贵州百花湖分层晚期有机质降解过程与溶解N2O循环

百花湖是一个具有季节性分层的富营养小型湖泊,在秋季湖水倒转期经常发生水质恶化事件,碳氮循环出现异常。文章研究特选择在秋初,湖泊分层开始消失时,测定了湖水中不同深度的N₂O,CH₄,CO₂,有机和无机碳同位素以及其他化学参数变化。结果发现:采样时百花湖在约6m和16m深度附近出现了两个温度不连续层(SDL和PDL),并影响到有机颗粒的沉降和分解。相对而言,有较多的有机质在这两个层内发生降解,但降解的途径有所不同,上部主要是有氧降解,下部则主要是无氧降解过程。N₂O的产生和消耗与有机质的降解过程完全对应:PDL层以上,ΔN₂O与AOU的线性关系反映了N₂O主要形成于硝化作用;PDL层以下反硝化作用导致N₂O严重不饱和;PDL内位于硝化作用和反硝化作用过渡带的N₂O峰,显然是硝化与反硝化联合作用的结果。PDL层内较大的CH₄浓度变化梯度,说明嗜甲烷细菌可能通过氧化NH+4贡献了部分N₂O。百花湖秋、冬季表层湖水N₂O都是过饱和的,都是大气N₂O的源,依据分子扩散模型计算湖泊N₂O的释放通量在12～14μmol/m·day之间,秋、冬季没有明显的差别。秋季底层湖水的反硝化作用是湖泊N₂O的汇,其消耗通量与表层的释放通量基本相当。     

Experimental research on reservoir sensitivity to stress and impacts on productivity in Kela 2 Gas Field

Kela 2 Gas Field, with high formation pressure (74.35MPa), high pressure coefficient (2.022) and difficulty of potential test and evaluation, is the largest integrated proved dry gas reservoir in China so far and the principal source for West-East Gas Development Project. In order to correctly evaluate the elastic-plastic deformation of rocks caused by the pressure decline during production, some researches, as the experiment on reservoir sensitivity to stress of gas filed with abnormal high pressure, are made. By testing the rock mechanic properties, porosities and permeabilities at different temperature and pressure of 342 core samples from 5 wells in this area, the variations of petro-physical properties at changing pressure are analyzed, and the applicable inspection relationship is concluded. The average productivity curve with the reservoir sensitivity to stress is plotted on the basis of the research, integrated with the field-wide productivity equation. The knowledge lays a foundation for the gas well productivity evaluation in the field and the gas field development plan, and provides effective techniques and measures for basic research on the development of similar gas fields.     

Determination of S-wave velocity structure using microtremors and spac method applied in Thessaloniki (Greece)

Array measurements of microtremors at 16 sites in the city of Thessaloniki were performed to estimate the V_s velocity of soil formations for site effect analysis. The spatial autocorrelation method was used to determine phase velocity dispersion curves in the frequency range from 0.8–1.5 to 6–7 Hz. A Rayleigh wave inversion technique (stochastic method) was subsequently applied to determine the Vs profiles at all the examined sites. The determination of V_s profiles reached a depth of 320 m. Comparisons with V_s values from cross-hole tests at the same sites proved the reliability of the SPAC method. The accuracy of the V_s profiles, the ability to reach large penetration depths in densely populated urban areas and its low cost compared to conventional geophysical prospecting, make Mictrotremor Exploration Method very attractive and useful for microzonation and site effects studies. An example of its application for the site characterization in Thessaloniki is presented herein.     

Optimizing a layered and laterally constrained 2D inversion of resistivity data using Broyden's update and 1D derivatives

Dense profile-oriented resistivity data allows for 2D and 3D inversions. However, huge amounts of data make it practically impossible to do full 2D or 3D inversions on a routine basis. Therefore, a number of approximations have been suggested over the years to speed up computations. We suggest using a combination of Broyden's update on the Jacobian matrix with derivatives calculated using a 1D formulation on a parameterized 2D model of locally 1D layered models. The approximations bring down the effective number of 2D forward responses to a minimum, which again gives us the ability to invert very large sections. Broyden's update is not as useful with a parameterized problem as is the case with a smooth minimum structure problem that has been the usual application. 1D derivatives, however, seem to be very effective when initiating a full 2D solution with Broyden's update. We compare the different methods using two different kinds of data on two synthetic models and on two field examples. The most effective and reliable optimization combines 1D derivatives with a full 2D solution and Broyden's update. When using Broyden's update the Jacobian matrix needs to be reset every once in a while. We do this whenever the difference in data residual from the previous iteration is less than 5%. This combined inversion method reduces the computation time approximately a factor of 3 without losing model resolution.     

风云2号卫星云图在短时强对流天气预报中的应用

利用风云2号水汽通道的云图进行强对流天气的临近预警，发现每小时1次的风云2号云图对强对流天气有着重要指示作用，尤其水汽图反映了大气中上层的水汽分布，水汽区的活动、干湿区边界、暗区等都与强对流的发生发展有着密切关系，并找出了可以作为临近预警的关键指标，在2003年的几次强对流天气预报中，风云2号云图发挥了很好的作用。     

CAPPS1和CAPPS2数值预报模式对比分析

对CAPPS1模式和CAPPS2模式预报广西污染物进行了对比分析。主要对比了其污染扩散原理、气象预报模式、操作系统、运行时间、预报时效及预报效果。分析表明：CAPPS1和CAPPS2模式对各种污染物预报的相关系数均在0．44以上，两种模式预报广西空气污染都是可行的；两种模式均对SO2的预报效果最好，NO2次之，PM10相对最差；CAPPS2模式对各种污染物的预报值与实测值相关系数均比CAPPS1高，其中NO2的相关系数提高幅度最大；CAPPS2模式对NO2和PM10的预报准确率比CAPPS1偏高，而对SO2的预报准确率比CAPPS1偏低；CAPPS2预报首要污染物正确率比CAPPS1高出11个百分点，而预报首要污染物等级正确率则高出9个百分点。     

6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜的显色反应及其应用

在pH10～12的Na2B4O7-NaOH缓冲溶液中,TritonX-100表面活性剂存在下,6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜发生显色反应,生成2∶1的深红色配合物。配合物的最大吸收峰位于535nm处,表观摩尔吸光系数1.42×105L·mol-1·cm-1。Cu2+的浓度在0～400μg/L符合比尔定律。用拟定方法测定铝合金及铜矿石样品中的微量铜,结果与原子吸收法结果相符,6次测定的RSD<3%。     

简要介绍R2V的功能及其在数字化图件中的应用

许多物化探及地质成果资料以纸质图件保存,在资料的再利用时需对其进行数字化.这里简要介绍一种数字化功能强大的矢量化软件-R2V的功能,针对物化探图件的特点,探讨了R2V数字化的流程.     

The Solubility of Sulphur in Hydrous Rhyolitic Melts

Experiments performed at 2 kbar, in the temperature range 800–1000°C,with fO₂ between NNO–2·3 and NNO+2·9 (whereNNO is the nickel–nickel oxide buffer), and varying amountsof sulphur added to hydrous metaluminous rhyolite bulk compositions,were used to constrain the solubility of sulphur in rhyolitemelts. The results show that fS₂ exerts a dominant control onthe sulphur solubility in hydrous silicate melts and that, dependingon fO₂, a rhyolitic melt can reach sulphur contents close to1000 ppm at high fS₂. At fO₂ below NNO+1, the addition of ironto a sulphur-bearing rhyolite magma produces massive crystallizationof pyrrhotite and does not enhance the sulphur solubility ofthe melt. For a given fO₂, the melt-sulphur-content increaseswith fS₂. For fixed fO₂ and fS₂, temperature exerts a positivecontrol on sulphur solubilities, at least for fO₂ below NNO+1.The mole fraction of dissolved sulphur exhibits essentiallylinear dependence on fH₂S at low fO₂ and, although the experimentalevidence is less clear, on fSO₂ at high fO₂. The minimum insulphur solubility corresponds to the redox range where bothfH₂S and fSO₂ are approximately equal. A thermodynamic modelof sulphur solubility in hydrous rhyolite melts is derived assumingthat total dissolved sulphur results from the additive effectsof H₂S and SO₂ dissolution reactions. The model reproduces wellthe minimum of sulphur solubility at around NNO+1, in additionto the variation of the sulphide to sulphate ratio with fO₂.A simple empirical model of sulphur solubility in rhyoliticmelts is derived, and shows good correspondence between modeland observations for high-silica rhyolites. KEY WORDS: sulphur; solubility; rhyolite; thermodynamics; fO₂; fS₂     

内蒙古温带半干旱羊草草原N2O通量及其影响因素

利用静态箱 -气相色谱法于 2 0 0 1～ 2 0 0 3年对内蒙古锡林河流域羊草草原进行了连续 2年的野外定位试验 ,获得羊草草原原状群落与土壤N2 O年排放通量分别在 3 91～ 4 71μgm- 2h- 1以及 5 5 0～ 10 0 3μgm- 2 h- 1范围内变动 ,证明内蒙古温带半干旱羊草草原生态系统是大气中N2 O的源 ;系统分析了羊草草原N2 O通量的季节变化、源汇特征以及关键的环境因子对草地N2 O通量的影响等 ,建立了N2 O通量与环境因子间的回归方程 ;并利用两年连续完整的观测数据对羊草草原N2 O年排放量进行了估算