River sediments,great floods and centennial‐scale Holocene climate change

A new analysis of all 346 published ¹⁴C dated Holocene alluvial units in Britain offers a unique insight into the regional impacts of global change and shows how surprisingly sensitive British rivers have been to relatively modest but repeated changes in climate. Fourteen major but probably brief periods of flooding are identified bracketed within the periods 400–1070, 1940–3940, 7520–8100 and at ca. 10 420 cal. yr BP. There is a strong correspondence between climatic deteriorations inferred from mire wet shifts and major periods of flooding, especially at ca. 8000 cal. yr BP and since ca. 4000 cal. yr BP. The unusually long and complete British record also demonstrates that alterations in land cover have resulted in a step change in river basin sensitivity to variations in climate. This has very important implications for assessing and mitigating the impact of increasing severe flooding. In small and medium‐sized river basins land use is likely to play a key role in either moderating or amplifying the climatic signal. Copyright © 2003 John Wiley & Sons, Ltd.     

INVERSE DDA OF A SYSTEM OF BLOCKS IN SPHERE COORDINATES

1　IntroductionDiscontinuousDeformationAnalysis(DDA)developedbyShiin 1 980’s[1 ,2 ] maybeusedtocalculatethedeformationanddisplacementsinamulti blocksystemandtoanalyzetherelationbe tweenforcesanddisplacementsinthesystem .Ifthesurveydisplacementofeverypointordirectionisknown,alldisplacementsanddeformationsofblocks,eventheglide ,theclosureandthestretchoftheboundary planeofblocks ,canbecalculated .TheresultisoptimallyfittedaccordingtotheLeastSquarePrinciple.DDAismainlyusedinrockblockssystems…     

从辽宁东、西部地质对比论郯庐断裂的平移运动

辽宁东、西部地质上诸多差异并非是原地升降运动造成的，而是二个异地岩块经郯庐断裂大规模左旋平移运动迁移到一起的结果。辽东半岛原曾与鲁西－徐淮地区处于相同的古纬度。郯庐断裂北延的主干断裂应是抚顺－敦化断裂，它在辽宁境内是地层区划的重要界线。郯庐断裂在太古宙末期即已出现，曾多次变换其平移方向，最近一次大规模左行平移活动的高峰期是在晚侏罗世晚期－早白垩世，结束于孙家湾组或泉头组堆积之前。     

The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

鄂尔多斯地块构造演化的古地磁学研究

鄂尔多斯地块与中朝地台其它地区相同时代地层的古地磁结果基本一致表明:晚二叠世以来,中朝地台经历了从低纬度(19°左右)向中纬度的北移过程,并伴有50°左右的逆时针旋转;晚二叠世—中三叠世地台北移10°(1000km)左右,而方位基本未变;中三叠世—中侏罗世主要发生50°左右的逆时针旋转,而北向位移不明显,这一旋转可能与杨子地台和中朝地台碰撞拼合有关,或者说是印支运动在该地区的反应,中侏罗世—早白垩世地块已基本和现代位置一致     

Structural characterization of deep-water deposits in a foreland basin, Silla Syncline (Chilean Patagonia), with applications to depositional processes

Based on our detailed structural characterization, we examine possible relationships between thrust faults and strike-slip faults and thrust-cored folds and depositional units in the Silla Syncline, a 4 km wide fold composed of fine-grained mudstone, coarse sandstone and conglomerate deposits of the Cerro Toro Formation in the Magallanes foreland basin, Chilean Patagonia. The syncline is bounded on its western flank by an asymmetric anticline and on its eastern flank by a broad zone of thrust faults and associated folds, which are oriented sub-parallel to the syncline axis. Deposition of the coarse-grained units of the Silla Syncline appears to have taken place in this structurally defined trough controlled primarily by thrust fault related growth structures flanking the syncline.The syncline and surrounding area have also been deformed by two sets of strike-slip faults, one right-lateral and one left-lateral. The strike-slip and thrust faulting operated contemporaneously for much of their active periods, although it appears that thrust faulting, confined within the fine-grained units, initiated slightly earlier than strike-slip faulting. In addition, younger igneous intrusions at high angle to bedding generally localize along the strike-slip faults. The cross-cutting relationships among the intrusions, strike-slip faults, and flexural slip faults show that all these structures were active during the same period, which extends beyond mid-Miocene.These conclusions support the premise that structures in deep-water sediments are important for understanding not only the deformation of a foreland basin, but also its depositional architecture.     

Multiple discriminant analysis of the Drava River alluvial plain sediments

Three discriminant function models are raised and cross-compared in order to distinguish geochemical patterns characteristic for the Drava River floodplain sediments. Based on data representing total element concentrations in samples collected from alluvium (A), terrace (T), and unconsolidated bedrock (B) at the border of a floodplain, four element clusters emerged accounting for discrimination between the referred groups of sediments. The most prominent is contaminant/carbonate cluster characteristic for alluvium. The other two are: silicate cluster typical for unconsolidated geological substrate (Neogene sedimentary rocks); and naturally dispersed heavy metal cluster separating terrace from the former two groups. Models introducing depth intervals and single profiles as grouping criteria reveal identical sediment-heavy metal matrices. The second important issue of this paper is possibility of reclassification of samples originally assigned to one of the a priori defined groups of sediments, based on established geochemical pattern. The mapped geological units can be reconsidered by the post hoc assignments to a different group if geological border between alluvium and terrace or between terrace and bedrock can not be established geologically with absolute certainty.     

冈底斯新近纪钾质火山作用:消减沉积物折返的地球化学与Sr-Nd-Pb同位素证据

在冈底斯岩浆岩带的羊八井地区,林子宗火山岩系上部出现小规模的粗面质火山岩.岩石学与地球化学研究表明粗面岩与时空密切相关的大体积安山质-英安质-流纹质火山岩属于不同的火山岩系:碱性钾质系列与钙碱性系列.详细的地球化学研究证明林子宗晚期小体积钾质岩具有独立的岩浆源区,而非早期钙碱性系统低压岩浆过程演化的产物.粗面质熔岩SiO2含量为62.91%～64.63%,具有高K2O(7.52%～8.05%)、Al2O3(16.64%-17.35%)、低TiO2(0.59%～0.68%)与MsO(0.15%～0.77%).钾质熔岩富集LILE与LREE,亏损HFSE,具有高Rb/Sr(1.1～2.3)、Th/La(0.59～0.80)、Th/U(6.3～10.9)和低Ce/Pb(4.1～6.2)与Ba/Th(4.3～14.5)比值,其同位素组成变化范围分别是87Sr/86Sr(I)=0.7068～0.7075、143Nd/144Nd(I)=0.51241～0.51252、206Pb/204Pb=18.87～18.95、207Pb/204Pb=15.63～15.70和208Pb/204Pb=39.24～39.68.粗面岩的地球化学与同位素特征表明冈底斯新近纪钾质火山岩来源于角闪岩相的消减沉积物熔融.因此,羊八井新近纪钾质火山熔岩提供了印度-亚洲大陆碰撞早期消减沉积物折返的证据.     

长江三角洲北翼J9孔揭示地层和古地磁特征

长江三角洲北翼地区缺少较长尺度的第四纪海陆变迁及环境演变的深入探讨,深达423m的海安县基岩标J9孔为此提供了较好的研究对象。通过观察该孔松散层岩心,总结其沉积特征,认为岩心可明显地划分为6个特征岩性段。同时,地层古地磁测试结果显示:0～200m为布容正极性世,200～334m为松山负极性世,334m以下为高斯正极性世。综合分析岩心沉积特征并参考古地磁测试结果对地层进行了初步划分,认为:0～39m为全新世地层,39～153m为晚更新世地层,153～200m为中更新世地层,200-334m为早更新世地层,之下为新近纪地层。地层中存在晚更新世晚期特征的硬粘土标志层,指示本地不是冰后期古河谷的发育地。