三元体系Mg~(2 )/Cl~-,Borate—H_2O25℃相关系和溶液性质的研究

用等温溶解法测定了Mg2+／Cl-，Borate-H2O三元体系25℃时的溶解度．此三元体系等温溶解度图为简单共饱型，它的平衡固相分别为三方硼镁石（Mg2B12O20·15H2O）和MgCl2·6H2O，未产生新的复盐或固溶体。拟合了MgB6O10随MgCl2浓度变化的溶解度曲线方程，并且对平稳溶液的物化性质（密度、粘度、折光率、电导、pH值）进行了测定，用半经验公式描述了一些物化性质随浓度的变化规律，结果令人满意。     

Critical evaluation and geological correlation of teleseismic phase data from Indian seismological stations

We evaluated the quality of seismic phase data from Indian seismological stations through the analysis of teleseismic travel times reported during 1976–83 and infer that only WWSSN stations (NDI, SHL, POO, KOD) apart from GBA and HYB can be rated satisfactory while the majority of stations (more than 40) produce very poor quality data sets. Detailed analysis of teleseismic P-wave travel time residuals shows that while the average structure of the upper mantle beneath India has high velocity (negative residuals) there are marked lateral variations. In particular, three zones of anomalous positive residuals (low velocity) are observed: one beneath the north western part of the Deccan trap, the second covering the southernmost peninsula (granulite terrain) and a third rather localized one, to the north of Delhi coinciding with Delhi-Haridwar ridge. New Delhi exhibits strong negative residuals in the E-SE quadrant along with negative station anomaly, implying that it is underlain by an anomalous high velocity crust/upper mantle. The negative residuals observed over India, continue beneath the Himalaya till the south of Lhasa but change sign further northward, suggesting the northern limit of the Indian upper mantle structure.     

长江下游地区地震的日月周期性

根据重力固体潮理论值公式,计算长江下游地区地震(M_s≥5.0,1900～1990)的各位相值,按Schuster检验和χ2检验进行判定,发现该地区的地震具有下述非随机的月亮和太阳的周期性:(1)半日周期,表现为太阳时角变化的半周期(P_R=0.023,χ2=7.576)和半日固体潮周期(P_R=0.017,χ2=8.167);(2)半月周期,表现为半个朔望月周期(P_R=0.011,χ2=8.985)和双周潮周期(P_R=0.061,χ2=5.588);(3)对M_s≥5.1地震,还显示出1年的周期,太阳黄经的P_R=0.035,χ2=6.712。对M_s≥5.2地震,还存在半个月球近地点黄经变化周期(P_R=0.043,χ2=6.309)。     

相图测定成矿压力方法的评述

本文对国内外广泛应用相图测定成矿压力的方法进行了评述。文中讨论了引起相图测定成矿压力不确切性的各种因素,并提出了消除或减弱这些影响因素的措施,以利于进一步提高利用相图进行成矿压力测定的精度。     

Thermodynamic modeling of binary CH4–CO2 fluid inclusions

An equation of state (EOS) explicit in Helmholtz free energy has been improved to calculate the PVTx and vapor–liquid phase equilibrium properties of CH₄–CO₂ fluid mixture. This EOS, where four mixing parameters are used, is based on highly accurate EOSs recommended by NIST for pure components (CH₄ and CO₂) and contains a simple generalized departure function presented by Lemmon and Jacobsen (1999). Comparison with experimental data available indicates that the EOS can calculate both vapor–liquid phase equilibrium and volumetric properties of this binary fluid system with accuracy close to that of experimental data up to high temperature and pressure within full range of composition. The EOS of CH₄–CO₂ fluid, together with the updated Gibbs free energy model of solid CO₂ (dry ice), is applied to calculate the CH₄ content (x_CH4) and molar volume (V_m) of the CH₄–CO₂ fluid inclusion based on the assumption that the volume of an inclusion keeps constant during heating and cooling. $V_{\text{m}}-x_{{\text{CH}}_4}$ diagrams are presented, which describe phase transitions involving vapor, liquid and CO₂ solid phases of CH₄–CO₂ fluid inclusions. Isochores of CH₄–CO₂ inclusions at given $x_{{\text{CH}}_4}$ and V_m can be easily calculated from the improved EOS.     

热带平流层CO浓度准两年振荡的位相变化特征

利用2005~2014年10年的卫星微波临边探测仪（MLS）资料分析了热带平流层一氧化碳（CO）体积混合比的年际变率,发现热带平流层CO浓度的准两年振荡（QBO）在30 hPa高度附近存在明显的位相变化特征。大气化学气候模式模拟结果表明,热带平流层CO的准两年振荡信号是化学和动力过程共同作用的结果,而动力作用主要是QBO引起的次级经向环流引起的物质传输。化学和动力过程共同作用导致热带平流层CO浓度的垂直梯度在30 hPa高度处发生反转,进而产生一氧化碳QBO信号的位相变化。此外,化学气候模式模拟结果还表明,与CO有关的化学过程不但可以减弱一氧化碳QBO信号的振幅,还可以在热带30~10 hPa高度范围内造成一氧化碳QBO和纬向风QBO信号之间约3个月的时间差。     

渤海中部海底恒温层温度及泥温相位随深度变化特征

利用渤海中部两点一年中４个季节泥温观测资料，近似确定两测点海底恒温层泥温分别为１１．０℃和１１．７℃。认国泥温随深度变化可视为一垂向波－泥温波，并利用这一概念分析了泥温相位随深度变化特征，８＾＃，Ａ（Ｂ）平台测点泥温波波长分别为ｌ８＝８ｍ和ｌＡ（Ｂ）＝１０ｍ。研究建议，以０．５ｍ处多年泥温平均值作为海底恒温层温度。     

正己烷/海水微乳液形成的相图研究

用相图方法研究正己烷／海水微乳液的形成。体系相图由水（或人工海水，盐度分别为０，１３．６９６，３０．０７０和４１．１１８）／油（正己烷）／表面活性剂（ＡＳ，ＣＴＡＢ及ＢＲＩＪ３５）／助表面活性剂（正丁醇）在４０℃时构成。分别研究表面活性剂类型，油及醇含量和海水盐度对微乳液形成的影响。结果表明：醇与表面活性剂的摩尔浓度比值大于１时，最适宜于形成微乳液；形成微乳液区的面积随正己烷含量增加而减少；含离子     

Optimisation of wave energy extraction with the Archimedes Wave Swing

This paper addresses the Archimedes Wave Swing (an offshore wave energy converter, which produces electricity from sea waves). It compares the performances of latching control (a discrete, highly non-linear, intrinsically sub-optimum control strategy), of reactive control, of phase and amplitude control (two optimum control strategies that involve non-causal transfer functions, which have to be implemented with approximations, thus rending the control sub-optimum), and of feedback linearisation control (a non-linear control strategy). From extensive simulations it is concluded that the latter performs clearly better irrespective of the sea state, and leads to a significant increase of absorbed wave power.     

Ages of peak HP-UHP metamorphism of eclogites from Chinese southwestern Tianshan: Evidence from Lu-Hf geochronologySCIEI北大核心CSCD

新疆西南天山蓝片岩-榴辉岩带是全球少有的几个经历超高压变质作用的洋壳俯冲带之一,近年来的同位素年代学研究表明其变质作用主要发生于石炭纪。然而,该蓝片岩-榴辉岩带峰期变质作用,特别是超高压变质作用的时代还未精确限定。本文选取来自该带的典型钠云母黝帘石榴辉岩(样品211-3和H76-10),在详细的岩石学和相平衡研究基础上,开展了Lu-Hf同位素年代学研究,以期获得其峰期变质作用时代。相平衡模拟结果表明两榴辉岩中石榴石均记录了升温降压型折返P-T(温度-压力)轨迹。其中,样品211-3经历了超高压变质作用,其压力峰期P-T条件为~540℃、~2.9GPa,石榴石-绿辉石-全岩Lu-Hf等时线年龄为326.9±1.3Ma;样品H76-10仅经历了高压变质作用,其压力峰期P-T条件为~490℃、~2.4GPa,石榴石-绿辉石-全岩Lu-Hf等时线年龄为306±11Ma。结合前人年代学数据,获得新疆西南天山超高压榴辉岩峰期变质作用时代为327~326Ma,高压榴辉岩峰期变质作用时代为316-306Ma。本文获得的超高压变质作用确切年龄326.9±1.3Ma,对于揭示古南天山洋深俯冲和闭合的时间具有重要意义。