小秦岭金矿含金石英脉中黄铁矿晶体的表面微形貌研究

利用微分干涉显微镜、扫描电镜、透射电镜等对小秦岭金矿含金石英脉中黄铁矿晶体的表面微形貌进行了研究。黄铁矿晶体的{210}面上发育自由生长层，表明{210}面是F面，其生长机理受二维成核层生长所制约。除简单的五角十二面体外，其他形态黄铁矿晶体的{210}面上也发育有自由生长层。{210}面上的正条纹有些是由{100}面上生长层的边缘台阶在{210}面上叠堆形成，另一些正条纹则是{210}面上生长层边缘台阶堆叠的产物。透射电镜和电子衍射花样研究表明，负条纹黄铁矿晶体是由30～50nm大小的核团经自动定向附生作用形成，每个核团不是单晶体，而是由许多早先在溶液中形成的小微晶聚合而成。这些特征表明负条纹黄铁矿晶体是在溶液过饱和度极高和温度梯度小的理想环境中形成，它的形成与杂质无关。PBC理论和唐纳-哈克定律能较好地解释自然界中黄铁矿晶体{100}面上普遍发育自由生长层、而{210}面上自由生长层极为罕见的原因。除日本释迦内矿区黑矿之上的浮岩凝灰岩中产生出负条纹黄铁矿晶体外，在石英脉型金矿床中也有负条纹黄铁矿晶体产出。     

洛川黄土剖面中矿物固定态铵的分布

对洛川黄土中的固定铵进行了初步分析。结果表明,在所测定的黄土古土壤层中,固定铵态氮含量在130-1之间变化。黄土中的固定铵态氮含量明显低于古土壤。13万a以来洛川黄土剖面中固定铵的分布呈～210现三次大的低高值的振荡特征,即末次间冰期S1古土壤中固定铵态氮含量最高,其次为冰后期的S0古土壤层,末次冰期形成的马兰黄土中固定铵态氮含量最低;在马兰黄土中同样体现出三次小的低高值的波动特征。黄土与μm组分的分布具有相似性,这些特征反映了洛川黄土中固定铵态氮的含量变化与气互层的古土壤中固定态铵的分布与黄土高原区气候的冷暖变化有较好的一致性,并且13万a以来洛川黄土剖面中固定铵的分布与磁化率和<2候条件有紧密的联系,揭示了黄土中固定铵的变化在一定程度上能指示黄土高原区古气候的演变。     

Continuous Multi‐probe Measurements in Fastflowing Waters Using a Hydrographic Slot

Taking continuous spatiotemporal in situ measurements with multi‐probes in fast‐flowing waters/rivers can be problematic because the sensors may be damaged by high shear forces and flotsam. To protect the multi‐probe and to enable easy access for the maintenance and calibration of the sensors, a special multi‐probe holder fixed in a hydrographic slot was developed. The validation of the probe system revealed a “memory effect” at short time scales (< 10 s) within sharp gradients caused by the overflow container of the multi‐probe rack keeping the sensors submerged in the sample water. Continuously recorded data (conductivity, temperature, pH, oxygen concentration and saturation, as well as in vivo fluorescence of chlorophyll‐a) from a research cruise on board the RV ALBIS along the river Elbe (river km 309) and entering the river Saale are presented. This river stretch upstream of the city of Magdeburg to the mouth of the Saale tributary was found to have a complex physicochemical character, which is attributable to the long mixing process of water from the river Saale and the river Elbe.     

Sorption of carbon dioxide–methane mixtures

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.     

Improved spatial delineation of streambed properties and water fluxes using distributed temperature sensing

A new method was developed for analysing and delineating streambed water fluxes, flow conditions and hydraulic properties using coiled fibre‐optic distributed temperature sensing or closely spaced discrete temperature sensors. This method allows for a thorough treatment of the spatial information embedded in temperature data by creating a matrix visualization of all possible sensor pairs. Application of the method to a 5‐day field dataset reveals the complexity of shallow streambed thermal regimes. To understand how velocity estimates are affected by violations of assumptions of one‐dimensional, saturated, homogeneous flow and to aid in the interpretation of field observations, the method was also applied to temperature data generated by numerical models of common field conditions: horizontal layering, presence of lateral flow and variable streambed saturation. The results show that each condition creates a distinct signature visible in the triangular matrices. The matrices are used to perform a comparison of the behaviour of one‐dimensional analytical heat‐tracing models. The results show that the amplitude ratio‐based method of velocity calculation leads to the most reliable estimates. The minimum sensor spacing required to obtain reliable velocity estimates with discrete sensors is also investigated using field data. The developed method will aid future heat‐tracing studies by providing a technique for visualizing and comparing results from fibre‐optic distributed temperature sensing installations and testing the robustness of analytical heat‐tracing models. Copyright © 2016 John Wiley & Sons, Ltd.     

基于“一张图”平台的国土资源执法监察系统设计与研究

从土地执法监察管理的实际需求出发,探讨了基于"一张图"平台的国土资源执法监察系统建设方案,设计了土地执法监察系统结构和功能模块,并进一步给出了土地执法监察数据库建设和数据交换的技术方法。该系统方案的应用将有利于快速、准确地监控国土资源违法行为,强化对国土资源违法行为的监控能力,有效地提高了国土部门执法监察工作效率和执法水平。     

L1范数与IQR统计量组合的GNSS坐标序列粗差探测算法

GNSS坐标时间序列中不可避免地含有粗差,未剔除的粗差将会导致参数估计有偏。因此,粗差探测与剔除是GNSS坐标序列分析中一项重要的数据预处理工作。针对GNSS坐标时间序列特点,提出了一种将L1范数(L1-norm)估计与四分位距统计量IQR(interquartile range)组合的移动开窗粗差探测算法,称之为L1_Mod IQR。该方法的主要思想是,首先利用L1范数估计得到较"真实"的残差,然后再对残差采用IQR统计量进行粗差探测。将L1_Mod IQR法与"3σ"法、基于最小二乘的τ检验法等粗差探测算法进行了模拟计算与对比,验证了该算法的有效性。进一步采用L1_Mod IQR算法对中国区域10个IGS站的高程时间序列进行了分析,结果表明中国区域IGS站高程序列的粗差剔除率最小为0.1%,最大为2.6%。并且以WUHN站为例与SOPAC提供的结果进行了对比,结果表明SOPAC提供的"Clean"数据仍含有大量的粗差,而L1_Mod IQR算法能够有效地剔除粗差。     

Conceptualizing multiple clusters in mega-city regions: The case of the biomedical industry in Beijing

This paper introduces a unique industrial configuration that has emerged in Beijing, where three economic clusters in the biomedical industry, originally established as industrial/research parks, have developed parallel to each other. This configuration of multiple co-located clusters of the same industry, which has not been discussed before, raises the question of whether the industrial/research parks are competing for the same resources, or whether they are complementary to each other and can collectively be viewed as a new type of industrial configuration. The paper conceptualizes a framework of multiple clusters in mega-city regions that distinguishes between collaborating and competing clusters and presents initial empirical evidence for the Beijing case. As such, this research aims to unravel the phenomenon of multiple clusters in mega-city regions and to understand the complex spatial interrelationships that exist within and beyond multiple co-located clusters in the same industry.     

桐柏山L构造岩形成机制构造解析及其对造山带演化的制约

桐柏杂岩中发育一套典型的L构造岩,其构造位置位于桐柏造山带核部,被两条近似对称的韧性剪切带所夹持,北侧剪切带左旋,南侧剪切带右旋。由于L构造岩构造位置特殊,其位于剪切带、桐柏背形、桐柏穹窿等多种构造体的交叉部位,L构造岩的构造成因解析可以为桐柏造山带的形成演化提供重要制约。通过对桐柏造山带L构造岩的构造成因机理解析和其变形温压条件的研究,同时结合前人对桐柏山其它主要构造单元的研究,我们提出,桐柏山L构造岩的形成主要受其南北两侧两条韧性剪切带控制,传统意义的桐柏杂岩体白垩纪之前与南北一体的韧性剪切带沿近似东西方向发生管状韧性剪切,剪切作用形成了一套典型的L构造岩。L构造岩的形成指示了桐柏山单元可能经历了一期中下地壳物质的管状的韧性的向东剪切流动,后期白垩纪桐柏山核部的L构造岩经历了大规模的岩浆上升与浮力增加,该L构造岩同剪切带一起发生隆升但管状剪切构造特征并未被改造,随着不均匀隆升桐柏山出现了现今的几何学特征。L构造岩反映出管状剪切形成了现今桐柏造山带近东西向线状构造样式的主体。