Exposure and bioavailability of arsenic in contaminated soils from the La Parrilla mine, Spain

Arsenic derived from mining activity may contaminate water, soil and plant ecosystems resulting in human health and ecotoxicological risks. In this study, exposure assessment of arsenic (As) in soil, spoil, pondwater and plants collected from the areas contaminated by mine tailings and spoils in and around the La Parrilla mine, Caceres province, Spain, was carried out using AAS method. Water solubility, bioavailability and soil–plant transfer coefficients of As and phytoremediation potential of plants were determined. Arsenic concentrations varied from 148 to 2,540 mg/kg in soils of site 1 and from 610 to 1,285 mg/kg in site 2 exceeding the guideline limit for agricultural soil (50 mg/kg). Arsenic concentrations in pond waters varied from 8.8 to 101.4 μg/l. High concentrations of water-soluble As in the soils that ranged from 0.10 to 4.71 mg/kg in site 1 and from 0.46 to 4.75 mg/kg in site 2 exceeded the maximum permitted level of water-soluble As (0.04 mg/kg) in agricultural soils. Arsenic concentrations varied from 0.8 to 149.5 mg/kg dry wt in the plants of site 1 and from 2.0 to 10.0 mg/kg in the plants of site 2. Arsenic concentrations in plants increased in the approximate order: Retama sphaerocarpa < Pteridium aquilinum < Erica australis < Juncus effusus < Phalaris caerulescens < Spergula arvensis in site 1. The soil–plant transfer coefficients for As ranged from 0.001 to 0.21 in site 1 and from 0.004 to 0.016 in site 2. The bioconcentration factor based on water-soluble As of soil varied from 3.2 to 593.9 in the plants of site 1 whereas it varied from 2.1 to 20.7 in the plants of site 2. To our knowledge, this is the first study in Europe to report that the fern species P. aquilinum accumulates extremely low contents of As in its fronds despite high As levels in the soils. Therefore, the S. arvensis, P. caerulescens and J. effusus plant species grown in this area might be used to partly remove the bioavailable toxic As for the purpose of minimization of mining impacts until hypothetical hyperaccumulating and/or transgenic plants could be transplanted for the phytoremediation of As contaminated soils.     

NCEP-FNL与T213L31同化资料对比 分析中的地形差异影响

分析了2005年5月11日至6月10日的NCEP—FNL与T213L31分析资料在位势高度、温度和风场上的整体差异，揭示了低层差异最小，差异极值主要分布在3个关键区的特征。进一步通过地形高度差异与位势高度差异的相关性分析，认为青藏高原附近的地形高度差异的极值是引起两种资料位势高度差异的主要原因，并计算分析了这种差异对高原周围中低层大气环流的动力和热力影响。结果显示，在NCEP—FNL中的西南涡强度和热源作用较强，中层风速切变较弱。     

桂岭岩体稀土、微量元素地球化学特征研究

文章运用岩石地球化学方法,对桂岭岩体的构造环境和地球化学特征进行了研究,结果显示：桂岭岩体岩石平均LREE／HREE=7．68,（La／Yb）N-6．77,（La／Sm）N-4．65,（Gd／Yb）N-1．04,平均δEu=0．45〈1,表明轻重稀土轻度分异,轻稀土相对富集,轻稀土内部分馏明显,存在负铕异常;岩体明显亏损Nb、Sr、Ti,显示桂岭岩体的源区可能主要来自地壳,是地壳环境下壳源岩石发生部分熔融的产物;研究表明,桂岭岩体形成于挤压一伸展的大地构造环境。     

һ���µ�GNSS��̬��λ���ȼ�ⷽ��

???????????????????????????GNSS?????λ???????????????????????????????????????????????????????????????????????????????1 cm?????????     

青蛤(Cyclina sinensis)组织蛋白酶L基因的表达与重组蛋白活性分析

利用荧光定量PCR方法检测了青蛤(Cyclina sinensis)在鳗弧菌(Vibrio anguillarum)胁迫下组织蛋白酶L基因(CsCPL)在各组织的表达差别及其在血淋巴中的时序表达关系。结果表明,CsCPL基因在青蛤血淋巴、肝脏、外套膜、鳃和闭壳肌等组织中普遍表达,其中以血淋巴表达水平最高。在鳗弧菌刺激后3—96h青蛤的血淋巴中CsCPL的表达量均出现明显上调,其中6h达到最大值并且与对照组有极其显著性差异(P0.01),说明该基因在青蛤免疫反应中具有重要作用。文章还对CsCPL基因进行了原核表达,其产物蛋白分子量约35kDa,经纯化及复性后具有明显的抑菌作用。     

青岛中港海水全浸初期不锈钢表面生物膜的细菌多样性分析

为了研究全浸15天不锈钢表面生物膜的形成情况,首先采用SEM及荧光显微镜进行观察,显示全浸15天不锈钢表面已有大量微生物及其腐蚀产物附着,表明其表面生物膜已经形成;进一步通过EDS对不锈钢表面进行元素分析,发现实海全浸15天的316L不锈钢表面出现了大量组成生物体的C、P等基本元素,并且还出现了不锈钢基体中所不存在而存在于生物膜及其代谢产物中O等元素,进一步证明了不锈钢表面生物膜的形成。采用16S rRNA基因结合PCR-RFLP技术分析手段对实海全浸15天的316L不锈钢表面生物膜细菌群落的多样性进行了研究,发现316L不锈钢表面附着细菌的OTU数为24,分别属于变形菌门和拟杆菌门,其中α-变形菌的OTU数是18,占总克隆数的72.3%,为绝对优势种群。     

Formation of iron plaque on mangrove Kandalar. Obovata (S.L.) root surfaces and its role in cadmium uptake and translocation

In this study, a pot experiment was conducted to investigate the formation of iron plaque under Cd stress and its role in Cd uptake and translocation by mangrove Kandalar. Obovata (S.L.). Results showed:     

Processes of the displacement field change of the 2009 April 6 M_W6.3 L’Aquila earthquake using persistent scatterer and small baseline methods

Using a time series method that combines both the persistent scatterer and small baseline approaches, we analyzed 9 scenes Envisat ASAR data over the L＇Aquila earthquake, and obtained a Shocke＇s displacement field and its evolution processes. The results show that： （1） Envisat ASAR clearly detected the whole processes of displacement field of the L＇Aquila earthquake, and distinct variations at different stages of the displacement field. （2） Preseismic creep displacement → displacement mutation when faulting → constantly slowed down after the earthquake. （3） The area of the strongest deformation and ground rupture was a low-lying oval depression region to the southeast. Surface faulting within a zone of about 22 km× 14 km, with an orientation of 135°, occurred along the NW-striking and SW-dipping Paganica-S. Demetrio normal fault. （4） In analyzing an area of about 54 km x 59 km, bounded by north-south axis to the epicenter, the displacement field has significant characteristics of a watershed： westward of the epicenter shows uplift with maximum of 130 mm in line-of-sight （LOS）, and east of the epicenter was a region with 220 mm of maximum subsidence in the LOS, concentrating on the rupture zone, the majority of which formed in the course of faulting and subsequence.     

L5载波的信号质量分析

增加第三民用频率L5载波是GPS现代化措施中的一项,目前美国已经有4颗卫星具有L5观测值。从L5的信号结构上进行分析,应用L5载波的实际观测数据,与L1载波和L2载波相比较,L5载波不但在信噪比上得到提高,而且其多路径效应的影响也比较小,具有较好的数据观测质量。     

多频电离层残差法用于周跳的探测与修复

周跳的探测与修复是高精度GNSS定位的核心问题,随着GNSS现代化的逐步实施,L5载波观测值的增加给周跳的探测提供了一种新的方法。文中结合三频组合观测值的一些特性,提出一种多频电离层残差法用于周跳的探测与修复。实验表明,文中方法不仅能探测出双频条件下不能探测出的一些特殊周跳组合,还可以单历元间直接解算得到单个频率上的周跳值。