a positive influence on seed size. In this way, environmental conditions prevailing during seed formation exerted a strong maternal effect on the size and quality of seeds produced and, probably also, in the developmental possibilities of F. cernua seedlings. This effect was subject to important, between-year variation.     

Laser Ablation ICP-MS Developments and Trends for 2003

This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis.