Study on the negative bias temperature instability effect under dynamic stress

This paper studies negative bias temperature instability (NBTI) under alternant and alternating current (AC) stress. Under alternant stress, the degradation smaller than that of single negative stress is obtained. The smaller degradation is resulted from the recovery of positive stress. There are two reasons for the recovery. One is the passivation of H dangling bonds, and another is the detrapping of charges trapped in the oxide. Under different frequencies of AC stress, the parameters all show regular degradation, and also smaller than that of the direct current stress. The higher the frequency is, the smaller the degradation becomes. As the negative stress time is too small under higher frequency, the deeper defects are hard to be filled in. Therefore, the detrapping of oxide charges is easy to occur under positive bias and the degradation is smaller with higher frequency.     

Improved understanding of petroleum migration history in the Hongche fault zone,northwestern Junggar Basin (northwest China): Constrained by vein-calcite fluid inclusions and trace elements

Calcite veins and cements occur widely in Carboniferous and Permian reservoirs of the Hongche fault zone, northwestern Junggar Basin in northwest China. The calcites were investigated by fluid inclusion and trace-element analyses, providing an improved understanding of the petroleum migration history. It is indicated that the Hongche fault behaved as a migration pathway before the Early Cretaceous, allowing two oil charges to migrate into the hanging-wall, fault-core and footwall reservoirs across the fault. Since the Late Cretaceous, the Hongche fault has been sealed. As a consequence, meteoric water flowed down only into the hanging-wall and fault-core reservoirs. The meteoric-water incursion is likely an important cause for degradation of reservoir oils. In contrast, the footwall reservoirs received gas charge (the third hydrocarbon event) following the Late Cretaceous. This helps explain the distribution of petroleum across the fault. This study provides an example of how a fault may evolve as pathway and seal over time, and how reservoir diagenetic minerals can provide clues to complex petroleum migration histories.     

Effects of different types of mechanical disturbances on a charophyte dominated macrophyte community

Charophytes are unique and endangered macroalgae. Mechanical stress is known to damage charophyte communities, however, virtually nothing is known how such disturbance affect seasonal succession and recovery of charophyte communities. We examined the response of a shallow water charophyte community to different types and timing of disturbances by conducting seasonal in situ field experiment in a brackish water ecosystem. The disturbances associated with mechanical removal of vegetation or sediment had the largest impact on the charophyte community. Disturbances that only partly damaged the plants had minor effects and communities were characterized by fast recovery. The timing of disturbance had significant effects on the charophyte community with stronger effects when disturbed at the early stage compared to mid-stage of seasonal succession.     

Reef status in the Rasfari region (North Malé Atoll,Maldives) five years before the mass mortality event of 1998

The Maldives was severely hit by massive coral bleaching and subsequent mortality in 1998. The results of reef monitoring in the following years have supported contrasting views about their recovery potential, partly because of the scarcity of information on the situation before 1998. Quantitative data on coral assemblages collected in 1993 in the Rasfari region (North Malé Atoll) may provide a base-line for the evaluation of the present status of the Maldivian reefs. Five years before the 1998 mortality, most coral communities appeared to be similar, in terms of both coral cover and growth-form composition, to those described in 1958 and 1964, notwithstanding increased human pressure and local events such as minor bleaching episodes in 1987 and crown-of-thorns starfish (COTS) attacks in 1989. Three lessons can be learnt from these results to help to understand the present situation, some ten years after the 1998 mass mortality. First, Maldivian reefs proved in the past to be capable of maintaining flourishing coral life despite various disturbances. Second, four years had been sufficient for complete reef recovery after a (minor) bleaching event. Third, recovery after both COTS attack and bleaching follows a predictable path suggesting that the presence of a three-dimensional community structure, which should reduce post settlement mortality of coral recruits, is essential for rapid coral recovery. As coral recruitment remains high and large tabular Acropora colonies are now reappearing, it is expected that Maldivian reefs should return to their original condition within the next few years.     

GRACE时变信号恢复方法对比分析

针对利用GRACE重力数据反演地表质量变化过程中产生的时变信号削弱和泄露现象,分别采用尺度因子法和迭代恢复法对信号进行恢复,并选用CSR Mascon产品从时间序列变化和空间分布两个角度对两种恢复方法的效果进行对比分析。结果表明:1)尺度因子法虽实现上较为简单,但其计算结果完全依赖于所选的先验模型,当所选模型的可靠性较差时,会影响到GRACE反演结果的可靠性。2)迭代恢复法的恢复过程仅受GRACE原始观测值的约束,能较好地恢复研究区域的长期趋势信号和周期信号,但在部分区域可能存在信号过量恢复的现象。建议采用迭代恢复法进行GRACE时变信号恢复。     

Dissolved aluminium and the silicon cycle in the Arctic Ocean

Concentrations of dissolved (0.2 µm filtered) aluminium (Al) have been determined for the first time in the Eurasian part of the Arctic Ocean over the entire water column during expedition ARK XXII/2 aboard R.V. Polarstern (2007). An unprecedented number of 666 samples was analysed for 44 stations along 5 ocean transects. Dissolved Al in surface layer water (SLW) was very low, close to 1 nM, with lowest SLW concentrations towards the Canadian part of the Arctic Ocean and higher values adjacent to and in the shelf seas. The low SLW concentrations indicate no or little influence from aeolian dust input. Dissolved Al showed a nutrient-type increase with depth up to 28 nM, but large differences existed between the different deep Arctic basins. The differences in concentrations of Al between water masses and basins could largely be related to the different origins of the water masses. In the SLW and intermediate water layers, Atlantic and Pacific inflows were of importance. Deep shelf convection appeared to influence the Al distribution in the deep Eurasian Basin. The Al distribution of the deep Makarov Basin provides evidence for Eurasian Basin water inflow into the deep Makarov Basin. A strong correlation between Al and Silicon (Si) was observed in all basins. This correlation and the nutrient-like profile indicate a strong biological influence on the cycling and distribution of Al. The biological influence can be direct by the incorporation of Al in biogenic silica, indirect by preferential scavenging of Al onto biogenic siliceous particles, or by a combination of both processes. From the slope of the overall Al–Si relationship in the intermediate water layer (AIDW; ~ 200–2000 m depth), an Al/Si ratio of 2.2 atoms Al per 1000 atoms Si was derived. This ratio is consistent with the range of previously reported Al/Si uptake ratio in biogenic opal frustules of diatoms. In the deepest waters (>2000 m depth) a steeper slope of the Al–Si relationship of 7.4 to 13 atoms Al per 1000 atoms Si likely results from entrainment of cold shelf water into the deep basins, carrying the signal of dissolution of terrigenous particles with a much higher Al:Si ratio of crustal abundance. Only a small enrichment with such crustal Al and Si component may readily account for the higher Al:Si slope in the deepest waters.     

The role of eddies in solute transport and recovery in rock fractures: Implication for groundwater remediation

A better understanding of solute transport and retention mechanism in rock fractures has been challenging due to difficulty in their direct observations in microscale rough‐walled fractures. Six representative troughs in a rough‐walled fracture were selected for microscale observations of eddy formation with increasing flow velocity and its effect on spatiotemporal changes of solute concentration. This experimental study was enabled by a microscale visualization technique of micro particle image velocimetry. With increasing flow velocity (Re ≤ 2.86), no eddies were generated, and solutes along the main streamlines transported rapidly, whereas those near the wall moved slowly. A larger amount of solutes remained trapped at all troughs at Re = 2.86 than Re < 1. For Re = 8.57, weak eddies started to be developed at the troughs on the lee side, which little contributed to overall solute flushing in the fracture. Accordingly, a large of amount of water was needed for solute flushing. The flow condition of 1 < Re < 10, before a full development of eddies, was least favourable in terms of time and amount of remediation fluid required to reach a target concentration. After large eddies were fully developed at troughs on the lee side for Re = 17.13, solutes were substantially reduced by eddies with less amount of water. Fully developed eddies were found to enhance solute transport and recovery, as opposed to a general consensus that eddies trap and delay solutes. Direct inflow into troughs on the stoss side also made a great contribution to solute flushing out of the troughs. This study indicates that fully developed eddies or strong inflows at troughs are highly possible to form for Re > 10 and this flow range could be favourable for efficient remediation.     

Laboratory simulation of natural leaching processes of eastern USA oil shale

Raw and retorted spent oil shales from Kentucky, as well as soil and overburden materials, were subjected to laboratory and field leaching tests. Standard batch leaching tests grossly undervalue the amount of dissolved ions as measured in the field, being too brief to enable slow reactions of the mineral matrix, such as hydrolysis and oxidation of sulfides or reactions of acidic leachates with soluble components of the clays. Laboratory column tests, devised to closely simulate natural leaching processes, achieved concentration levels and elemental release patterns similar to those found in field tests. The column tests provide a reliable means to assess the leachability of metals in these materials.     

聚四氟乙烯平板型气态膜回收淡盐水中氯气

本文以离子膜电解氯化钾制取碳酸钾工艺产生的淡盐水为原料,系统地研究了聚四氟乙烯平板型气态膜回收氯过程中膜性能和次氯酸钠水溶液的制备。初步研究表明,次氯酸钠含量大于100g/L,氢氧化钠有效利用率为90％;聚四氟乙烯膜有传质快、对离子截留性能好、使用寿命长等优点,在工业上有较好的应用前景。