裂隙岩体渗流场分析及其三维有限元程序设计

针对水工建筑物裂隙岩基渗流场计算,采用双重介质解法编制了三维有限元裂隙渗流计算程序,用水量交换项耦合主干裂隙网络及裂隙岩块,自由面位置的确定使用自由面虚点法迭代逼近,得到了合理的计算结果。计算使用ANSYS建立渗流模型并剖分网格,相应的前处理子程序降低了裂隙渗流计算的复杂性,提高了裂隙渗流理论计算方法的可用性。     

基于TOPSIS和热点分析的都汶公路沿线地质生态环境承载力评价

针对山区公路沿线复杂地质生态环境动态变化等问题, 以都江堰 - 汶川公路沿线区域为研究对象, 提出了一种基于承载力综合质量和空间聚类关系对区域地质生态环境承载力评价的方法, 实现了对具有地质灾害易发特点的山区公路沿线区域承载力状况的科学评价。通过自然 - 环境 - 人文模型构建区域承载力状况评估指标体系, 借助层次分析法确定各评价指标因子的权重, 采用TOPSIS算法（逼近理想解排序方法）进行计算并加权叠加得到承载力综合质量状况, 结合热点分析的结果对研究区的承载力状况进行等级划分。结果表明： 研究区的地质环境、 生态环境、 社会经济承载力质量空间分布皆呈现出高度聚集性, 划入适宜建设区的面积占比31.12%, 后备调控区的面积占比31.98%, 不宜建设区面积占比36.79%, 研究区内的映秀镇、 漩口镇和都江堰所组成的三角区呈现大面积的高值聚集区, 承载力综合质量好, 空间聚集度高, 利于规划建设。评价结果为区域承载力准确评价和空间利用格局研究提供了新思路, 也可为防灾减灾工作提供参考。     

智能大厦接地电阻检测中应注意的问题

根据目前常用接地电阻检测仪器的测量原理,对在日常检测中所出现导致接地电阻检测数据失真的情况进行了分析和探讨,同时针对不同的成因,提出了不同的解决方法。     

谈谈如何避免高空观测记录错情

对使用59-701微机数据处理系统以后高空观测记录容易出错的环节进行归纳和分析,并提出相应的解决措施。     

我国不同海区沉积物石英颗粒表面的微结构

同为海洋沉积环境，不同海区底质沉积物石英颗粒表面的微结构不同，反映出不同的海区沉积环境下的动力能，化学能的强弱，同时温度是化学溶蚀作用重要因素。     

碘氟法测铜改进

碘氟法测铜较其他碘量法快速、准确。提出以三价铁沉淀完全时,作为中和溶液调节所需PH值的指示,直观方便,容易掌握。     

Effects of solution mining on groundwater quality in the Kazan trona field,Ankara-Turkey: model predictions

Three aquifer systems as deep, middle, and shallow were identified in the Kazan trona ore deposit area. The flow conditions and the interaction between various layers were conceptualized into a site hydrogeological model. Each aquifer system was hydraulically and chemically characterized and represented in a numerical groundwater model. The resulting model has been calibrated under steady-state and transient conditions using available data. The flow model was used in conjunction with a three-dimensional solute transport model to assess the impacts of the pilot well solution mining of the trona deposit on groundwater resources during operation and post-operation periods. The results of operation period indicate that, even under the worse conditions (50 times increase in vertical hydraulic conductivity due to subsidence), ion contribution from the mine area with 118,000 mg/l maximum concentration would be about 58 mg/l into the deep aquifer system. This contribution is about 1.45% of the existing concentration (4,000 mg/l) in the deep aquifer. After 1,000 years of post-operation period, ion contribution from the mine area with maximum 119,000 mg/l concentration would be about 205 mg/l into the deep aquifer under extremely worse conditions. This contribution is about 5–20% of present concentrations in the deep aquifer. Retardation factors, which were not considered during model simulations would decrease the predicted concentrations. It is concluded that pilot well solution mining of the trona deposit would not have significant impact on the quality of groundwater resources in the overlying aquifers.     

Removal of Phosphate in Aqueous Solution by Permethylated Poly(ethyleneimine) Entfernung von Phosphat mit permethyliertem Poly(ethylenimin) in wäßriger Lösung

The use of cationic, water-soluble, permethylated poly(ethyleneimine) (PMP) for the removal of phosphate ions was investigated using the Liquid-phase Polymer-based Retention (LPR) technique. The results showed that the retention values were dependent on the filtration factor (Z) and pH. In the presence of 10 mg/L phosphate and 1% PMP, 52% of the phosphate was retained at pH = 1.0 and 93% at pH = 8.5 for Z = 2. However only 11% of phosphate was retained at pH = 1.0 and 80% at pH = 8.5 for Z = 5. The maximum binding capacity of phosphate by 1% of PMP was 22 mg phosphate per gram of PMP at pH = 1.0 and 185 mg phosphate per gram of PMP at pH = 7.0. The influence of nitrate, chloride, and sulfate ions on the interaction of phosphate ions with PMP was also investigated. It was found that the interaction is strongly influenced by sulfate ions. In addition, viscosimetric measurements were performed and discussed.     

云南金顶铅锌矿床方铅矿溶解实验及紫外吸收光谱特征

在进行金顶铅锌矿床方铅矿溶解实验的基础上，测定并讨论溶解液的紫外吸收光谱特征，确定溶解液中铅的存在形式，进而初步探讨铅在含矿流体中的迁移形式。     

Early diagenetic imprints and U–Th isotope systematics of fossil land snail shells from the Chinese Loess Plateau

The loess-paleosol sequence on the Chinese Loess Plateau provides a unique archive that records climate change in East Asia in the Quaternary, yet absolute dating of the loess deposits is challenging due to the lack of directly datable materials. Fossil land snail shells, which are made from aragonite, are widely preserved in the loess deposits and have long been used to reconstruct past environmental changes. U-series dating of fossil land snail shells has the potential to provide a route for absolute dating of the loess deposits but remains largely unexplored. In this study, we present the first systematic investigation on the U-series isotope geochemistry as well as the early diagenetic imprints of fossil land snail shells (Cathaica sp.) from the Mangshan loess-paleosol sequence in Henan province, central China. Several geochemical techniques, including Raman microscopy, SEM, LA-ICPMS, LA-MC-ICPMS, solution-MC-ICPMS, and AMS ¹⁴C dating, were employed to investigate the mineralogy, chemical and isotopic compositions of both modern and fossil snail shells to micrometer level. Our results show that the fossil Cathaica sp. shells are overall characterized by a higher degree of porosity and elevated contents of organic matter compared to live-collected shells of the same species. The layers with higher porosity and organic matter content in the fossil Cathaica sp. shell are also found to be enriched in Na, Mg, Mn, Ba, and U, indicating diffusion and adsorption of these elements by specific surface binding sites of either aragonitic lattice or organic compounds of the fossil shell. Combining in-situ measurements using LA-MC-ICPMS with solution U-series determination, we further demonstrate that fossil Cathaica sp. shell is relatively homogeneous regrading both [²³⁴U/²³⁸U] and [²³⁰Th/²³⁸U] values although the distribution of U in the fossil shell is sample-specific. The comparison of different dating results suggests that the calculated apparent closed system U–Th ages are all systematically younger (∼6000 to 13,000 years) than the corresponding shell ¹⁴C ages and quartz SAR (single-aliquot regenerative-dose) ages from the Mangshan section. We suggest that the underestimation of U–Th ages of fossil Cathaica sp. shells is very likely caused by diagenetic uptake of U that started immediately after the burial of the shell and effectively ceased when the fossil shell was isolated from the pore waters due to persistent deposition of eolian dust at the Mangshan section. Our work on both modern and fossil Cathaica sp. shells thus provides detailed morphological and geochemical characterization for the diagenetic alteration of fossil snail shells and suggests that U-series dating of fossil land snail shells may provide age constraints for dust deposits in the semi-arid region although the timing of early diagenetic U-uptake by the fossil shells need to be better quantified for reliable age determination.