Characteristics of ionic components in precipitation in Kitakyushu City,Japan

Precipitation samples were collected by filtrating bulk sampler in Kitakyushu City, Japan, from January 1988 to December 1990. Volume weighted annual mean of pH was 4.93, but the pH distribution indicated that most probable value lay in the range pH 6.0–6.4. Volume weighted annual mean concentrations of major ionic components were as follows; SO ₄ ^2– : 84.2, NO ₃ ^– : 28.1, Cl^–: 86.3, NH ₄ ⁺ : 45.5, Ca²⁺: 63.3, Mg²⁺: 27.0, K⁺: 3.4, Na⁺: 69.0 µ eq l^–1. The highest concentrations of these ionic components were observed in winter and the lowest occurred in the rainy season. The ratio of ex-SO ₄ ^2– /NO ₃ ^– exhibited the lowest ratio in summer, and the highest ratio in winter. Good correlations were obtained between Cl^– and Na⁺, ex-SO ₄ ²⁺ and ex-Ca²⁺, NO ₃ ^– and ex-Ca²⁺, and NH ₄ ⁺ and ex-SO ₄ ^2– , respectively. However, no correlation between Cl^– and Na⁺ with Ca²⁺ was observed. The relationship of H⁺ with (ex-SO ₄ ^2– + NO ₃ ^– ) - (ex-Ca²⁺ + NH ₄ ⁺ ) indicated positive correlation.     

海城震区深地震测深资料A/D转换方法及其效果的研究

介绍深地震测深模拟磁带资料在CROMEMCO型微机上实现A/D转换的方法及其效果。在实现A/D转换研究中,进行了时标信号采集方式、六响信号处理、模拟回放电路改进等方法的试验,从而提高了A/D转换精度与效果。经对海城震区实际资料分析可知:该系统A/D转换精度达到了规范要求。     

矿山地理信息系统中的空间和时间四维数据模型

现有的许多地理信息系统（GISs）一般都没有考虑时间这一维数据。本文依据矿山的特点和需求，提出了能满足空间和时间要求的GIS的概念。针对传统数据模型所存在的缺点，以及根据处理历史数据所具有的特点，提出了一种用于矿业开发的空间和时间综合四维数据模型。这种模型通过采用四维空间线性编码技术，可大大减少数据存贮所需的辅助操作。为了适应综合四维数据处理的需要，笔者研究出了一种新的拓扑结构——四维空间和时间因素的拓扑关系。     

Identification and occurrence of novel C36–C54 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.     

HP—3808A测距仪测距精度分析

本文采用数理统计方法,详细分析了HP—3808A激光测距仪近几年来积累的测量数据,求得仪器平均测距相对精度为1:70万。并且讨论了进一步提高测距精度的技术措施。     

豫北及其外围地区地壳上地幔结构研究

利用菏泽～长治和郑州～济南深地震测深剖面资料，进行了一维、二维射线追踪走时拟合与合成地震图计算，获得了该区地壳上地幔速度结构。结果表明，地壳上地幔速度结构在纵向和横向上具有明显的不均一性。浅部断裂较发育，对应其地壳深部界面和速度等值线起伏变化较明显。在华北坳陷区南部上地幔隆起的背景上存在两个局部凸起，凸起最高处与浅部的东濮凹陷、汤阴地堑基本对应，Ｍ面埋深分别约３１ｋｍ和３４ｋｍ     

Beeinflussung der Enzymaktivität einer Protease durch Huminstoffe Influence of Humic Substances on the Activity of a Protease

This paper deals with the influence of different humic substances (HS) on the enzyme activity (EA) of the proteolytic enzyme pronase E. The EA was determined by analyzing the concentration of the amino acid valine hydrolyzed from caseine. For amino acid analysis, a flourescence detector was used after precolumn derivatization and HPLC-separation of the hydrolysis products. The data show that the presence of HS has no adverse effects on amino acid analysis. Based on this result, a decrease of EA was observed in the presence of HS acting as enzyme inhibitors. Clear inhibition effects could be seen for different fulvic acids (HO3 FA, FBR FA and FBR 1.0 FA) at concentrations of 150 mg/L. In case of FBI-2 FA, higher concentrations were necessary to decrease the EA significantly. At an inhibitor concentration of 1500 mg/L the EA was mostly found to be less than 50%. The standard deviations of the results don't allow a differentiation between the HS of different origin and treatment. Specifying HS according to their influence on EA has to remain uncertain. As shown in a kinetic study of the hydrolysis of L-Leucine-2-naphthylamide-hydrochloride, the inhibitor HO3 FA decreases the maximum velocity of the reaction but has no effect on the Michaelis constant. These results indicate that this HS acts as a noncompetitive inhibitor.     

Biological marker compounds as indicators of the depositions! history of the Maoming oil shale

The Eocene Maoming oil shale from Guangdong Province occurs as a laterally uniform stratigraphic section, typically 20–25 m thick, from which the aliphatic hydrocarbon constituents of six representative samples were investigated using GC and C-GC-MS. The sediments evaluated included the basal lignite, a vitrinite lens from the overlying claystone, and four intervals from the massive oil shale bed. As expected, the lignite and vitrinite differ markedly from the oil shales. The lignite is dominated by bacterial hopanoids and components of higher plant origin, including C₂₉ steroids and triterpenoids such as oleanenes. Visually, the oil shale samples show corroded and degraded phytoclasts, spores, wispy particles of fluorescent organic material attributable to dinoflagellates and, especially in the uppermost sample, colonial algal bodies. The distributions of biological markers in the oil shales show many features in common, notably a dominance of dinoflagellate-derived 4-methylsteroids, and a significant proportion of higher-plant derived n-alkanes with marked odd-over-even carbon number predominance. Overall, they exhibit several features that resemble characteristics of the Messel shale. The hydrocarbons of the lowest shale horizon suggest that there may have been a gradual transition between deposition of the original peat and the subsequent oil shales. The aliphatic hydrocarbons of the uppermost shale are dominated by a number of C₃₁ and C₃₃ botryococcane homologues and other unusual branched alkanes possibly derived from green algae. All of the samples are immature. Overall, molecular and microscopic examination of the stratigraphic succession of the Maoming oil shale suggests a shallow, lacustrine environment within which peats were deposited. This lake subsequently deepened to support abundant algal populations, especially dinoflagellates, culminating in a dominance of botryococcoid algae.     

成层介质中交流电测井响应

本文给出了纵向成层、径向不均匀介质中轴对称电磁波的反射阵和透射阵的递推公式．用这些阵可以计算交流电测并响应，包括感应测并和深探测电磁波传播测井（ＤＰＴ）．同时还给出了幅度基函数和斜度基函数，它们分别＂支撑＂起结点上函数的幅度和斜度．     

粘滑失稳及其物理场时空分布的实验研究

摩擦滑动的物理场实验研究表明：（１）能量空间分布的差异是失稳的重要条件，单发型大事件常发生于高能量向低能量的突变带或高能量背景区内的相对低能量区；（２）单发型大事件的孕育过程常常经历若干个能量输入输出循环，产生多个前兆阶段，并在失稳前源区常有一个弱化过程。小震或群发型事件失稳前常常只有一个能量积累与强化的过程，失稳前兆阶段性反映较差；（３）粘滑失稳时断层的位错与声发射的大小未见明显关系