Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

鄂尔多斯盆地靖边气田马五_(1+2)气藏储集单元研究

综合地震、地质、测井等信息,考虑沉积、成岩、地貌、生产动态等多因素,在沟槽识别和致密带研究基础上,通过井间干扰、油层压力变化和试井边界响应分析,按照局部、就近原则对靖边气田马五1+2气藏进行了储集单元划分。共划分出111个储集单元,其中独立型69个,复合型42个。这些储集单元的面积多介于10～50km2之间,单个储集单元的井数一般少于6口。在对气藏储层特征综合认识的基础上,确定流动单元划分思路与流程,并认为关键环节包括古沟槽识别、致密带研究、动静结合确定储集单元等3个方面。储集单元一方面受控于被致密岩相包围的有利成岩相带,宏观上与弱—中等充填泥粉晶白云岩相对应性好;另一方面又受各级古沟槽夹持,在两个一级古沟槽之间往往共生多个储集单元,而这些储集单元边界又严格地受二级或三级沟槽切割控制。     

Multiple magnetization events in the Red River carbonates, Williston Basin, Canada: Evidence for fluid-flow?

Samples collected from the Upper Ordovician Red River carbonates in a well at the centre of the Williston Basin revealed two paleomagnetic components with different inclinations, 60.3 ± 3.9° (k = 70.7, N = 12) and 20.4 ± 3.3° (k = 141.2, N = 8), but similar declination values in individual specimens. Inclination-only analysis indicates two possible scenarios for the age of these two magnetizations: in scenario (a) the timing of magnetization happened sometime between Late Ordovician to Devonian; and in scenario (b) there are two different remagnetizations, one that overlaps Pennsylvanian to Permian time while the other can have either a Late Jurassic or a Tertiary age. Whereas dolomitization and some isotopic data tend to support scenario (a), previous paleomagnetic data from the Williston Basin and from younger units in the same well, the tectonic evolution of the basin, and the hydrocarbon maturation pattern in the Red River carbonates all favour chemical remagnetization(s) driven by orogenic fluids during the Alleghenian and Laramide orogenies.     

Alpine reworking of Ordovician protoliths in the Western Carpathians: Geochronological and geochemical data on the Muráñ Gneiss Complex, Slovakia

Magmatic protoliths of Ordovician age have been identified in the metamorphic rocks of the Muráñ Gneiss Complex, Veporic Unit (Central Western Carpathians). Vapor digestion single zircon U–Pb dating yields an intrusion age of 464 ± 35 Ma (upper intercept) for the granite protolith. A lower intercept age of 88 ± 40 Ma records amphibolite-facies metamorphic overprint in the Cretaceous, during the Alpine orogeny. Geochemical and isotopic data suggest crustal origin of the orthogneiss. Nd_initial are between − 2.6 and − 5.0 and T_DM^Nd between 1.3 and 1.5 Ga (two-step approach). ⁸⁷Sr / ⁸⁶Sr_initial ratios vary between 0.7247 and 0.7120, and a steep REE pattern further constrains the crustal affinity of these rocks. Associated amphibolite bodies have Nd_initial values of 6.5, ⁸⁷Sr / ⁸⁶Sr_initial ratio of 0.7017, and a flat REE pattern. They are interpreted as MORB derived metabasites. Whole-rock Pb isotope analyses define a linear array in a ²⁰⁶Pb / ²⁰⁴Pb vs. ²⁰⁷Pb / ²⁰⁴Pb diagram with an age of ca. 134 Ma, consistent with intense Alpine metamorphism and deformation.

These basement rocks of the Central Western Carpathians are interpreted as Ordovician magmatic rocks intruded at an active margin of Gondwana. They represent the eastern prolongation of Cambro–Ordovician units of the European Variscides, which were part of the peri-Gondwana superterrane and accreted to Laurussia during the Variscan orogeny. Variscan metamorphic overprint is not recorded by the isotopic data of the Muráñ Gneiss Complex. Alpine metamorphism is the most dominant overprint.     

藏北申扎地区奥陶纪鹦鹉螺类一新属（Variabioceras）

文中材料是采自西藏申扎县塔尔玛乡桥东—扎扛一带鹦鹉螺化石的一部分。描述了3属6种。其中有1个新属Variabioceras gen.nov．和3个新种V．typicum gen．etsp．nov．，V．zangbeiense gen．et sp．nov．，V．robustum gen．et sp．nov．     

渭北东部奥陶系岩溶地下水环境同位素特征分析

本文通过对渭北东部岩溶地下水环境同位素组成特征的研究,分析了大气降水、地表水、地下水三者之间的转化关系,并对研究区岩溶地下水的形成进行了初步探讨,认为大气降水是研究区岩溶地下水的补给源,地表水与地下水之间存在水力联系,地表水对地下水的补给占补给水源的74.3%.西部岩溶裸露区为岩溶水的直接补给区,其周边浅埋区为岩溶水的间接补给区,东南部的岩溶中-深埋区为岩溶水的径流排泄区.     

内蒙古大青山地区寒武系与奥陶系之间的一个重要的层序界面

大青山地区寒武纪－奥陶纪地层分布零星，是由中生代逆冲推覆构造就位于此的一系列近东西向延展的构造岩片组成。下寒武统色麻沟组直接覆盖在太古界变质岩之上，缺失中元古界什那干群，寒武系与奥陶系之间呈假整合接触，标志着区内寒武纪与奥陶纪之间发生过一次抬升构造运动，其形成机制与古亚洲洋内的稳定陆快向华北板块拼贴事件有关，是早奥陶世末期华北板块整体抬升的序幕。这个层序界面的认识，对于恢复华北板块北部边缘构造演化历史具有重要意义。     

渤海湾盆地北部奥陶纪岩相古地理

渤海湾盆地北部主要包括黄骅坳陷、沧县隆起、冀中坳陷和下辽河坳陷,区内奥陶系厚 6 0 0～ 80 0m,主要由石灰岩和白云岩组成。下奥陶统分为冶里组和亮甲山组,中奥陶统分为下马家沟组、上马家沟组和峰峰组,上统缺失。其中下马家沟组、上马家沟组和峰峰组又进一步划分为下段和上段。早奥陶世冶里期和亮甲山期,本区以局限海环境为主,其内散布着一些潮坪和滩。中奥陶世,本区岩相古地理面貌变化旋回极为明显,下马家沟期早期潮坪广布,晚期以局限海为主;上马家沟期早期又是潮坪广布,晚期以开阔海为主;峰峰期早期潮坪广布,晚期又以开阔海为主。在奥陶纪,本区经历了 4个大的海侵-海退旋回,其中上马家沟期晚期是本区乃至整个华北地台的最大海侵期。     

Ordovician Graptolite Rhabdosome Complication and Its Implications on Sea Level Changes

A total of four times of rhabdosome complication events, i.e., the lateral branching of graptolite stipes during the Late Middle Ordovician, the secondary branching of graptolite stipes at the earliest Upper Ordovician, the early Qiantangjiangian of Upper Ordovician and the middle Qiantangjiangian, respectively, is discussed in this paper. These events and other adaptation events demonstrate close relationships between a diverse graptolite fauna and sea level changes, and consequently can be employed to study sea level fluctuations. It is safe to conclude that the complication of rhabdosome started at the maximum flooding surface (MFS) and terminated at the beginning of regression.     

藏北申扎一带下奥陶统拉塞组的发现及意义

吉林省地质调查院在进行1：25万《多巴区幅》区域地质调查时，在西藏北部申扎县一带首次发现一套富含北方珠角石动物群Armenoceras sp.,Wutinoceras sp.,Discoactinoceras multiplerum Kobayashi,Adaomsoceras sp.,Sactoceras sp.,Ordosoceras sp.,Oncoceratida,Ormoceratidae,? Curtoceras sp.,Ormoceras sp.,Liulinoceras sp.,Deiroceras cf.globsom Zholt et Shen及腕足类、牙形刺、苔藓虫、海百合茎等化石的海相碳酸盐岩地层。该地层的岩石组合特征及生物群面貌与区内已知的地层存在明显的差异，其地质时代也明显早于区内已知的其它古生代地层，故建立下奥陶统拉塞组。