南海神狐海域天然气水合物注热降压开采数值模拟研究

针对南海神狐海域天然气水合物成藏条件,利用pT+H软件和水平井技术对天然气水合物的注热和注热降压开采效果进行了模拟分析。重点讨论了注入热水温度为30、60、90℃时水合物饱和度以及CH4气体饱和度、CH4产气率、累积CH4产气量和产水量的变化规律,发现两种开采模式下水合物低饱和度分布范围随时间增长和温度升高而增大;CH4产气率在开采10 d内升高较快,之后逐渐减小。模拟结果表明:注热降压开采模式比单纯注热模式的效果有较大改善,而且温度对于提高CH4产气量效果不明显,但因为天然气水合物藏的低渗透性,神狐海域的天然气水合物的CH4产气量不大。研究结果可为南海神狐海域和类似地区天然气水合物开采提供参考。     

历史极端雨涝事件研究——1823年我国东部大范围雨涝

1823年(清道光三年)我国发生大范围、多流域的严重雨涝,这是在小冰期寒冷气候背景下的重大气象灾害和极端气候事件.文章依据历史文献记载复原了1823年的气候实况并绘图显示,指出该年我国华北夏季雨期长、多大雨,北京6～8月雨日53天、降水量663mm超过现代(1971～2000年)平均值5成;长江中下游全年多雨,梅雨期长...     

城市开发区工业与生活混合污水处理设计——以四川省成都市某工业开发区为例

城市工业开发区建设时推荐我国工业规模化和产业结构升级的重要措施和手段.但随着而来的是各种各样的工业废水、生活污水汇聚,为城市污水处理厂设计和工艺选择提出了新的要求.文章以四川省成都市为例,生化处理部分采用改良A2/O工艺.结果表明,该工艺具有较好的除氮去磷效果,出水可稳定达到国家<城镇污水处理厂污染物排放标准>(GB1...     

鄂尔多斯盆地旦八油田延长组长3储层研究

三叠系延长组长3储集层灰色细粒长石砂岩储层物性差,属低孔、低渗储层.空隙以粒间孔、溶孔为主,且成岩作用控制孔隙结构.根据岩性、物性特征,把研究区储层分为四类:Ⅰ类好储集层,Ⅱ类较好储集层,Ⅲ类较差储集层,Ⅳ类非储层.     

四溴双酚A的合成工艺改进

以乙腈为溶剂,在H2O2存在下,以双酚A、溴为原料制备了四溴双酚A,讨论了加料方式、搅拌速率、n(Br2)/nBPA、反应温度、氧化剂的滴加速度等工艺条件对制取四溴双酚A产率的影响。在选定的实验条件下制取四溴双酚A的产率可达95.2%。     

NNFFC-adaptive output feedback trajectory tracking control for a surface ship at high speed

An adaptive output feedback controller based on neural network feedback-feedforward compensator (NNFFC) which drives a surface ship at high speed to track a desired trajectory is designed. The tracking problem of the surface ship at low speed has been widely investigated. However, the coupling interactions among the forces from each degree of freedom (DOF) have not been considered in general. Furthermore, the influence of the hydrodynamic damping is also simplified into a linear form or neglected. On the contrary, coupling interactions and the nonlinear characteristics of the hydrodynamic damping can never be neglected in high speed maneuvering situation. For these reasons, the influence of the nonlinear hydrodynamic damping on the tracking precision is considered in this paper. Since the hydrodynamic coefficients of the surface ship at high speed are very difficult to be accurately estimated as a prior, it will be compensated by NNFFC as an unknown part of the tracking dynamics system. The stability analysis will be given by the Lyapunov theory. It indicates that the proposed control scheme can guarantee that all the signals in the closed-loop system are uniformly ultimately bounded (UUB), and numerical simulations can illustrate the excellent tracking performance of the surface ship at high speed under the proposed control scheme.     

EH4方法在辽宁本溪大台沟铁矿勘查中的应用

EH4连续电导率剖面测量是近年来地质勘察中采用的新方法,可以推断隐伏铁矿体的埋深、宽度、规模及产状。本溪大台沟铁矿勘查中进行了EH4连续电导率剖面测量,经钻探验证。取得了较好的效果。寻找深部隐伏铁矿体,磁法测量和EH4测量2种方法综合运用,为后续钻探工作提供更充分的依据。     

1819年黄河中游极端降水:史实、特征及气候背景

据清官档案与方志记载,复原了1819年(清嘉庆二十四年)黄河中、下游大范围房屋倒塌、民田冲没、人口伤亡、黄河多处决溢等雨涝灾情图景及时空分异特征,这是在明清小冰期大气候背景下的极端气候事件和重大气象灾害.研究指出,该年黄河中游夏秋季雨期长(连阴雨)、且多大到暴雨,二级流域(汾河、渭河)6-9月份降水县区雨日高达40日以...     

CaSO4-C-H2O体系研究：模拟实验与热力学探讨

传统认为TSR成因的固态沥青(焦沥青)属于热化学反应的终端产物,不会对TSR的反应进程起到重要作用.本文以活性炭作为固态沥青(焦沥青)的模型化合物,开展了CaSO4-C-H2O体系的热模拟实验研究,探讨了CaSO4-C-H2O体系发生TSR的热力学特征.实验结果表明,CaSO4-C-H2O体系在300℃时即可启动TSR,主要生成CaCO3、H2S和CO2等产物.这一TSR门限温度要远低于以往室内利用气态或液态烃类进行的TSR模拟实验温度范围,与热力学计算结果一致.利用HSC Chemistry 5.0软件进行TSR过程模拟,发现25～200℃时CaSO4-C-H2O体系发生的TSR完全受动力学控制,在温度保持不变情况下,压力增大不利于CaSO4-C-H2O体系发生TSR.较少的含水量对TSR有一定促进作用,而含水量过多则可能抑制TSR的进行,含水量对TSR的影响可能与CaSO4在水中的饱和浓度有关.在一定的温度下,当体系pH≤2时,随着pH逐渐降低,CaSO4的量呈线性递减,但在沉积盆地地层水pH范围内(pH＞4),pH对TSR的作用可以忽略不计.CaSO4-C-H2O体系发生的TSR反应是一个放热过程,并且随着温度升高,反应热逐渐增大.在25～200℃范围内,TSR反应热为12.9～133 J/molCaSO4.热力学计算以及模拟实验结果均暗示,固态沥青(焦沥青)可能比烃类更容易参与TSR.     

Correlation of the middle devonian formations of Australia

In the Precambrian rocks west and southwest of the Mount Isa Fault three significant fold generations are recognized. Within individual successions, units containing an early phase of deformation are juxtaposed by a late fault against a sequence that does not share these earlier events.

Many of the large‐scale structures in the Judenan Beds are first‐generation folds, whereas west of the Judenan Beds the area is dominated by second‐generation folds. These two sets of folds are tentatively correlated and are referred to as the Judenan Folds. An earlier set of pre‐Judenan folding is only found in the units west of the Judenan Beds. One phase of the Sybella Granite is also associated with the Judenan folding. Later small‐scale folds associated with a crenulation cleavage are, however, of little regional importance and are commonly found only in zones of highly deformed rocks.