高效液相色谱法测定贵州铜仁地区优质矿泉水中16种多环芳烃

本文使用高效液相色谱仪对贵州铜仁地区优质矿泉水中16种多环芳烃进行分析测试,研究了测定优质矿泉水中多环芳烃的方法,并进行了方法验证和实际样品测试,对仪器柱温箱温度和萃取溶剂种类等条件进行优化,选出最适条件。建立的检测方法线性关系良好(R2均大于0. 999 0),检出限为0. 002 6 0. 009 8μg/L,16种多环芳烃的回收率为73. 87%116. 16%,替代物十氟联苯的回收率为70. 17%85. 61%,方法精密度(RSD)为0. 85%16. 77%。方法前处理过程简单,有利于实际样品快速分析,在贵州铜仁地区优质矿泉水资源调查项目中发挥重要作用。     

SRES A2 情景下中国区域性高温热浪事件变化特征

随全球变暖,应对高温热浪事件是未来现代化城市面临的难题之一。本文利用全球模式-HadAM3p提供的3组不同边界场和初始场驱动区域气候模式系统PRECIS的输出结果,模拟未来情景下中国区域性高温热浪事件发生频率、强度及持续时间的变化趋势。结果表明：全球PRECIS对基准时段（1961-1990年）的高温热浪事件的发生的频率、强度和持续时间及对应的大气环流特征具有较强的模拟能力。相对于基准时段,未来情景下未来时段（2071-2100年）中国各地区的高温热浪的强度增加,发生频率增幅超过了100 %,且持续时间增加30 %以上。此外,观测资料和模拟结果均表明武汉和哈尔滨地区的高温热浪与500 hPa高度场的正距平密切相关。而未来情景下,武汉和哈尔滨地区500 hPa高度场的正距平呈增加趋势,表明这些地区未来可能面临危害更严重的高温热浪事件。     

Determination of total sulfur in geothermal water by inductively coupled plasma-atomic emission spectrometry

Sulfur speciation and concentration in geothermal water are of great significance for the research and utilization of the water resources. In most situations, it is necessary to determine the total sulfur in geothermal water. In this study, the method was established for the determination of determining total sulfur content — the inductively coupled plasma-atomic emission spectrometry (ICP-AES), with the wavelength of 182.034 nm selected in spectral line of sulfur. It was identified that the optimal working conditions of the ICP-AES instrument were 1 200 W for high frequency generator power 9 mm for vertical observation height, 0.30 MPa atomizer pressure, and 50 r/min analytical pump speed. The matrix interference of the method was eliminated by the matrix matching method. Using this method, sulfur detection limit and minimum quantitative detection limit were 0.028 mg/L and 0.110 mg/L, respectively, whilst the linear range was 0.0–100.0 mg/L. The recovery rate of sample was between 90.67% and 108.7%, and the relative standard deviation (RSD) was between 0.36% and 2.14%. The method was used to analyze the actual samples and the results were basically consistent with the industry standard method. With high analysis efficiency, the method has low detection limit and minimum quantitative detection limit, wide linear range, good precision and accuracy, and provides an important detection method for the determination of total sulfur in geothermal water.     

Numerical 3D modeling of the effects of strain rate and confining pressure on the compressive behavior of Kuru granite

This paper deals with numerical modeling of the compressive behavior of granite rock under high strain rate dynamic loading and wide range of confining pressure. For this end, a constitutive model based on damage mechanics and viscoplasticity for rock is formulated and implemented in explicit dynamics FEM. The viscoplastic part is based on a simple power law type yield criterion that incorporates the rate-dependency with a linear viscosity term. Moreover, a Rankine type of tensile cut-off is employed. The damage part of the model is formulated with separate scalar damage variables in tension and compression. The model is calibrated for Kuru granite and validated with the experimental data from dynamic compression tests at the strain rate of 600 1/s up to 225 MPa of confining pressure. The numerical simulations demonstrate that, despite the underlying continuum modeling approach, the model captures the correct experimental failure modes, including the transition from single-to-multiple fragmentation, as well as the dynamic compressive strengths at different confining pressures.     

Paleoproterozoic juvenile magmatism within the northeastern sector of the São Francisco paleocontinent: Insights from the shoshonitic high Ba–Sr Montezuma granitoids

New,integrated petrographic,mineral chemistry,whole rock geochemical,zircon and titanite UPb geochronology,and zircon Hf isotopic data from the Montezuma granitoids,as well as new geochemical results for its host rocks represented by the Corrego Tingui Complex,provides new insights into the late-to post-collisional evolution of the northeastern Sao Francisco paleocontinent.U-Pb zircon dates from the Montezuma granitoids spread along the Concordia between ca.2.2 Ga to 1.8 Ga and comprise distinct groups.Group I have crystallization ages between ca.2.15 Ga and 2.05 Ga and are interpreted as inherited grains.Group II zircon dates vary from 2.04 Ga to1.9 Ga and corresponds to the crystallization of the Montezuma granitoids,which were constrained at ca.2.03 Ga by the titanite U-Pb age.Inverse age zoning is common within the ca.1.8 Ga Group III zircon ages,being related to fluid isotopic re-setting during the Espinhaco rifiting event.Zircon ε_(Hf)(t) analysis show dominantly positive values for both Group I(-4 to+9) and Ⅱ(-3 to+8) zircons and T_(DM2) model ages of 2.7-2.1 Ga and 2.5-1.95 Ga,respectively.Geochemically,the Montezuma granitoids are weakly peraluminous to metaluminous magnesian granitoids,enriched in LILES and LREE,with high to moderate Mg#and depleted in some of the HFSE.Their lithochemical signature,added to the juvenile signature of both inherited and crystallized zircons,allowed its classification as a shoshonitic high Ba-Sr granitoid related to a late-to post-collisional lithosphere delamination followed by asthenospheric upwelling.In this scenario,the partial melting of the lithospheric mantle interacted with the roots of an accreted juvenile intra-oceanic arc,being these hybrid magma interpreted as the source of the Montezuma granitoids.The Corrego Tingui Complex host rocks are akin to a syn-to late-collisional volcanic arc granitoids originated from the partial melting of ancient crustal rocks.The results presented in this study have revealed the occurrence of juvenile rocks,probably related to an island arc environment,that are exotic in relation to the Paleo-to Neoarchean crust from the Sao Francisco paleocontinent's core.     

贵州海马谷地区金矿矿床特征及成矿模式

本文对海马谷地区金矿进行调查,在贵州安龙海马谷发现北东向陡倾角断层控制金矿体,其围岩为二叠系茅口组生物灰岩,矿石为硅化灰岩角砾岩。根据本次调查及收集已有勘查研究成果,建立了该区的成矿模式,认为该区北东向陡倾角断层是下一步该区重要的找矿目标。     

Coda waves: A review

The analysis and interpretation of coda waves have received increasing attention since the early seventies. In the past few years interest in this subject has spread worldwide, and the study of high-frequency seismic coda waves has become a very important seismological topic. As a conclusion of the studies accomplished in this time, coda waves are considered the result of scattering processes caused by heterogeneities acting on seismic waves.P andS waves play a particularly important role in this interaction. The process introduces an attenuation which, added to the intrinsic absorption, gives the observed apparent attenuation. Therefore, coda waves constitute a thumbprint left by the heterogeneities on the seismograms. Coda waves offer decisive information about the mechanism of how scattering and attenuation take place. This review describes coda waves in detail, and summarizes the work done in this subject to 1986. The relation between coda waves and attenuation in the context of research on seismic scattering problems is stressed. Particular attention has been given to the application of coda waves to estimate source and medium parameters. The state-of-the-art of the temporal variations of coda wave shape, and the possible use of these variations as an earthquake precursor also are presented. Care has been taken to introduce the statistical models used to deal with the heterogeneities responsible for scattering.     

Estimating agricultural production in marginal and food insecure areas in Kenya using very high resolution remotely sensed imagery

Regularly monitoring the amount of food produced in food insecure, isolated, subsistence farming areas can be used to help identify households or communities who may be in need of additional food resources. Measuring seasonal food production in developing countries, particularly at a sub-national level, is complicated by lack of data. In this study we use high resolution remotely sensed data to calculate cultivated area in two different growing areas, during two different seasons in Kenya. The results of the research support the usefulness of this approach for agricultural monitoring in the developing world and suggest that monitoring cultivated area requires attention to the specific growing characteristics of an area.     

松嫩高平原县域土地利用空间格局地形梯度特征分析——以巴彦县为例

以黑龙江省巴彦县为研究区,基于研究区DEM数据,运用土地利用类型的分布指数、土地利用结构的信息熵、均衡度和优势度,明确研究区土地利用空间格局的地形梯度特征及地形因子对土地利用空间格局的影响。结果表明：① 研究区土地利用空间格局在地形因子的作用下存在明显的梯度特征,旱地、水田、草地、水域、建设用地及其他用地主要分布在较低地形级别区,林地主要分布在较高地形级别区。② 除林地以外,其他土地利用类型分布的优势地形位均位于较低地形级别区,林地分布的优势地形位位于较高地形级别区,各土地利用类型分布的优势区域不尽相同。③ 研究区土地利用结构的信息熵及均衡度变化趋势相同,优势度的变化趋势与信息熵、均衡度的变化趋势相反,土地利用空间格局与地形因子具有显著的相关性。     

羌塘南缘多龙矿集区荣那斑岩-高硫型浅成低温热液Cu-(Au)套合成矿:综合地质、热液蚀变及金属矿物组合证据

位于羌塘南缘多龙矿集区内的荣那斑岩-高硫型浅成低温热液Cu-(Au)矿床系近年来中铝西藏与西藏地质五队合作勘查取得重大找矿突破的铜矿床,控制资源量已达超大型规模,但对该矿床的成因类型仍存在争议。本文根据详细的钻孔岩芯、结合光学显微镜、扫描电镜观察、硫化物的电子探针分析,认为该矿床成矿与早白垩世花岗闪长斑岩有关。矿体主要产于下中侏罗统色哇组长石石英砂岩和成矿斑岩体中,矿体呈东西走向、南倾的隐伏状,延深巨大,金属矿化以铜为主,伴有金、银矿化,偶见钼矿化。热液蚀变具有两阶段蚀变:与斑岩型矿化有关的黑云母化、角岩化、硅化-绢云母化及硅化-伊利石-绿泥石化以上部叠加的高级泥化,蚀变分带明显。相应的该矿床具有斑岩型细脉浸染状矿化和以硫砷铜矿为特征的高硫型矿化,含铜矿物主要分为4个带,大致与蚀变分带相对应,下部主要为斑铜矿-黄铜矿;过渡带以斑铜矿-铜蓝组合为特征;中上部为蓝辉铜矿-砷黝铜矿-硫砷铜矿组合;顶部主要由为辉铜矿-蓝辉铜矿组成。总体上,矿床中上部为Cu-S体系、向下转变Cu-Fe-S体系。与其它类似矿床相比,该矿床硫化物中以富Zn、贫金为特征。综上认为该矿床为斑岩-高硫型浅成低温热液Cu-(Au)套合成矿的典型实例,其勘查突破为羌塘南缘火山岩区及覆盖区的找矿打开了一扇窗口。