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411.
基于有限元方法,采用2015年尼泊尔MW7.8地震震后5 a的GPS观测资料约束青藏高原南缘的岩石圈流变结构,利用通过主前缘逆冲断裂带(MFT)间的距离来约束边界位置的垂直边界结构和印度弹性俯冲板片结构探测印度板块和青藏高原板块的边界结构。结果表明,2种结构均能产生与观测数据一致的南-西南水平运动模式,并能较好地解释远场地面位移,但垂直边界结构模型得到的垂直形变偏大,而俯冲板片结构模型能很好地解释中尼边境及以北地区的隆升现象。青藏高原下地壳稳态和瞬态粘滞系数的最优结果分别为1×1018 Pa·s和1×1017 Pa·s。 相似文献
412.
收集及处理尼泊尔境内的GPS连续观测站和中国藏南地区的GPS基准站数据,获得2015年尼泊尔MW7.8地震震后3 a的GPS水平形变场。结果显示,尼泊尔地震的震后形变主要分布于尼泊尔北部及中尼边境区域,且东西方向形变较小,南北方向形变较大,整体继续向南运动,最大震后位移约为10.93 cm。采用孔隙弹性回弹模型计算的理论地表位移远小于GPS观测值,无法解释GPS观测到的震后形变。采用震后余滑模型反演的结果表明,震后余滑主要集中在断层的下倾延伸部分,且空间分布较广,余滑释放的地震矩为1.09×1020 Nm。采用PSGRN/PSCMP程序计算粘弹性引起的理论地表形变结果显示,粘弹性松弛模型不能解释近场GPS观测值,但在远场区域的运动方向与GPS观测值一致。采用粘弹性松弛和震后余滑组合机制模型进行反演,余滑释放的地震矩降为1.08×1020 Nm,且空间分布更加集中。研究结果表明,组合机制模型在保证了模型拟合精度的基础上,反演结果与应力驱动模型反演结果更接近。 相似文献
413.
Characterization of humic substances by advanced solid state NMR spectroscopy: Demonstration of a systematic approach 总被引:2,自引:0,他引:2
Characterization of humic substances is challenging due to their structural complexity and heterogeneity. Solid state nuclear magnetic resonance (NMR) is regarded as one of the best tools for elucidating structures of humic substances. The primary solid state NMR technique that has been used so far is the routine 13C cross polarization-magic angle spinning (CP-MAS) technique. Although this technique has markedly advanced our understanding of humic substances, the full potential of NMR for characterizing humic substances has yet to be realized. Recent technical developments and applications of advanced solid state NMR have revealed the promise to provide deeper insights into structures of humic substances. In this paper, we summarized and demonstrated the systematic solid state NMR protocol for characterization of humic substances using a humic acid as an example. This protocol included (1) identification of specific functional groups using spectral editing techniques, occasionally assisted by 1H13C two-dimensional heteronuclear correlation (2D HETCOR) NMR, (2) quantification of specific functional groups based on direct polarization-magic angle spinning (DP-MAS) and DP-MAS with recoupled dipolar dephasing, combined with spectral editing techniques, (3) determination of connectivities and proximities of specific functional groups by 1H13C 2D HETCOR or 2D HETCOR combined with spectral editing techniques, and (4) examination of domains and heterogeneities by 1H13C 2D HETCOR with 1H spin diffusion. We used a soil humic acid as an example to demonstrate how this protocol was applied to the characterization of humic substances step by step. Afterwards, based on typical 13C NMR spectra of humic substances we described how we could combine different NMR techniques to identify specific functional groups band by band from downfield to upfield. Finally, we briefly mentioned the potential new NMR techniques that could be developed to enrich the current systematic protocol. This systematic protocol is not only applicable to humic substances but also to other natural organic matter samples. 相似文献
414.
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417.
Quantitative precipitation forecasts: a statistical adaptation of model outputs through an analogues sorting approach 总被引:2,自引:0,他引:2
Medium-term quantitative precipitation forecasts (QPFs) up to several days ahead are required to issue early flood warnings and to allow optimum operation of hydraulic structures or reservoirs. This paper describes an approach which can be seen as an adaptation of deterministic meteorological model outputs. It involves searching for a sample of past situations similar to the current one from a long meteorological archive. The analogy is considered in terms of general circulation patterns over a window covering western Europe. For this restricted sample of days similar to the day at hand, the corresponding sample of observed daily precipitation is extracted for each catchment. The rainfall to be observed during the current day is assumed to follow the same distribution, known from this empirical sample. This provides a probabilistic forecast expressed, for example, by a central quantile and a confidence range. This paper describes the many choices underlying the optimisation of this approach: choice of predictor variables to characterise a meteorological situation, choice of similarity criterion between two situations, criterion for performance evaluation between two versions of the algorithm, etc. This method was calibrated over about 50 catchments located in France, Italy and Spain, using a meteorological and hydrological archive running from 1953 to 1996. Comparisons carried out over a validation sample (1995–1996) with three poor-man methods prove the interest of this approach, in a perfect prognosis context. In real-time operation, the use of forecast instead of observed predictor variables, essentially geopotential fields, produces only a minor decrease in performance. The use of the single-valued central quantile supplemented by the confidence interval provided a QPF that has proved effective and informative on the potential for extreme values. 相似文献
418.