Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Effects of crab–halophytic plant interactions on creek growth in a S.W. Atlantic salt marsh: A Cellular Automata model

The Bahía Blanca Estuary (38° 50′ S, and 62° 30′ W) presents salt marshes where interactions between the local flora (Sarcocornia perennis) and fauna (Chasmagnathus granulatus) generate some kind of salt pans that alter the normal water circulation and condition its flow and course towards tidal creeks. The crab–vegetation dynamics in the salt marsh presents variations that cannot be quantified in a reasonable period of time. The interaction between S. perennis plant and C. granulatus crab is based on simple laws, but its result is a complex biological mechanism that causes an erosive process on the salt marsh and favors the formation of tidal creeks. To study it, a Cellular Automata model is proposed, based on the laws deduced from the observation of these phenomena in the field, and then verified with measurable data within macroscale time units. Therefore, the objective of this article is to model how the interaction between C. granulatus and S. perennis modifies the landscape of the salt marsh and influences the path of tidal creeks. The model copies the basic laws that rule the problem based on purely biological factors.The Cellular Automata model proved capable of reproducing the effects of the interaction between plants and crabs in the salt marsh. A study of the water drainage of the basins showed that this interaction does indeed modify the development of tidal creeks. Model dynamics would likewise follow different laws, which would provide a different formula for the probability of patch dilation. The patch shape can be obtained changing the pattern that dilates.     

基于MAPGIS的市政设施数据模型研究

本文主要介绍了市政基本设施的组成,提出了基于MAPGIS基本数据组织的市政设施数据模型,并讨论了市政设施数据模型的实现。从而,利用该数据组织模型可实现城市级的市政设施管理的综合集成与共享,提高市政设施管理和养护水平。     

网络导航中基于SVG的地理空间数据组织与传输

介绍网络导航服务系统,通过对MapX Mobile、ArcPad和SVG的地理空间数据组织的比较,得出基于Mobile SVG的地理空间数据组织方式优于其它两种组织方式。它不但适合网络导航服务系统的数据交互操作,而且同一图幅的数据量也明显少于MapX Mobile、ArcPad两种格式的数据。然后利用gzip软件包对数据进行压缩,减少数据传输所需的时间。     

利用UML模型构建Geodatabase的方法与实践

利用UML模型生成Geodatabase数据库便于数据库的更新及移植,同时能很好地反映数据库结构及对象之间的关系。论文分析了利用VISIO建模工具构建Geodatabase的UML模型以及在此基础上利用ArcGIS Desktop相关模块生成Geodatabase数据库的方法,并以上海市绿化林业信息数据库为例,演示了Geodatabase的创建及更新过程。     

初至层析静校正在复杂山地三维地震勘探中的应用

随着地形高差增大、地貌单元多变、近地表模型复杂,目前被广泛应用的初至折射静校正的精度已无法满足精细勘探的要求。初至层析静校正技术,由给定的初始模型进行正演,用射线追踪方法得到初始模型的初至波,利用该初至波和实际拾取的初至波进行比较,计算地表模型的修正量,反复迭代求得准确的地表模型。山西省国阳新能股份有限公司二矿390水平九采扩区地表标高940～1100m,地貌单元复杂,在对该区资料处理时,利用初至层析折射静校正,经9次迭代计算后,真实地刻划出近地表模型。在二种静校正技术对比中,初至折射静校正不但近地表模型精度低于层析折射静校正,而且其叠加剖面精细程度也远低于层析静校正,如在初至折射静校正叠加剖面同相轴上呈现的凹凸形态,在层析静校正叠加剖面并无显示,且后者剖面的信噪比也比前者明显提高。     

About the specification of erosion flux for soft stratified cohesive sediments

The present paper deals with the specification of bed erosion flux that accounts for the effects of sediment-induced stratification in the water column. Owing to difficulties in measuring the bed shear stress _b and the erosive shear strength _s, we suggest a series of methods that combine laboratory and numerical experiments. A simplified turbulent transport model that includes these effects helps to quantify _b and _s. Focusing on soft stratified beds, the present study considers erosion rate formulas of the form =_f exp {[T_b-T_s]} where is a model constant (=1 for Gularte's (1978) formula and =1/2 for Parchure's (1984) formula). First, the bed erosive strength profile _s(Z) is adjusted by forcing the turbulent transport model with measured erosion rates. Second, three procedures are suggested to determine the erosion rate formula coefficients _f and : a global procedure and two different layer-by-layer procedures. Each procedure is applied to an erosion experiment conducted in a rotating annular flume by Villaret and Paulic (1986). The use of the layer-by-layer procedure based on a least squares fitting technique provides a closer fit than the global procedure. The present study points out the complementarity of experimental and numerical approaches and also suggests possible improvements in laboratory test procedures.