辽东山地老秃顶子冰缘地貌植物群落类型及基本特征

基于48个样地的群落调查数据,运用TWINSPAN分类方法,对辽东山地老秃顶子冰缘地貌植物群落类型进行了划分,并对群落结构、种类组成和生活型谱进行了系统研究.结果表明:老秃顶子冰缘地貌植被可划分为16个森林群系、6个灌丛群系,归并为落叶阔叶林、针阔混交林、暗针叶林、矮曲林、灌丛、灌草丛6个植被型.其中,石海地貌主要发育灌丛和灌草丛,也有针阔混交林和矮曲林分布;石河地貌主要发育针阔混交林和落叶阔叶林,也有暗针叶林分布;石流坡地貌主要发育针阔混交林、落叶阔叶林和灌丛,也有矮曲林分布.老秃顶子冰缘地貌植被由68科138属193种维管束植物组成;石海与石河间植物群落物种组成属中等不相似,而石河与石流坡间属中等相似.老秃顶子冰缘地貌植物群落中高位芽植物占38.0%,隐芽植物占36.3%,地面芽植物占21.8%,地上芽植物和一年生植物均很少,反映出辽东山地冰缘地貌区具有夏季温暖多雨、冬季寒冷漫长的气候特点.相对而言,石海、石流坡地貌中隐芽植物较多,石河地貌中高位芽植物较多,表明石海、石流坡地貌具有更为冷湿的小气候环境.     

绿柱石中隧道水的红外光谱

应用富时叶变换红外谱仪研究了三个启三绿柱石样（包括原样与热处理）。将３４３５ｃｍ＾－１宽吸收带归属于与铁离子成键的水。谱图表明隧道水的大量脱去是在８００℃以上的温度开始的,对于富碱样品,更可能是在１０００℃以后开始。隧道中碱金属离子的阻塞作用是造成绿柱石隧道水难以失去的重要原因．     

Recent Advances in Prediction and Processing of Strong Ground Motions

We present an overview of our recent results on utilizing small earthquakes in the earthquake engineering practice. Site-specific ground motion time-histories of large earthquakes can be successfully simulated using recordings of small earthquakes which are often referred to as 'empirical Green's functions' in seismology. Another important practical problem is whether and how these observations can be used in seismic risk studies which are based on empirical attenuation relations for ground motion parameters. We study a possibility of extrapolating attenuation relations for small earthquakes, to larger magnitudes using the data from the Garner Valley downhole array in Southern California. Finally we introduce efficient ground motion processing techniques in frequency- and time-domains and apply them to site response estimation.     

Calculation of the UV Absorption Spectra of As(III) Oxo- and Thio- Acids and Anions in Aqueous Solution and of PF3 in the Gas-phase

Changes in the UV spectra of As(OH)₃ solutions with variations in pH and temperature have recently been used to determine the temperature dependence of the pK_a of the acid. In previous studies I used quantum mechanical techniques to study changes in structure and vibrational spectra as a function of pH for arsenites and thioarsenites. I previously calculated UV spectra for ``molecular' minerals, like realgar As₄S₄. Here I use a number of different quantum mechanical methods, both Hartree-Fock and density functional theory based, to calculate the UV spectra for both a related simple well-characterized gas-phase molecule PF₃ and for As(OH)₃ and As(SH)₃ and their conjugate anions and some neutral and anionic oligomers in aqueous solution. For the monomeric species small numbers of water molecules have been explicitly included, in a supermolecule or microsolvation approach. I find that UV absorption energies accurate to a few tenths of an eV can be obtained both for gas- phase PF₃ and for neutral arsenious acid in aqueous solution, for which the UV absorption maximum is calculated to occur around 6.5 eV, consistent with experiment. Accurate calculation of the UV energies for arsenite anions in aqueous solution is much more difficult, since basis set size and solvation effects are considerably larger than for the neutral molecules, but fairly reliable results can still be obtained. Deprotonation is found to reduce the lowest calculated UV transition energy by about half an eV. Oligomerization also reduces the lowest calculated UV energy by at least half an eV. Replacement of one or all the –OH groups by –SH groups reduces the lowest calculated UV energies by about 2 eV. UV excitation energies have been calculated for oligomeric species as large as As₃E₃(EH)₃ and As₄E₆, where E = O, S, and may be useful for identifying such species in solution.     

生物成因与无机成因文石的FTIR光谱区别

对16种贝壳交叉页片层中生物成因文石的FT IR谱进行测量,并与无机成因文石进行对比和统计分析后,首次发现生物成因与无机成因文石的FT IR光谱有明显可区分的特征,生物成因文石2ν带(面外弯曲振动)频率平均值为863.4 cm-1,而无机成因文石该带的平均值为855.5 cm-1,两者频率位移达7.9 cm-1。因此文石的2ν带可作为指纹带鉴别生物和无机成因文石。     

AHDEB油田白垩系油藏油气充注期次的流体包裹体证据

伊拉克AHDEB油田油藏成藏规律对油田后期开发具有重要意义, 与埋藏史相结合的流体包裹体研究是揭示油藏油气成藏期次和时间的有效手段.利用伊拉克AHDEB油田白垩系油藏储层样品对流体包裹体特征进行了分析, 并且通过流体包裹体的显微观察、荧光颜色、单一包裹体的红外光谱和均一温度测定, 结合地质背景对该油田的油充注期次进行了研究.研究表明, 油包裹体以发绿色和黄绿色荧光为主, 少数发浅黄色和黄褐色荧光.油包裹体的显微傅立叶红外光谱测定结果计算的CH_2a/CH_3a、X_inc、X_std可划分油的成熟度, 表明存在两种成熟度的油.最后, 根据均一温度测定结果, 结合埋藏史和热史, 认为该油田可能存在4期油充注成藏相关的流体活动: 第1成藏期发生在95.0~96.5Ma, 相当于晚白垩世早期; 第2成藏期为71.0~78.5Ma, 相当于晚白垩世晚期, 第1期和第2期烃源岩排烃规模小, 产生中-重质油, 后期遭受氧化而形成沥青; 第3成藏期发生在14.0~15.0Ma, 相当于中中新世, 处于生排烃高峰期, 为主要成藏期; 第4期发生在10.0Ma左右, 与第3期为多幕连续充注.      

红外光谱方法在找金中的应用综述

从四个方面介绍了红外光谱在金矿普查评价中的应用：石英薄片中气液包裹体与金的关系研究；石英中杂质阳离子与金的关系研究；黄铁矿与金的关系研究；金矿区氧化带和矿带共生组合矿物研究。     

显微荧光光谱技术在油气成藏研究中的应用——以塔里木盆地巴什托上古生界油气藏为例

根据原油在紫外光的激发下产生荧光的特点,通过显微荧光光谱方法,对有机包裹体的荧光光谱进行定量化分析,利用其主峰波长与荧光强度、主峰波长与红/绿商的相关性,对塔里木盆地巴什托上古生界油气藏的成藏特征进行了初步研究。在研究区所采集的32块岩石样品中共获得64个荧光光谱数据。分析结果表明,巴什托上古生界油气藏存在3个油源,其主峰波长主要集中在439~443nm、469~472 nm和498~503 nm三个值段上,且为不同演化阶段的混源充注。前两者来自于寒武—奥陶系烃源岩,由下至上充注成藏;后一油源来自于石炭系巴楚组,随演化程度的变化同时向上、下两个方向充注。综合同期捕获不同主峰波长的有机包裹体,推测研究区至少存在4期油充注、1期天然气充注。     

云南金顶异极矿晶体化学特征与颜色成因探讨

为研究云南金顶铅锌矿床中异极矿谱学特征和颜色成因,利用湿法化学全分析、振动光谱仪、X光粉晶衍射仪和电子探针对5组异极矿样品谱学特征和化学成份进行研究。湿法化学全分析得出了异极矿的化学成份,成份中出现了可能致色的铜、铁和镍元素;X光粉晶衍射和振动光谱分析得出异极矿晶胞参数和特征谱线表明样品蓝色和白色环带均为异极矿,5组样品的平均晶胞参数为：a=0．8372nm,b=1．0702nm,c=0．5116nm;红外光谱测试中获得了未见报道的452cm。以下异极矿晶体结构吸收峰,同时分析了异极矿中的结构水、结晶水吸收谱带;对红外光谱和拉曼光谱中的各吸收谱带和特征峰进行了归属。通过电子探针、红外光谱、拉曼光谱测试和分析认为异极矿的蓝色与Cu^2＋的类质同像替代有关,白色异极矿不含铜元素,白色和蓝色异极矿结构相似,异极矿玻璃光泽和土状光泽与其含有较多的结晶水有关。     

煤中惰质组在泥炭沼泽古环境研究中的应用

惰质组是煤中一种常见的显微组分。它不仅能用来鉴别成煤前植物的木炭化程度,而且还是泥炭沼泽古环境恢复的有效途径。近年来,欧洲学者利用惰质组成功推算了地史时期三叠纪—侏罗纪之交(T—J)的古火灾温度及类型,并重建了古植被类型及泥炭沼泽古生态环境变化。与其它方法相比,利用煤中惰质组含量及其反射率进行古环境恢复的工作对于植物种类繁多、沉积岩层中夹杂的煤层或煤炭、尤其对于古气候环境波动较大的地质转折时期最为理想。因此,利用惰质组的部分参数对我国含煤沉积盆地的古生态恢复以及成煤环境的研究有积极的借鉴意义。