The extended N2 method taking into account higher mode effects in elevation

The N2 method has been extended in order to take into account higher mode effects in elevation. The extension is based on the assumption that the structure remains in the elastic range when vibrating in higher modes. The seismic demand in terms of displacements and storey drifts can be obtained by enveloping the results of basic pushover analysis and the results of standard elastic modal analysis. The approach is consistent with the extended N2 method used for plan‐asymmetric buildings. The proposed procedure was applied to three variants of three steel frame buildings used in the SAC project. The structural response was investigated for two sets of ground motions. Different ground motion intensities were used in order to investigate the influence of the magnitude of plastic deformations. The N2 results were compared with the results of nonlinear response‐history analysis, two other pushover‐based methods (modal pushover analysis (MPA) and modified MPA (MMPA)), and pushover analysis without consideration of higher modes. It was found that a considerable influence of higher modes on storey drifts is present at the upper part of medium‐and high‐rise structures. This effect is the largest in the case of elastic behaviour and decreases with ground motion intensity. The higher mode effects also depend on the spectral shape. The approximate methods (extended N2, MPA and MMPA) are able to provide fair estimates of response in the case of the test examples. Accuracy decreases with the height of the building, and with the intensity of ground motion. The N2 results are generally conservative. Copyright © 2011 John Wiley & Sons, Ltd.     

Geochemical environment of Cenomanian - Turonian black shale deposition at Wunstorf (northern Germany)

Major- and minor- element determinations were carried out on a high-resolution sample set obtained from a sediment drill core at Wunstorf (N. Germany). This study interval includes the black shale-bearing Hesseltal Formation associated with the Oceanic Anoxic Event 2 (OAE 2), also referred to as Cenomanian-Turonian Boundary Event (CTBE). Seven black shale packages, each containing several black shale layers, were defined by elevated TOC values, with black shale packages 1-4 deposited during OAE 2. Packages 5-7 extend above the level of the positive carbon-isotope excursion defining OAE 2, indicating that conditions favouring organic carbon burial must have prevailed longer in the Wunstorf Basin than elsewhere. Geochemical analyses revealed no significant differences between black shale packages deposited during and after OAE 2. Enrichment patterns of sulphur, iron and redox-sensitive and sulphide-forming trace metals point to suboxic to anoxic conditions existing at the sediment-water interface during black shale deposition, whereas sulphidic conditions prevailed deeper in the sediment. Variations in element/Al ratios follow cyclic patterns which are interpreted to represent climatically-induced changes in sediment supply. Reduced vertical mixing led to water-column stratification and caused black shale deposition.     

习水县岩溶水系统ρ(Sr2+)、ρ(Sr)/ρ(Ca)、ρ(Sr)/ρ(Mg)分布特征及其应用

通过对流域内不同类型水取样分析,发现流经不同岩层的地下水具有不同的ρ(Sr2+)、ρ(Sr)/ρ(Ca)、ρ(Sr)/ρ(Mg)值.一般来说,流经砂岩层的基岩裂隙水ρ(Sr2+)低,而ρ(Sr)/ρ(Ca)、ρ(Sr)/ρ(Mg)值较高,当砂岩中的基岩裂隙水受到灰岩岩溶水或煤系地层水补给时,其ρ(Sr2+)、ρ( Sr...     

Amplitude Variation with Offset Responses Modeling Study of Walkaway Vertical Seismic Profile Data at CO2 Geological Storage Site, Ketzin, Germany

An important component of any CO2 sequestration project is seismic monitoring for tracking changes in subsurface physical properties, such as velocity and density. Different reservoirs have different amplitude variation with offset (AVO) responses, which can define underground conditions. In the present paper we investigate walkaway vertical seismic profile (VSP) AVO response to CO2 injection at the Ketzin site, the first European onshore CO2 sequestration pilot study dealing with research on geological storage of CO2. First, we performed rock physics analysis to evaluate the effect of injected CO2 on seismic velocity using the Biot-Gassmann equation. On the basis of this model, the seismic response for different CO2 injection saturation was studied using ray tracing modeling. We then created synthetic walkaway VSP data, which we then processed. In contrast, synthetic seismic traces were created from borehole data. Finally, we found that the amplitude of CO2 injected sand layer with different gas saturations were increased with the offset when compared with the original brine target layer. This is the typical class III AVO anomaly for gas sand layer. The AVO responses matched the synthetic seismic traces very well. Therefore, walkaway VSP AVO response can monitor CO2 distribution in the Ketzin area.     

Early Cambrian Mollusc Watsonella crosbyi: A Potential GSSP Index Fossil for the Base of the Cambrian Stage 2

The mollusc Watsonella crosbyi was studied on the basis of material from the lower Cambrian Dahai Member of the Zhujiaqing Formation in eastern Yunnan, China and the Pestrotsvet Formation of the Aldan River region in the Siberian Platform. This fossil had been excessively described under different names in the literature, such as Heraultia varensalensis Cobbold, 1935, H. sibirica Missarzhevsky, 1974, Heraultipegma yunnanensis He and Yang, 1982, H. yannanese He and Yang, 1982, Watsonella yunnanensis, W. crosbyi Grabau, 1900, etc. Taxonomic revision shows that other species are junior synonyms of W. crosbyi. Analysis of functional morphology implies that W. crosbyi may be rather a helcionelloid than a rostroconch since its univalved conch is untorted endogastric and lacks a rostrum and a true internal pegma. Replicas of the original microstructures preserved on the surfaces of phosphatic internal moulds confirm that the shell consists of two layers. The inner layer is lamello-fibrillar, and the outer layer is spherulitic prismatic. The widespread geographical occurrences in both siliciclastic and carbonate rocks of the late Terreneuvian indicate that W. crosbyi is an important index fossil for global correlations and subdivision of the Cambrian Series 1 (Terreneuvian). The first appearance datum (FAD) of W. crosbyi is suggested to be a potential GSSP (Global Boundary Stratotype Section and Point) candidate marker for defining the base of the Cambrian Stage 2.     

Theoretical Prediction of Gibbs Free Energies of Formation for Crystalline α-MOOH and α-M2O3 Based on a Linear Free-Energy Relationship

In the present study, the modified Sverjensky–Molling equation, derived from a linear-free energy relationship, is used to predict the Gibbs free energies of formation of crystalline phases of α-MOOH (with a goethite structure) and α-M2O3 (with a hematite structure) from the known thermodynamic properties of the corresponding aqueous trivalent cations (M3+). The modified equation is expressed as ΔG0f,MVX=aMVXΔG0n,M3++bMVX+βMVXγM3+, where the coefficients aMVX, bMVX, and βMVX characterize a particular structural family of MvX (M is a trivalent cation [M3+] and X represents the remainder of the composition of solid); γ3+ is the ionic radius of trivalent cations (M3+); ΔG0f,MVX is the standard Gibbs free energy of formation of MvX; and ΔG0n,M3+ is the non-solvation energy of trivalent cations (M3+). By fitting the equation to the known experimental thermodynamic data, the coefficients for the goethite family (α-MOOH) are aMVX=0.8838, bMVX=?424.4431 (kcal/mol), and βMVX=115 (kcal/mol.?), while the coefficients for the hematite family (α-M2O3) are aMVX=1.7468, bMVX=?814.9573 (kcal/mol), and βMVX=278 (kcal/mol.?). The constrained relationship can be used to predict the standard Gibbs free energies of formation of crystalline phases and fictive phases (i.e. phases that are thermodynamically unstable and do not occur at standard conditions) within the isostructural families of goethite (α-MOOH) and hematite (α-M2O3) if the standard Gibbs free energies of formation of the trivalent cations are known.     

P-G交汇技术在SY地区中的应用

SY地区须家河组二段（下砂）储层类型复杂,各井中均见到砂层,但该砂层储集体有的为高孔隙而有的则致密,在区域平面上表现出分布不均匀的特点。对该段储层预测方法及种类也有较多,但常规叠后反演很难对其进行区分和识别。利用叠前AVO技术,建立储层段的AVO正演模型并采用相应的工作流程,然后利用P-G交汇法对砂岩储层进行解释,发现含气储层与非含气储层的P-G交汇特征不同,砂岩储层含气后则具有交汇趋势线角度增大及远离背境趋势线的特征;而砂岩非储层则相反;其次储层段的P-G交汇点所分布的象限也不相同。通过这些特征,对全区现有钻遇该储层段的钻井进行预测,预测结果和钻井气测情况相吻合,取得了如期效果。     

自然邻点插值算法及其在二维不规则数据网格化中的应用

由于观测数据的不足,对不规则散点数据的二维插值在地球物理中应用非常广泛。这里研究并实现了自然邻点二维插值算法,并以一个大地电磁测深反演数据为例,验证了该方法的可行性与效果。实际资料试算与成图结果表明,该方法具有精度高、插值效果好、速度快以及便于模拟地形数据等优点。     

Local, global and virtual buzz: The importance of face-to-face contact in economic interaction and possibilities to go beyond

Novel information and communication technologies have created new possibilities for transferring information and knowledge over distance. Although this might open up broad options for economic interaction, knowledge regarding the effects of these changes on the geographies of production and innovation is still incomplete. Under these circumstances, permanent co-location and face-to-face (F2F) interaction may be efficient in some contexts but not in others. Support by computer-mediated communication (CMC), temporary, and virtual interaction is increasingly becoming the basis for establishing trans-local production networks. By combining results from social psychology with economic geography, it is argued that there is no generally superior spatial fix for economic interaction. Different spatial configurations can be advantageous in different production and innovation contexts, even over large distances without permanent or even regular F2F contact. This paper systematically investigates the effects of new communication technologies and different organisational forms for economic interaction by emphasizing the potential of combining CMC with forms of temporary and permanent F2F interaction.     

Associated terrestrial and marine fossils in the late-glacial Presumpscot Formation, southern Maine, USA, and the marine reservoir effect on radiocarbon ages

Excavations in the late-glacial Presumpscot Formation at Portland, Maine, uncovered tree remains and other terrestrial organics associated with marine invertebrate shells in a landslide deposit. Buds of Populus balsamifera (balsam poplar) occurred with twigs of Picea glauca (white spruce) in the Presumpscot clay. Tree rings in Picea logs indicate that the trees all died during winter dormancy in the same year. Ring widths show patterns of variation indicating responses to environmental changes. Fossil mosses and insects represent a variety of species and wet to dry microsites. The late-glacial environment at the site was similar to that of today's Maine coast. Radiocarbon ages of 14 tree samples are 11,907 ± 31 to 11,650 ± 50 ¹⁴C yr BP. Wiggle matching of dated tree-ring segments to radiocarbon calibration data sets dates the landslide occurrence at ca. 13,520 + 95/−20 cal yr BP. Ages of shells juxtaposed with the logs are 12,850 ± 65 ¹⁴C yr BP (Mytilus edulis) and 12,800 ± 55 ¹⁴C yr BP (Balanus sp.), indicating a marine reservoir age of about 1000 yr. Using this value to correct previously published radiocarbon ages reduces the discrepancy between the Maine deglaciation chronology and the varve-based chronology elsewhere in New England.