各向异性介质中的AVO

分析了横向各向同性和方位各向异性介质的本构关系,由此讨论弹性波在两种各向异性介质中的传播特点,提出可表征这两种介质各向异性程度的广义参数．以此为基础讨论了两种各向异性介质中存在水平界面时的反射系数近似式,将Dely等人推导的横向各向同性介质中的反射系数公式推广到方位各向异性介质的主轴方向上．根据算例讨论修正的Banik和Thomsen的近似式,着重分析两种各向异性介质中的AVO关系及其对实际勘探的影响和指导意义．     

Binary coefficients: A theoretical and empirical study

Binary coefficients can be assigned to several categories on the basis of algebraic and conceptual properties. The phi coefficient of association is related algebraically to the chi-square statistic for 2-by-2 contingency tables, and use of this coefficient in cluster analysis permits the objective, nonarbitrary partitioning of objects among groups on the basis of previously selected levels of significant, positive association. Similarity, matching, and distance coefficients possess neither conceptual nor operational statistical meaning for many geological data sets. The weighted pair group method and flexible clustering strategy may give an overly conservative partitioning of objects among groups. Clustering by the unweighted pair group method, using the phi coefficient, is recommended for the analysis of biostratigraphic and paleoecologic presence—absence data.     

Generalized Laplace coefficients and Newcomb derivatives

It is shown how the generalized Laplace coefficients can be employed to deduce explicit formulas for ordinary and Newcomb derivatives of the Laplace coefficients.      

GOCE+EGM08+RTM组合模型计算高程异常

针对EGM08重力场模型构建过程中存在的不足,提出用GOCE重力场模型替换EGM08模型的中低频部分,用剩余地形模型RTM拓展EGM08模型的甚高频信号。模拟分析表明,GOCE模型能大幅提高高程异常计算的精度,而RTM对高程异常的贡献也不可忽视。实测GPS/水准数据表明,GOCE模型对高程异常的贡献达到43%,而RTM也贡献了1cm的精度。     

基于分层EOF的深海声速剖面时变特征建模

针对目前局部海域小时间尺度声速场建模方法未顾及不同深度区间内声速变化规律的问题,本文根据实测深海声速剖面的统计特征,提出了声速剖面分层方法,并进一步基于经验正交函数（Empirical Orthogonal Function, EOF）提出了局部小时间尺度的声速剖面分层时变模型构建方法。利用南海实测全海深声速剖面数据,分析了分层EOF第一模态系数和等效平均声速的日变化特征,并比较了不同拟合模型的精度。最后,利用试验海区的温度和潮汐数据分析了声速剖面周期变化的影响因素。结果表明： ①声速剖面分层EOF第一模态系数及等效平均声速具有日周期变化特征,上层声速日周期变化特征不明显,中层声速日周期变化特征较明显,下层声速变化较小但仍具有日周期变化特征;②局部海域小时间尺度声速拟合应考虑长期变化项的影响;③试验海区声速剖面EOF第一模态系数变化与温度显著相关,提取的声速剖面时变特征与海区潮汐周期特征基本吻合。     

闽江流域水体氨氮降解系数实验模拟研究

本研究采用模拟实验对闽江流域氨氮的降解规律进行研究,降解系数采用稳态一维降解模型进行分析计算,闽江上游流域氨氮的平均降解系数为0.140~0.260 d-1,中下游流域氨氮的平均降解系数为0.099~0.203 d-1。结果表明,闽江上游流域氨氮自净能力比中下游流域的自净能力好,古田溪断面的氨氮平均降解系数低于全国的平均值,说明氨氮自净能力相对较弱,本研究为确定流域水环境容量和纳污能力及制定污染物总量控制提供科学依据。     

强迫摇荡运动三维球体水动力系数的CFD计算

采用计算流体力学(CFD)的雷诺平均法(RANS方法),并考虑了自由表面的影响(采用VOF方法模拟自由表面),来模拟三维球体的单自由度强迫摇荡运动,得到纵荡、升沉及横摇的附加质量与阻尼系数。该数值模拟结果与三维势流理论计算的结果进行比较,趋势基本一致,但CFD方法更能凸显粘性的作用。本文所应用方法能合理给出浮式结构物的水动力系数,更精确描述海洋浮式结构物周围的流场,可应用于船舶与海洋工程浮式结构物的水动力性能研究。     

Chalcophile element partitioning between sulfide phases and hydrous mantle melt: Applications to mantle melting and the formation of ore deposits

Understanding the geochemical behavior of chalcophile elements in magmatic processes is hindered by the limited partition coefficients between sulfide phases and silicate melt, in particular at conditions relevant to partial melting of the hydrated, metasomatized upper mantle. In this study, the partitioning of elements Co, Ni, Cu, Zn, As, Mo, Ag, and Pb between sulfide liquid, monosulfide solid solution (MSS), and hydrous mantle melt has been investigated at 1200 °C/1.5 GPa and oxygen fugacity ranging from FMQ−2 to FMQ+1 in a piston-cylinder apparatus. The determined partition coefficients between sulfide liquid and hydrous mantle melt are: 750–1500 for Cu; 600–1200 for Ni; 35–42 for Co; 35–53 for Pb; and 1–2 for Zn, As, and Mo. The partition coefficients between MSS and hydrous mantle melt are: 380–500 for Cu; 520–750 for Ni; ∼50 for Co; <0.5 for Zn; 0.3–6 for Pb; 0.1–2 for As; 1–2 for Mo; and >34 for Ag. The variation of the data is primarily due to differences in oxygen fugacity. These partitioning data in conjunction with previous data are applied to partial melting of the upper mantle and the formation of magmatic-hydrothermal Cu–Au deposits and magmatic sulfide deposits.I show that the metasomatized arc mantle may no longer contain sulfide after >10–14% melt extraction but is still capable of producing the Cu concentrations in the primitive arc basalts, and that the comparable Cu concentrations in primitive arc basalts and in MORB do not necessarily imply similar oxidation states in their source regions.Previous models proposed for producing Cu- and/or Au-rich magmas have been reassessed, with the conclusions summarized as follows. (1) Partial melting of the oxidized (fO₂ > FMQ), metasomatized arc mantle with sulfide exhaustion at degrees >10–14% may not generate Cu-rich, primitive arc basalts. (2) Partial melting of sulfide-bearing cumulates in the root of thickened lower continental crust or lithospheric mantle does not typically generate Cu- and/or Au-rich magmas, but they do have equivalent potential as normal arc magmas in forming magmatic-hydrothermal Cu–Au deposits in terms of their Cu–Au contents. (3) It is not clear whether partial melting of subducting metabasalts generates Cu-rich adakitic magmas, however adakitic magmas may extract Cu and Au via interaction with mantle peridotite. Furthermore, partial melting of sulfide-bearing cumulates in the deep oceanic crust may be able to generate Cu- and Au-rich magmas. (4) The stabilization of MSS during partial melting may explain the genetic link between Au-Cu mineralization and the metasomatized lithospheric mantle.The chalcophile element tonnage, ratio, and distribution in magmatic sulfide deposits depend on a series of factors. This study reveals that oxygen fugacity also plays an important role in controlling Cu and Ni tonnage and Cu/Ni ratio in magmatic sulfide deposits. Cobalt, Zn, As, Sn, Sb, Mo, Ag, Pb, and Bi concentrations and their ratios in sulfide, due to their different partitioning behavior between sulfide liquid and MSS, can be useful indices for the distribution of platinum-group elements and Au in magmatic sulfide deposits.     

Chemical and physical properties affecting strontium distribution coefficients of surficial-sediment samples at the Idaho National Engineering and Environmental Laboratory, Idaho

 The U.S. Geological Survey and Idaho State University, in cooperation with the U.S. Department of Energy, conducted a study to determine strontium distribution coefficients (K_ds) of surficial sediments at the Idaho National Engineering and Environmental Laboratory (INEEL). Batch experiments using synthesized aqueous solutions were used to determine K_ds, which describe the distribution of a solute between the solution and solid phase, of 20 surficial-sediment samples from the INEEL. The K_ds for the 20 surficial-sediment samples ranged from 36 to 275 ml/g. Many properties of both the synthesized aqueous solutions and sediments used in the experiments also were determined. Solution properties determined were initial and equilibrium concentrations of calcium, magnesium, and strontium, pH and specific conductance, and initial concentrations of potassium and sodium. Sediment properties determined were grain-size distribution, bulk mineralogy, whole-rock major-oxide and strontium and barium concentrations, and Brunauer-Emmett-Teller (BET) surface area. Solution and sediment properties were correlated with strontium K_ds of the 20 surficial sediments using Pearson correlation coefficients. Solution properties with the strongest correlations with strontium K_ds were equilibrium pH and equilibrium calcium concentration correlation coefficients, 0.6598 and –0.6518, respectively. Sediment properties with the strongest correlations with strontium K_ds were manganese oxide (MnO), BET surface area, and the >4.75-mm-grain-size fraction correlation coefficients, 0.7054, 0.7022, and –0.6660, respectively. Effects of solution properties on strontium K_ds were interpreted as being due to competition among similarly charged and sized cations in solution for strontium-sorption sites; effects of sediment properties on strontium K_ds were interpreted as being surface-area related. Multivariate analyses of these solution and sediment properties resulted in r² values of 0.8071 when all five properties were used and 0.8043 when three properties, equilibrium pH, MnO, and BET surface area, were used. Received: 30 November 1998 · Accepted: 16 February 1999     

双基地激光测风雷达回波信号仿真研究

本文针对传统的体散射模型并未考虑大气不均匀性对信号传输的影响等问题,通过引入垂直非均匀的大气参数改进了模型,并利用其建立了体目标的双基地激光测风雷达方程,仿真了侧向散射回波信号,并与单基地雷达进行了对比分析。研究表明:水平方向上,双基地激光测风雷达的回波信号分布特征与单基地雷达差异较大,其回波信号等值线在近地面为卵形线,随着探测高度的增加,回波信号等值线逐渐变为以主、被动雷达为焦点的椭圆形,并最终趋近于圆形;垂直方向上,双基地激光测风雷达的回波信号随高度衰减剧烈,近地面的回波能量约为10^-10 J,4 km高度的回波能量约为10^-15J,在中低层大气(0~10 km),回波信号中气溶胶散射占比大,在高层大气(10 km以上),分子散射占比大。