Temporal trend, spatial distribution, and terrestrial sources of PBDEs and PCBs in Masan Bay, Korea

Congener specific determination of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) was carried out in 21 surface sediment samples and a sediment core from Masan Bay, Korea. Among the 40 PBDE congeners targeted only 29 were detectable. PBDE congener profile within sediments was dominated by BDE-209 followed by BDEs-99, -47, -153 and -183, sequentially. In surface sediments, the average ΣPBDEs levels approached that of average ΣPCBs values. However, trends observed in the sediment core suggest that this pattern will alter over time and result in higher surface sediment PBDE concentrations than PCBs in future. Various diffuse and point sources for PBDEs and PCBs were identified in this location. Shipping and other industrial activities were associated with PCB contamination while domestic and industrial waste discharges corresponded with PBDE contamination. The average concentration for PBDEs and PCBs in surface sediments were 5.7, 7.2 ng/g dry weight, respectively.     

Focal mechanisms of recent earthquakes in the Southern Korean Peninsula

We evaluate the stress field in and around the southern Korean Peninsula with focal mechanism solutions, using the data collected from 71 earthquakes ( M_L = 1.9–5.2) between 1999 and 2004. For this, the hypocentres were relocated and well-constrained fault plane solutions were obtained from the data set of 1270 clear P -wave polarities and 46 SH / P amplitude ratios. The focal mechanism solutions indicate that the prevailing faulting types in South Korea are strike-slip-dominant-oblique-slip faultings with minor reverse-slip component. The maximum principal stresses (σ₁) estimated from fault-slip inversion analysis of the focal mechanism solutions show a similar orientation with E–W trend (269°–275°) and low-angle plunge (10°–25°) for all tectonic provinces in South Korea, consistent with the E–W trending maximum horizontal stress (σ_Hmax) of the Amurian microplate reported from in situ stress measurements and earthquake focal mechanisms. The directions of the intermediate (σ₂) and minimum (σ₃) principal stresses of the Gyeongsang Basin are, however, about 90 deg off from those of the other tectonic provinces on a common σ₂–σ₃ plane, suggesting a permutation of σ₂ and σ₃. Our results incorporated with those from the kinematic studies of the Quaternary faults imply that NNW- to NE-striking faults (dextral strike-slip or oblique-slip with a reverse-slip component) are highly likely to generate earthquakes in South Korea.     

中国北方磷矿成矿类型和找矿方向

笔者是在“五国编图项目”(中国、俄罗斯、哈萨斯坦、蒙古国、韩国)的中国北方磷矿床资料研究基础之上完成本论文的。中国北方磷矿床分为“沉积型”、“沉积变质型”和“岩浆型”三大类型。沉积型磷矿床主要产生于晚震旦纪陡山沱期和早古生代寒武纪早期,磷质来源以海洋生物磷为主;沉积变质型磷矿床主要产生于中元古代,磷质来源以火山磷质为主,也可能有生物磷质参与;沉积型和沉积变质型磷矿都包含陆地风化迁入盆地中的磷成分;岩浆磷矿床主要产生于海西期和加里东期的超镁铁岩浆岩,多与铁、钒、钛成为成矿系列。沉积型磷矿在华北地台南缘和塔里木地块北缘应重视,而沉积变质型在华北地台北缘有远景;岩浆型则主要勘查超镁铁岩系列。     

What is responsible for increasing flood risks? The case of Gangwon Province,Korea

We examined the anthropogenic and natural causes of flood risks in six representative cities in the Gangwon Province of Korea. Flood damage per capita is mostly explained by cumulative upper 5% summer precipitation amount and the year. The increasing flood damage is also associated with deforestation in upstream areas and intensive land use in lowlands. Human encroachment on floodplains made these urban communities more vulnerable to floods. Without changes in the current flood management systems of these cities, their vulnerability to flood risks will remain and may even increase under changing climate conditions.     

Geology and Hydrothermal Alteration of the Milyang Pyrophyllite Deposit, Southeast Korea

Abstract: The Milyang pyrophyllite deposit, which is embedded in the Late Cretaceous Yuchon Group of the Kyongsang Supergroup, is one of the largest hydrothermal clay deposits in the Kyongsang basin, southeast Korea. Host rocks of the deposit are porphyritic andesite lava and minor andesitic lapilli tuff. In the Milyang district, a hydrothermally altered zone is about 2 × 3 km in extent; we can recognize the concentric arrangement of advanced argillic, propylitic, and sericitic alteration zones from the central to peripheral parts of the zone. The Milyang pyrophyllite deposit forms a part of the advanced argillic alteration zone. The Milyang pyrophyllite deposit is subdivided into the following four zones based on mineral assemblages: the pyrophyllite zones 1, 2, 3, and the silicified zone. The pyrophyllite zone 1, which occupies the central part of the deposit, comprises mainly pyrophyllite, kaolinite, and diaspore without quartz. Diaspore nodules often concentrate in beds 40–50 cm thick. Andalusite, dumortierite, and tourmaline locally occur as network veins, crack‐filler, or small spherulitic spots. The Al₂O₃ content of the ore ranges from 27 to 36 wt%. The pyrophyllite zone 2, which constitutes a major part of the deposit, comprises mainly pyrophyllite, kaolinite, and quartz. The Al₂O₃ content of the ore ranges from 15 to 24 wt%. The pyro‐phyllite zone 3 is the hematite‐rich marginal facies of the deposit. The silicified zone, which occurs as beds and septa, is mostly composed of quartz with minor pyrophyllite and kaolinite; the SiO₂ contents range from 79 to 90 wt%. Comparing chemical compositions of the high‐Al ores with those of unaltered host andesite, the Fe, Ca, alkalis, HFSE, and HREE contents are significantly depleted, whereas S, B, As, Sr, and LREE are enriched. The hydrothermal alteration of the Milyang pyrophyllite deposit can be classified into the following four stages: 1) extensive sericitic and propylitic alteration, 2) medium‐temperature (200–250°C) advanced argillic alteration, 3) high‐temperature (250–350°C or more) advanced argillic alteration, and 4) retrograde low‐temperature alteration. The heat and some volatile components such as B and S would be derived from the Pulguksa Granite intruded underneath the deposit.     

Evaluation of remedial alternatives for a petroleum contaminated unconfined aquifer with fluctuating groundwater level

This study evaluated remedial alternatives for a petroleum-contaminated site where an unconfined aquifer composed of a sandy layer of about 3–3.5 m thickness is covered by alluvial deposits and reclaimed soil of about 1.5 m thickness. Precambrian gneiss, of low permeability, lies below the sandy layer. The shallow water table is about 3 m below the surface, but shows high fluctuations of up to 1.5 m in response to precipitation events. The unsaturated soil near the water table and the groundwater are highly contaminated with petroleum hydrocarbons, especially toluene, which have apparently leaked from storage tanks. Selection of the remedial alternatives required consideration of the relevant laws on soil and groundwater conservation in Korea, the results of risk analysis and the hydrogeological conditions. The contaminated area has been divided into zones in which different remediation goals are set based on risk analysis and the degree of natural attenuation. It is estimated that the clean-up goal can be achieved in two years by the combined use of a trench drain and well point pumping to collect the contaminated groundwater for treatment, and a dual air injection system for the contaminated soil.     

Decoding Neoarchaean to Palaeoproterozoic tectonothermal events in the Rangnim Massif,North Korea: regional correlation and broader implications

Any knowledge about Archaean to Palaeoproterozoic magmatic and metamorphic events in North Korea has the potential to make a significant difference to our understanding of the early tectonic configuration and evolution of East Asia. This zircon U–Pb dating and Hf isotopic study documents multiple Neoarchaean to Palaeoproterozoic tectonothermal events from the meta-igneous complex in the Machollyong ‘Group’ of the Rangnim Massif. Two tonalitic-trondjemitic gneiss samples record a crystallization age of meta-igneous protoliths at ca. 2.56 Ga and multiple migmatization and metamorphism from 2.52 to 1.85 Ga. A meta-dolerite sample yields a magmatic emplacement age of ca. 1.83 Ga. In situ zircon Hf isotopic data indicate that most zircons from the gneiss samples have ε_Hf(t) values from –16.9 to + 3.1 and crustal model ages from 2.84 to 3.73 Ga, whereas magmatic zircons from the meta-dolerite dike record ε_Hf(t) values from –5.2 to + 5.2 and model ages of 2.05–2.44 Ga. The first-recognized Neoarchaean tonalitic-trondjemitic migmatite complex in the Rangnim Massif, together with previously identified tonalitic-trondhjemitic-granodioritic (TTG) rocks in the Rimjingang Belt and the coeval counterparts in western Gyeonggi massif, represents the oldest crustal nuclei in the Korean Peninsula. The multiple tectonothermal events in this study present reliable evidence not only for attesting to consanguinity of the basement between the Korean Peninsula and the North China Craton but also for defining the influence scope of the late Palaeoproterozoic orogeny in the Korean Peninsula.     

中朝地台南部下、中寒武统层序地层特征

中朝地台南部下、中寒武统 (风台组—张夏组 )可划分 9个三级层序。除底部的 DS-A层序外 ,其余 8个层序均可与中朝地台大部分地区进行对比。下部的 3个层序 (DS- A～ DS-2 )属 型层序 ,其余为 型层序。研究表明 ,本区的沉积层序除受早古生代全球海平面变化控制之外 ,秦岭板块的俯冲对中朝地台南部层序地层的发育也具有一定的影响     

Interdecadal variation in Korean spring drought in the early 1990s

Statistical change-point analysis was applied to a spring time series of the Palmer Drought Severity Index (PDSI) in Korea, and this showed that the total analysis period can be divided into two periods: a wet period (1975–1990) and a dry period (1991–2014). To investigate the deepening of the spring drought in Korea, a difference in the spring means between the 1991–2014 and 1975–1990 periods was analyzed with respect to large-scale environments. In the recent spring, a typical pressure system pattern in winter, which was an anomalous west-high east-low pressure system pattern, was strengthened throughout the troposphere around Korea. Due to the anomalous pressure system pattern, Korea was affected by relatively cold and dry anomalous northerlies. Furthermore, the western North Pacific subtropical high (WNPSH) was not intensified, and thus the supply of warm and moist airs into Korea was further reduced due to the upper-level jet moving further to the south. In order to determine the reason for the development of the anomalous west-high east-low pressure system pattern in East Asia, the difference in spring snow depth between the two periods was analyzed, and the analysis results showed that positive anomalies were predominant throughout most regions in East Eurasia. As a result, in the analysis of the ground heat net flux, negative anomalies were strengthened in most regions in East Eurasia. The cooling effect in the surrounding regions due to the high snow depth in East Eurasia strengthened the anomalous pressure system pattern as a west-high east-low type.