Heat capacity of γ-Fe2SiO4 between 5 and 303 K and derived thermodynamic properties

A multi-anvil device was used to synthesize 24 mg of pure γ-Fe₂SiO₄ crystals at 8.5 GPa and 1,273 K. The low-temperature heat capacity (C _p) of γ-Fe₂SiO₄ was measured between 5 and 303 K using the heat capacity option of a physical properties measurement system. The measured heat capacity data show a broad λ-transition at 11.8 K. The difference in the C _p between fayalite and γ-Fe₂SiO₄ is reduced as the temperature increases in the range of 50–300 K. The gap in C _p data between 300 and 350 K of γ-Fe₂SiO₄ is an impediment to calculation of a precise C _p equation above 298 K that can be used for phase equilibrium calculations at high temperatures and high pressures. The C _p and entropy of γ-Fe₂SiO₄ at standard temperature and pressure (S°₂₉₈) are 131.1 ± 0.6 and 140.2 ± 0.4 J mol⁻¹ K⁻¹, respectively. The Gibbs free energy at standard pressure and temperature (ΔG° _f,298) is calculated to be −1,369.3 ± 2.7 J mol⁻¹ based on the new entropy data. The phase boundary for the fayalite–γ-Fe₂SiO₄ transition at 298 K based on current thermodynamic data is located at 2.4 ± 0.6 GPa with a slope of 25.4 bars/K, consistent with extrapolated results of previous experimental studies.     

新疆地区表土孢粉分布规律及其与植被关系研究

对中国新疆地区218个样点进行植被调查及表土孢粉分析的研究结果表明,新疆地区温带山地针叶林、高寒草甸及盐生草甸、温带草原、荒漠以及荒漠-沙漠过渡带均具有相对特殊的孢粉组合,新疆南北向样带的孢粉图式揭示出表土孢粉从北到南随地形、纬度和植被的改变而发生的空间变化。针叶林区表土孢粉浓度平均值为22 602粒/g、草原为3 834粒/g、荒漠为1 762粒/g、沙漠为0-10粒/g。但在同一植被类型中,特别是在草原和荒漠中,孢粉浓度与植被盖度之间并不呈现线性相关关系。根据大空间尺度样品的A/C(蒿Artemisia/藜Chenopodiaceae)值的中位数统计,草原为1.264、荒漠为0.565、沙漠为0.243。Ep/C(麻黄Ephedra/藜Chenopodiaceae)比值的中位数在荒漠为0.098、草原为0.063。     

青藏高原崇测冰芯氯离子、硫酸根离子记录

通过对青藏高原崇测冰帽一支18．70m冰芯中Cl^-、SO4^2-离子含量变化的分析表明，20世纪90年来Cl^-、SO4^2-离子含量在波动中呈下降趋势，两种离子的周期性波动变化相似，20世纪晚期比早期和中期的波动幅度小，总体上离子含量逐渐减少与温度在波动中上升相一致，但每一次温度的升高与离子含量的下降并非一一对应。陆源物质和青藏高原上的盐湖是冰芯中Cl^-、SO4^2-离子的主要贡献者。揭示了研究地区大气成分和环境变化与气候变化的关系及亚洲粉尘在全球环境变化中的源区地位。     

海南三亚地区S4指数与C/N、ROTI的比较分析

本文通过利用海南三亚站（1834°N, 10962°E）GPS闪烁/TEC接收机2004年8月到2005年7月间观测数据，在对三亚地区闪烁初步统计分析的基础上，比较分析了观测数据中S₄（幅度闪烁指数）和C/N（载噪比），S₄和ROTI（TEC变化率标准差）的关系，同时对2004年11月7日的闪烁事件进行了具体的分析. 通过比较分析得出：（1）三亚地区全年的闪烁强度具有明显的半年变化，在春秋季出现全年闪烁强度的最大值；（2）S₄与C/N具有很好的负相关性；（3）ROTI可以作为由小尺度不规则结构引起闪烁出现的指示剂.     

High-resolution climate variability of southwest China during 57-70 ka reflected in a stalagmite δ18O record from Xinya Cave

A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS ²³⁰Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ ¹⁸O and δ ¹³C, mostly in the 2.3–26 cm part. The δ ¹⁸O and δ ¹³C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval. Speleothem δ ¹⁸O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ ¹⁸O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18 respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ ¹⁸O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ ¹⁸O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously published speleothem records. According to SPECMAP δ ¹⁸O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record, the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS 4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology. The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having climatic significance. Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician Special Project of Chongqing Science Committee (Grant No. 2003-7835)     

铼—锇同位素分析中试样化学预处理方法进展

评述了用于Re-Os同位素体系分析的化学前处理技术的发展。简要介绍了卡洛斯管熔样法、Os的CCl4提取、溴提取和微蒸馏方法。卡洛斯管封闭熔样方法，有效地防止了Os的挥发损失和保证了Os同位素平衡，是一种很有发展前景的熔样方法。蒸馏法仍是分离和纯化Os的有效方法，溶剂（CCl4)提取和溴提取法在许多实验室里应用，而微蒸馏则是Os的二次纯化的主要方法。Re的化学分离和纯化仍是离子交换和萃取法。引用主要文献29篇。     

塔里木盆地哈得4油田成藏年代学研究

哈得4油田是近年来在满加尔凹陷北部发现的第一个海相油田，一直被认为是喜山期形成的油藏。然而，根据包裹体测温、伊利石K／Ar同位素测年以及油气水界面追溯等多种方法对其成藏年代重新研究表明，该油田主力油藏石碳系CⅢ油藏主杰晚海西期形成的古油藏，C5薄砂层油藏则可能为喜山期由CⅢ油藏垂向调整形成的次生油藏。     

FBS-3A型反馈式宽频带地震计电流标定方法研究

随着时间的推移和环境条件的缓慢变化，地震计各部件的性能参数会有所改变，及时了解这种变化并加以控制和调整，有助于提高地震计输出结果的可信度．所以，一台地震计无论在交付使用前，还是在使用过程中，都需要进行标定．目前，比较常用的标定方法有方波电流标定和正弦电流标定．本文从系统分析的角度出发，在分析得到地震计传递函数的基础上，将方波电流标定和正弦电流标定过程进行理论抽象，进而在复频域对两种电流标定过程进行仿真推导；并在此基础上，讨论了方波电流标定输出曲线与地震计固有参数之间以及正弦电流标定的稳态输出与标定电流之间的关系，并且论述了两组特定频率正弦电流的标定输出之间的关系．最后，作为理论分析在实践中的具体应用，给出了两种电流标定过程在实际工作中的应用方法．本文旨在阐明两种常用的电流标定方法的物理意义，对地震计的调试及应用有积极的参考作用．      

珠江三角洲地区由海风锋触发形成的强对流天气过程分析

使用自动气象站、雷达回波、卫星云图、常规天气图、探空和风廓线仪等有关观测资料, 普查了1998年7月上旬珠江三角洲地区8次由海风锋触发形成的强对流天气过程, 并对其中7月3日过程进行了综合分析, 归纳出该类强对流天气过程的一些活动特征和规律。     

面向国土资源调查的地理信息系统集成方案研究

分析国内外国土资源调查中GIS方法研究和应用的现状和趋势 ,提出基于多层次GIS集成的国土资源大调查思路 ,介绍和总结在大调查中应该关注的地理信息系统方法和应用。同时指出我国国土资源大调查的重点在开展微型化嵌入式GIS、三维 /四维GIS、网络GIS等方面的研究。