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21.
Lars Olov Andersson 《Physics and Chemistry of Minerals》2008,35(9):505-520
The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1
signal typical for the CH3 radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal
c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g
// = 2.00263, g
⊥ = 2.00249 and A// = 2.288 mT, A⊥ = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms
are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A
0 = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g
// = 2.00265, g
⊥ = 2.00625 and A// = 0.895 mT, A⊥ = 0.885 mT, could come from a HCO3 radical. One narrow and easily saturated signal with g
// = 2.00227 and g
⊥ = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to
the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g
// = 2.0017 and g
⊥ = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise
from a carbon dioxide radical, which rotates around its symmetry axis. 相似文献
22.
Influence of Structural Non-Stationarity of Surface Roughness on Morphological Characterization and Mechanical Deformation of Rock Joints 总被引:2,自引:2,他引:0
N. Fardin 《Rock Mechanics and Rock Engineering》2008,41(2):267-297
Summary Structural non-stationarity of surface roughness affects accurate morphological characterization as well as mechanical behaviour
of rock joints at the laboratory scale using samples with a size below the stationarity threshold. In this paper, the effect
of structural non-stationarity of surface roughness is investigated by studying the scale dependence of surface roughness
and mechanical behaviour of rock joints. The results show that the structural non-stationarity mainly affects the accurate
characterization of the surface roughness of the fracture samples. It also controls the amount and location of the contact
areas during shear tests, which in turn affects the mechanical properties and asperity degradation of the samples. It is concluded
that for accurate determination of the morphological and mechanical properties of rock joints at laboratory and field scales,
samples with size equal to or larger than the stationarity threshold are required.
Author’s address: Nader Fardin, Rock Mechanics Group, Department of Mining Engineering, Faculty of Engineering, University
of Tehran, P.O. Box: 11365/4563, Tehran, Iran 相似文献
23.
滑坡体三维地质建模与可视化分析 总被引:1,自引:0,他引:1
针对滑坡地质研究的自身特点,提出了面向滑坡地质体三维建模的NURBS-BRep混合数据结构和地质结构单元实体构造技术.通过对滑坡基础地质数据的预处理、滑坡数字地形和滑动面的三维建模、地质结构面的系统构造、地质结构体的生成和显示,形成了一套完整的滑坡三维地质模型的构建方法.将该方法应用于某水库滑坡,建立了相应的三维滑坡地质模型,并基于此模型进行了三维剖切分析、数字钻孔、等值线生成、滑块自动剖分、滑坡失稳可视化动态模拟和滑坡体方量精确计算等一系列实用的可视化分析,为滑坡稳定性的准确计算和客观评价提供了有力的支持. 相似文献
24.
一种新的波浪变形三维数值模式──0-1混合型边界元 总被引:4,自引:0,他引:4
为提高边界元法模拟三维波场波浪变形的数值计算精度,借鉴常数元和线性元剖分方式、波势函数及波势函数法向导数对单元节点设定的各自适应性,提出了一种新的单元剖分模式──0-1混合型边界元,以控制和减缓由于计算误差累计而造成的波浪数值计算上的“横向振动”,借此结合边界元法的分区模式可实现较大范围的波场线性波浪变形计算,并为时域内的波浪非线性变形计算提供时间步长的数值保证. 相似文献
25.
26.
以1,4—苯二酚和不同的短链脂肪酸为基本原料,经溴代、加成、形成酰卤和酰化等反应,合成了六种新的溴化脂肪酸—2,3,5,6—四溴—1,4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析,以及红外吸收光谱和氢核磁共振谱的研究,验证了化合物的结构。 相似文献
27.
根据湍流封闭理论,建立一种适用于正压浅海湍流运动的雷诺应力封闭模型(RSM),以代替目前三维浅海动力学模型中普遍采用的湍粘性系数的传统假设。通过直接建立并模化f—平面上正压海洋的雷诺应力传输方程,分别得到的微分形式和代数形式的RSM方程组。并讨论了进行数值计算所需要的边界条件。利用该模型可以进一步研究浅海潮流、风暴潮流及风海流等浅海流动的三维结构和湍流特性。 相似文献
28.
The mixing characteristics of particles such as dredged sediment of variable size discharged into cross flow are studied by a 3D numerical model, which is developed to model the particle-fluid two-phase flow. The Eulerian method with the modified k-ε parameterization of turbulence for the fluid phase is used to solve fluid phase, while a Lagrangian method for the solid phase (particles), both the processes are coupled through the momentum sources. In the model the wake turbulence induced by particles has been included as additional source term in the k-ε model; and the variable drift velocities of the particles are treated efficiently by the Lagrangian method in which the particles are tracked explicitly and the diffusion process is approximated by a random walk model. The hydrodynamic behavior of dumping a cloud of particles is governed by the total buoyancy of the cloud, the drag force on each particle and the velocity of cross-flow. The computed results show a roughly linear relationship between the displacement of the frontal position and the longitudinal width of the particle cloud. The particle size in the cloud and the velocity of cross flow dominate the flow behavior. The computed results are compared with the results of laboratory experiments and satisfactory agreement is obtained. 相似文献
29.
东营城区高精度三维地震采集方法研究 总被引:3,自引:0,他引:3
根据东营城区内建筑物较多,环境干扰较大,地下构造复杂,断裂非常发育,目的层埋藏深,资料信噪比较低的特点,以地震老资料和钻井资料为基础,建立地震地质模型,利用射线追踪技术选取合适的观测系统参数。充分利用卫星数字地图,没计了灵活多变的观测系统,采用可控震源与炸药震源配合使用方法,及时对城区内地下面元的覆盖次数、方位角和炮检距的分布进行质量监控,利用现场处理系统对资料进行及时分析,提高了地震资料品质。所获得的东营城区高精度三维地震采集资料显示,其浅中层分辨率和中深层信噪比都有了明显改善,取得了良好的地质效果。 相似文献
30.