Change of Organic δ13C in Ornithogenic Sediments of the Xisha Archipelago, South China Sea and its Implication for Ecological Development

Organic carbon isotopes in sediments have been frequently used to identify the source of organic matter.Here we present a study of organic δ~(13)C on two sediment profiles influenced by guano from Guangjin and Jinqing islands in the Xisha Archipelago,South China Sea.Organic matter from ornithogenic coral sand sediments has two main sources,guano pellets and plant residues,and their organic δ~(13)C(δ~(13)C_(OM)) are significantly different.Organic carbon δ~(13)C_(guano) is much higher thanδ~(13)C_(plants),and δ~(13)C_(OM)of bulk samples is intermediate.Based on a two-end-member mixing model,the proportions of guano-and plant-derived organic matter in the bulk samples were reconstructed quantitatively.The results showed that seabirds began to inhabit the islands around approximately1200-1400 AD,and that guano pellets have been an important source of soil organic matter since then.With the accumulation of guano-derived nutrients,plants began to develop prosperously on the islands in the last 200 years,which is reflected by the significant increase of plant-derived organic matter in the upper sediment layer.However,guano-derived organic matter decreased greatly in recent decades,indicating a rapid decrease in seabird population.Our results show that organic δ~(13)C can be effectively used to quantitatively determine different source contributions of OM to bulk ornithogenic coral sand sediments.     

三峡重庆地区钻孔应变资料可靠性检验与分析

对三峡重庆地区6个四分量钻孔应变资料进行可靠性分析,利用其增量观测数据进行相对标定,得到各站点测区的应变参数,并分析测区相对应变特征。结果表明,6个站点的钻孔应变观测资料是可靠的,其中1个站点测区面应变呈现张性变化,靠近三峡库首区的5个站点测区面应变呈现压性变化,测点主压应变方向与大范围构造应力场方向较为一致,表明三峡重庆地区呈现压性特征。     

青藏高原湖泊面积动态监测

高原湖泊的动态变化对区域水循环具有重要影响。受全球气候变化的影响,青藏高原湖泊自20世纪90年代开始呈现剧烈扩张趋势。为揭示近年来青藏高原湖泊面积的时空变化规律,本文提出了一种改进的半自动湖泊提取算法,结合环境减灾卫星（HJ-1A/1B）和Landsat系列卫星影像数据,对青藏高原内流流域中面积大于50 km²的127个湖泊进行了连续6年的动态监测,并分析了该区域2009-2014年湖泊面积时空变化特征。研究结果表明,该区域湖泊整体呈现显著扩张趋势,年均变化速率为231.89 km²yr^-1（0.87 %yr^-1）,6年间湖泊面积扩张速率有所减缓。其中,扩张湖泊有104个,收缩湖泊有23个,变化速率分别为271.08 km²yr^-1（1.02 % yr^-1）和-39.19 km²yr^-1（-0.15 %yr^-1）。不同区域湖泊面积变化具有明显差异,主要表现为东部及北部大部分区域湖泊扩张,南部地区大部分湖泊面积稳定,萎缩湖泊主要分布于研究区四周。最后,本文通过分析冰川融水补给对湖泊面积变化的影响,发现存在冰川融水补给的湖泊面积变化率远大于不存在冰川融水补给的湖泊。由此可见,近年来冰川融水的增加是促进青藏高原内流流域湖泊扩张的主要因素之一。     

不同植被红边指数在城市草地健康判别中的对比研究

遥感红边指数与表征绿色植物生长状况的重要生化参数有密切的关系,是植被长势监测的重要因子。为寻找出最适用于城市草地生长状况监测的红边指数,本文基于Sentinel-2A数据,对比分析了不同红边指数在城市草地健康状况估算方面的差异。本文以福州市和厦门市的城市草地为例,在全面分析各种健康水平草地光谱响应特征差异的基础上,选取了6种与草地生化参数相关的红边指数,即红边位置REP、地面叶绿素指数MTCI、归一化差值红边指数NDRE1、新型倒红边叶绿素指数IRECI、红边叶绿素指数CI_red-edge以及叶绿素吸收指数MCARI2,然后采用独立样本T检验及欧式距离对这6种红边指数在草地健康判别中的优劣进行了定量对比。结果表明：IRECI指数对草地健康状况最为敏感,该指数在不同健康等级草地的值域区间和均值都存在显著性差异,其判别总精度均大于85%;NDRE1和MCARI2指数次之,其他3个指数则难以判别草地的健康状况。因此,在基于Sentinel-2A影像的城市草地健康遥感判别中,推荐使用IRECI指数。     

不同城市规划的生态质量差异对比研究

为定量分析不同城市规划理念带来的生态质量差异,本文以福州市在不同时期规划建设的2座体育场馆为例,基于Sentinel-2A遥感影像,应用新型遥感生态指数RSEI分析对比了这2座体育场馆的生态效应。在全面分析其主要地表覆盖信息的基础上,探讨了二者之间生态质量差异的原因。研究发现,采用传统理念规划的福建省奥林匹克体育中心的生态指数RSEI均值为0.39,而实行绿色生态规划的海峡奥林匹克体育中心的RSEI均值为0.42,优于福建省奥林匹克体育中心。总的看来,海峡奥体中心在规划中采用透水铺装和不勾缝的铺装形式,加大绿地斑块面积以及预留风道等绿色措施有效地提高了地表湿度、降低了地表温度和干度,从而对该体育中心的生态质量起到积极的作用。     

5V正极材料LiNi_(0.5)Mn_(1.5)O_4的制备及电化学性能研究

采用溶胶-凝胶-自蔓延燃烧法和固相法制备了LiNi0.5Mn1.5O4,XRD图谱表明由溶胶-凝胶-自蔓延燃烧法得到纯相的LiNi0.5Mn1.5O4,而用固相法制成的LiNi0.5Mn1.5O4中含杂相物质。采用恒流充放电和倍率放电等分析方法对LiNi0.5Mn1.5O4/Li电池进行测试。结果表明溶胶-凝胶-自蔓延燃烧法制备的样品所组装电池放电容量较高,工作电压较高,循环稳定性较好,且倍率性能优良。     

Recent warming in the Yellow/East China Sea during winter and the associated atmospheric circulation

We examine characteristics in the variability of sea surface temperature (SST) in the Yellow/East China Sea during the boreal winter (December–January–February) for the period 1950–2008 in observations. It is found that the mean SST in the Yellow Sea/East China Sea gradually increases during recent decades. A warming trend of a basin scale SST is significant in most of the regions in the Yellow/East Sea, which is well explained by the variability of the first empirical orthogonal function SST mode. We suggest one candidate mechanism that the North Pacific oscillation (NPO)-like sea level pressure play an important role to warm the Yellow/East China Sea. Anomalous anticyclonic circulation, which is the southern lobe of NPO-like sea level pressure over the North Pacific, causes a weakening of northerly mean winds over the Yellow/East China Sea during winter. This contributes to increase in the SST in the Yellow/East China Sea through the changes in the latent heat and sensible heat fluxes.     

龙岩地震台GM4型磁通门磁力仪典型干扰分析

GM4型磁通门磁力仪是"十五"项目中地磁学科主要仪器。龙岩台GM4型磁通门磁力仪主要受到来自铁磁性物质和电磁类型的干扰。由已知干扰类型,对记录曲线典型畸变形态进行对比、分析、总结,可以更好分辨干扰,进行恰当、合理、准确地预处理,保证数据的连续、可靠、精确。     

西南岩溶地区找水的地球物理方法探讨

总结了目前国内主要的物探找水技术方法,分析了各种方法的优缺点及其适应范围。以云南个旧市的找水成果作为典型案例,重点介绍了EH4电磁成像找水方法的技术特点、在岩溶区找水的可行性分析、数据处理和成果解释过程,最后推断出可能存在地下水的位置,并布设井位用于指导施工。后期追踪调查表明,勘察区已成功打出地下水,证明了使用EH4电磁成像技术在岩溶区找水的可行性。     

Selective Solid Phase Extraction for Separation and Preconcentration of Palladium from Gold Ore and Anode Slime after Complexation with a N4O2 Mixed Donor Ligand Derivative

A selective and sensitive method for the preconcentration, separation, and determination of palladium with flame atomic absorption spectrometry using 4,15‐bis[(4‐methylphenyl)sulfonyl]‐20,21‐dinitro‐2,3,4,5,6,7,9,10,12,13,14,15,16,17‐tetradecahydro‐8,11‐ethano‐1,18,4,8,11,15‐benzodioxa tetraaza cycloicosine (TNACIN) on XAD‐2010 was developed. TNACIN–Pd(II) complex formed acidic aqueous solution (0.075–0.100 M HNO₃) was accumulated on XAD‐2010 and then eluted with 1 M HCl in acetone. The effects of some analytical parameters including pH, TNACIN amount, sample volume, eluent type, and concentration, sample flow rate and matrix ions were studied for optimization of the method. Detection limit and precision were calculated for Pd(II). This method was also verified with CRM and internal standard, and satisfactory results were obtained.