高能电子爆发与绕月卫星表面电位大幅下降的联动效应

"嫦娥"一号、二号绕月飞行经历地球磁尾边界层区域时,分别在2007年11月26日—2008年2月5日和2010年10月3日—2011年2月28日,发现了15次月球轨道0.1~2 MeV电子急剧增加(Bursts of 0.1~2 MeV Energetic Electrons,BEE),卫星周围等离子体离子加速的现象.统计研究表明,这类现象发生在稳定太阳风和弱行星际磁场条件下,且无显著空间环境扰动事件发生时,离子的加速滞后于高能电子爆发,离子能量的变化与高能电子通量的时间演化正相关,地球磁鞘内侧或边界层过渡区域是该类现象的高发区,离子能量增加时卫星表面电位大幅下降可达负几千伏.为了研究高能电子爆发与绕月卫星表面电位变化的关系及其对月球表面电位的影响,本文用电流平衡法建立绕月卫星和月球表面充电模型,并假设能量电子(2eV~2 MeV)满足幂律谱的分布,模拟急剧增加的能量电子对卫星和月球表面电位的影响.模拟结果表明,能量电子急剧增加使得绕月卫星和月球表面电位大幅下降;能量电子总流量1011 cm-2时,绕月卫星和月球表面充电电位可达负上千伏;月球充电到大的负电位的时间仅为卫星充电时间的1/10.鉴于高能电子急剧增加事件的高发生率(~125次/年),能量电子急剧增加使得绕月卫星表面电位大幅下降的发生率应大于实测等离子体离子加速现象的发生率(~25次/年).     

小波分析在前兆资料处理中的应用

利用小波变换分析了河南省2003~2007年地磁、地电、地下流体以及2004~2008年断层气CO2等前兆资料,并将断层气CO2的分析结果与河南省4级以上地震进行了震例研究。结果表明,小波分析方法对不同频率的信息识别功能较强,有助于将数据的趋势变化和局部变化分离,是地震前兆数据处理的一种有效方法;断层气CO2的震例研究表明,在豫北地区4级以上地震前1~6个月,断层气CO2会出现高值突跳异常。     

Selective Solid Phase Extraction for Separation and Preconcentration of Palladium from Gold Ore and Anode Slime after Complexation with a N4O2 Mixed Donor Ligand Derivative

A selective and sensitive method for the preconcentration, separation, and determination of palladium with flame atomic absorption spectrometry using 4,15‐bis[(4‐methylphenyl)sulfonyl]‐20,21‐dinitro‐2,3,4,5,6,7,9,10,12,13,14,15,16,17‐tetradecahydro‐8,11‐ethano‐1,18,4,8,11,15‐benzodioxa tetraaza cycloicosine (TNACIN) on XAD‐2010 was developed. TNACIN–Pd(II) complex formed acidic aqueous solution (0.075–0.100 M HNO₃) was accumulated on XAD‐2010 and then eluted with 1 M HCl in acetone. The effects of some analytical parameters including pH, TNACIN amount, sample volume, eluent type, and concentration, sample flow rate and matrix ions were studied for optimization of the method. Detection limit and precision were calculated for Pd(II). This method was also verified with CRM and internal standard, and satisfactory results were obtained.     

Metal Ion Extraction with Bipyridine Derivatives as Chelating Ligands in Supercritical Carbon Dioxide

Three fluorinated bipyridine ligands have been designed and synthesized as chelating agents for the extraction of metal ions in supercritical CO₂ (sc‐CO₂). The ligand solubilities in sc‐CO₂ were investigated at different temperatures and pressures, and the measured data have been correlated using a semiempirical model. The calculated results showed satisfactory agreement with the experimental data. Based on these data, metal ion extraction with the three compounds as chelating agents in sc‐CO₂ was performed from spiked filter paper, whereby ligand 1 showed the highest extraction efficiency, especially for Ni²⁺ and Cu²⁺. The extraction constants, K_ex, of the three chelating ligands were seen to increase with increasing extraction efficiency for the same metal ion in the same extraction system.     

北京市大气PM2.5中多溴联苯醚污染水平与来源分析

2008年1月、9月和10月在北京城区5个采样点共采集9个大气颗粒物PM_2.5样品。遵循US EPA-1614方法,采用同位素稀释、高分辨气相色谱/高分辨质谱(HRGC/MS)联用技术,测定了大气颗粒物PM_2.5样品中14种多溴联苯醚(PBDEs)的质量浓度,研究了北京市城区大气颗粒物PM_2.5中多溴联苯醚的污染水平、分布特征及来源。结果表明: 9个大气颗粒物PM_2.5样品中PBDEs的质量浓度范围为2.82~57.94 pg/m³,平均值为15.67 pg/m³,BDE-209的质量浓度为0.34~7.32 pg/m³,PM_2.5样品中PBDEs的质量浓度冬季高于秋季;高溴代联苯醚在颗粒物中的含量高,低溴代联苯醚的含量低;交通源对大气颗粒物PM_2.5中PBDEs的污染贡献值很小,工业污染源贡献大于交通源,从含有溴代阻燃剂的物品释放到大气中的PBDEs对大气颗粒物PM_2.5中PBDEs的污染贡献值最大。     

Silicate‐oxide mineral chemistry of mafic–ultramafic rocks as an indicator of the roots of an island arc: The Chilas Complex,Kohistan (Pakistan)

The Chilas Complex is a major lower crustal component of the Cretaceous Kohistan island arc and one of the largest exposed slices of arc magma chamber in the world. Covering more than 8000 km², it reaches a current tectonic width of around 40 km. It was emplaced at 85 Ma during rifting of the arc soon after the collision of the arc with the Karakoram plate. Over 85% of the Complex comprises homogeneous, olivine‐free gabbronorite and subordinate orthopyroxene–quartz diorite association (MGNA), which contains bodies of up to 30 km² of ultramafic–mafic–anorthositic association (UMAA) rocks. Primary cumulate textures, igneous layering, and sedimentary structures are well preserved in layered parts of the UMAA in spite of pervasive granulite facies metamorphism. Mineral analyses show that the UMAA is characterized by more magnesian and more aluminous pyroxene and more calcic plagioclase than those in the MGNA. High modal abundances of orthopyroxene, magnetite and ilmenite (in MGNA), general Mg–Fe–Al spatial variations, and an MFA plot of whole‐rock analyses suggest a calc‐alkaline origin for the Complex. Projection of the pyroxene compositions on the Wo–En–Fs face is akin to those of pyroxenes from island arcs gabbros. The presence of highly calcic plagioclase and hornblende in UMAA is indicative of hydrous parental arc magma. The complex may be a product of two‐stage partial melting of a rising mantle diaper. The MGNA rocks represent the earlier phase melting, whereas the UMAA magma resulted from the melting of the same source depleted by the extraction of the earlier melt phase. Some of the massive peridotites in the UMAA may either be cumulates or represent metasomatized and remobilized upper mantle. The Chilas Complex shows similarities with many other (supra)subduction‐related mafic–ultramafic complexes worldwide.     

The Godzilla Megamullion,the largest oceanic core complex on the earth: a historical review

The Godzilla Megamullion is the largest known oceanic core complex (OCC) on the Earth, located in the Parece Vela Basin in the Philippine Sea. In this article, the history of Godzilla Megamullion study is reviewed for the first time, dividing it into three major phases: (i) the early studies done before Japan's extended continental shelf survey program; (ii) the studies during Japan's extended continental shelf survey program that discovered the OCC; and (iii) the studies by the post‐discovery cruises. The early studies included an interpretation of US nautical chart of the southwestern Pacific and the site surveys for Deep Sea Drilling Project cruises (DSDP Legs 6, 31 and 59). The early studies recognized the presence of the Parece Vela Rift, the extinct spreading axis of the Parece Vela Basin, and established the currently accepted model that the Philippine Sea evolved with eastward progression of backarc spreading and arc migration. The modern understanding of the Parece Vela Basin comes from Japan's extended continental shelf survey program. The program revealed the ultramafic petrology as well as a two‐stage evolution model of the basin. Following these results, the discovery of the Godzilla Megamullion was made in 2001. The studies by the post‐discovery cruises further revealed important characteristics of the OCC, such as the presence of abundant plagioclase‐bearing peridotite and the systematic temporal changes in both deformation microstructures and composition of plagioclase and amphibole in gabbroic mylonites and ultramylonites. Zircon U–Pb ages of gabboric and leucocratic rocks indicate that the terminal phase of Parece Vela Basin spreading was with a significant decline in spreading rate and asymmetry accompanying formation of the Godzilla Megamullion. The estimated denudation rate of the OCC was approximately 2.5 cm/yr; significantly slower than the previous estimate based on poorly constrained magnetic data.     

Genetic algorithm for fitting a mixed Bingham distribution to 3D orientations: a tool for the statistical and paleostress analyses of fracture orientations

The clustering of fracture orientations is important for tectonic studies and for geotechnical engineering. In this study, a real‐coded genetic algorithm was adopted to fitting a mixed Bingham distribution to orientation data by maximizing the log‐likelihood function of the distribution. The maximization is a difficult problem, because the function has multimodality and singularity. It was found that the algorithm was effective for this problem. Given the orientations of dilational fractures, the present method determines not only the stress axes and stress ratio of each of the fracture groups but also the maximum non‐dimensionalized fluid pressure at the time of their formation. In addition, the software calculates the 95 % error ellipses of the concentration axes. The present method found that the orientations of ore veins of the Akenobe Mine, SW Japan, should be partitioned into three clusters. It is shown that two of the groups had distinctive Zn and Sn contents, and that the ore fluids had overpressures only slightly greater than the minimum principal stress at the time of the deposition of Zn‐ and Sn‐rich veins.     

A new Lower Triassic (Induan) Jerus Limestone locality in northwest Pahang,Peninsular Malaysia: Conodont fauna,depositional and tectonic settings

Limestones exposed north of Raub, Pahang, Malaysia, and sandwiched between the Bentong‐Raub Suture Zone and the westernmost margin of the Sukhothai Arc terrane, yield a late Dienerian (late Induan) conodont fauna. The co‐occurrence of Neospathodus dieneri Sweet (morphotypes 1, 2 and 3) and Neospathodus pakistanensis Sweet represents the Neospathodus dieneri morphotype 3 sub‐zone of the Neospathodus dieneri Zone. The sampled limestones are interpreted as the northwards extension of the Jerus Limestone which crops out near Cheroh and Jerus villages, significantly extending the known outcrop of the Jerus Limestone northwards. The Jerus Limestone is interpreted as hemipelagic and formed in a foredeep or forearc setting on top of the accretionary complex formed by eastwards subduction of the Palaeo‐Tethys during the Lower to Middle Triassic.     

Seismic fragility of traction elevators

Second‐generation performance‐based earthquake engineering (PBEE‐2) requires a library of component fragility functions to estimate probabilistic damage to a wide variety of building components. The present work draws on a large body of (mostly) post‐earthquake reconnaissance and (some) post‐earthquake survey observations of traction elevators to create fragility functions useful in PBEE‐2. Two surveys provide detailed observations of 115 representative elevators at 12 hospitals shaken in the 1989 Loma Prieta and 1994 Northridge earthquakes and selected without regard to or foreknowledge of damage. Of these, 55 failed and 60 did not. Approximately half were installed after an important code change of 1972, so one can distinguish the performance of pre‐1973 and post‐1973 elevator construction. They experienced a range of strong motion: 22 with peak ground acceleration (PGA) < 0.25 g, 93 with 0.25 g < PGA < 0.85 g. The hospitals had elevator failure rates as low as 0% and as high as 100%. A third survey describes damage qualitatively for six sites with PGA ≤ 0.25 and per‐site failure rates of 0% to perhaps 30%. Fragility functions are offered where the damage state is the loss of functionality of the elevator. The elevators in these surveys exhibit a median capacity of PGA ≈ 0.35 g with a logarithmic standard deviation of 0.40. Capacity is modestly sensitive to whether the elevator was installed before or after 1973. Using building‐specific intensity measures such as S_a(T₁) does not improve the fragility functions. Copyright © 2015 John Wiley & Sons, Ltd.