高放废物处置库预选场地地学信息库的建立

本文以高放废物处置库预选场地甘肃北山玉门镇地学信息库的建立为例,详细阐述了地理信息系统在高放废物地质处置中的应用,并在此基础上分析了其应用前景,为不同层次的管理、科研人员提供了全新思路;介绍了将地理信息系统技术引入图件和资料管理的优点。     

A transdisciplinary analysis of water problems in the mountainous karst areas of Morocco

Water management and engineering in the karstic High Atlas of Morocco are difficult tasks under the prevailing geological, hydrogeological, geomorphological, vegetational and climatic conditions. It is important to be able to understand and predict the characteristics and availability of water for future water planning in the region under changing climatic and agricultural conditions. An interdisciplinary analysis of problems and adequate hydrological modelling tools developed by geologists, hydrologists and biologists are necessary. The karst areas of the High Atlas Mountains are characterised by impermeable triassic basalt underlying substantial subsurface reservoirs with high potential discharge rates. The karst groundwater aquifers are extensive but largely unknown in dimension, probably with a hierarchical network of groundwater flow paths. It is estimated that approximately 70% of the surface water is directly lost to groundwater. Steep landslide- and debris flow prone slopes exist next to coarse-grained, highly porous river beds. Infrequent, high intensity rainfall or snowmelt causes a particularly high flood risk to these karst areas. In addition, agriculture and land use changes have degraded the karst areas. The most important driving forces for degradation include permanent overgrazing even during droughts and the use of firewood by a continually growing population. Large scale degradation of vegetation has occurred in the oro-mediterranean (mountainous Mediterranean) zone, between 2600 and 3400 m which coincides with the most important zone for karstic groundwater creation. The combination of high amounts of groundwater flow and rapid surface flow due to sparse vegetation has increased the problems of flood flow.     

长石在高温高压条件下的物理化学行为

长石是地学上非常重要的矿物之一。它有可能随着板块俯冲而进入地球深部,因此它在高温高压条件下的相行为以及物理化学性质对地球深部地球动力学研究非常有意义。本文总结了长石端员组份(钾、钠、钙长石)以及其固溶体系列已知的高温、高压实验数据,并绘制成相图。已有的研究成果显示:这三种端员组份在高压下的相行为有较大差异,并产生了许多只在高温高压条件下稳定的相如K-Holl-I、K-Holl-II、CF、CAS及CaPv等。由这些高压相构成的具有长石成分的不同相组合的密度在约5~23GPa的压力范围内超过地幔岩的密度,因此这些相组合可以主动俯冲到上地幔的深处。另一方面,已有研究表明,这些高压相对碱金属及碱土金属在地幔中的赋存状态有着非常重要的影响。     

Influence of high-pressure processing on the structure and memory effect of synthetic layered double hydroxides

We investigate the structural evolution of synthetic layered double hydroxides (LDH) samples, processed at room temperature and high-pressure (up to 7.7 GPa) in a toroidal chamber with two pressure-transmitting media, lead and graphite, using X-ray diffraction, thermogravimetry and N₂-adsorption isotherms techniques. The X-ray patterns of compacted samples show a decrease in the peak intensities. For both pressure-transmitting media, our samples revealed a reduction of the basal d-spacing for the (003) plane when processed at 7.7 GPa. The expected high-pressure-induced amorphization was not observed. Surprisingly, we find high-pressure processing to have a strong influence on the memory effect of the LDH, due essentially to the reduction of the surface area and pore closing. Even when immersed in water, our samples did not recover the LDH structure, when either calcined at 450°C and compacted at 7.7 GPa, or calcined at 700°C and immediately compacted at 2.5 and 7.7 GPa.     

高温高压下水的剪切粘滞度的平衡分子动力学计算

本项工作用ＴＩＰ４Ｐ模型对水分子进行了平衡分子动力学模拟。根据Ｇｒｅｅｎ－Ｋｕｂｏ理论,计算了温度从６５２Ｋ到８１４Ｋ,密度从０．５３６０ｇ／ｃｍ３到０．８６３８ｇ／ｃｍ３六个不同温度和密度水的剪切粘滞度,并和实验值进行了对比。在所计算的温度和密度范围,平衡分子动力学计算结果与实验值的平均绝对值差别为１５％,好于使用非平衡分子动力学方法获得的粘滞度值。平衡分子动力学的方法将是获得地学中高温高压下流体输运性质的重要途径。     

断裂熔融作用中单质铁的形成及其指示的孕震环境

目前缺乏来自于地震断裂带的假玄武玻璃的原始特征研究,制约着我们对地震孕震环境和地震发生机制的认识。本文以龙门山断裂带汶川科钻2号钻孔岩心的碎裂岩及花岗闪长岩为研究对象,通过氩气环境下的高温加热实验(最高温度达1750℃)、显微结构观察、地球化学分析和岩石磁学测试,探讨断裂熔融作用中单质铁的形成及其指示意义。花岗闪长岩和碎裂岩在1100℃时发生部分熔融作用,形成了非晶质和微晶;在≥1300℃时形成了大量单质铁组成的微球粒,可能是含铁矿物发生了以碳物质为还原剂的高温还原反应。高温实验后样品的磁化率值高于碎裂岩的磁化率值,新生成的磁铁矿是≤1100℃的样品高磁化率值的主要原因;熔融作用中形成的单质铁和少量的磁铁矿是≥1300℃样品高磁化率值的重要原因。结合前人对于快速摩擦实验熔体、地幔物质及陨石的研究,我们认为粘土矿物、硅酸盐矿物含量较多的断层泥在同震滑移中因热增压机制很难形成单质铁;而花岗岩、安山岩、辉长岩、闪长岩等岩浆岩和糜棱岩在流体作用弱和硫化物含量低的环境中易在大地震中形成单质铁。龙门山断裂带的假玄武玻璃的熔融温度≥1300℃,硫元素含量较低并发现有过剩铁元素。因此,表明龙门山断裂带的假玄武玻璃中可能形成了单质铁,其和磁铁矿是假玄武玻璃高磁化率值异常的重要原因,并指示了深部流体作用弱、硫化物含量低、还原性的孕震环境。     

Quartz resources in the Serra de Santa Helena formation,Brazil: A geochemical and technological study

This study presents an evaluation of Brazilian quartz deposits of Corinto and Olhos D'água, in Minas Gerais State, as potential high purity raw material for the production of silica glass. Both deposits are part of the Serra de Santa Helena formation, which holds other quartz deposits. Several quartz samples from these mines were analyzed to evaluate their chemical purity, by determination of the content of trace elements by ICP-MS after acid digestion. The technological characteristics of the ores after flame-fusion into silica glass were evaluated according to their bubble generation and UV transparency. The results indicate that silica glass with chemistry suitable for crucible applications can be obtained from materials of both mines, and even optical grade silica glass can be manufactured using transparent ore from one of the mines. In addition, this work explores the trace elements composition of each mine, as well as their fluid inclusions, and characterizes the mines as being of hydrothermal origin. Small differences in the physical and chemical characteristics of quartz that could affect the technological behavior of the ores are related to the geological history of the mines and provide interesting insights regarding the exploration of other quartz resources within the same geological formation.     

上海市磁悬浮轨道交通线工程岩土工程概况

文章概述了上海市磁县浮轨道交通工程，并对工程沿线的岩土工程特性作了简要的分析评价。     

太古宙克拉通型下地壳剖面：华北怀安－丰镇－尚义的麻粒岩－角闪岩系

华北克拉通北缘晋冀内蒙交界地区有变质程度连续变化、从高压基性麻粒岩、麻粒岩到角闪岩相的变质岩系出露。它们的古变质压力由＞１．４ＧＰａ（５０ｋｍ）变化到０．５ＧＰａ（１５ｋｍ）；岩石类型从变辉长岩、中酸性正片麻岩到表壳岩变化；变质矿物组合由不含水的耐火组合变为富含云母和角闪石的组合；地球化学性质表现出从贫Ｓｉ和Ａｌ、轻度亏损生热元素到具有正常的化学成分的连续变化；包裹体流体性质在轻度亏损生热元素的麻粒岩中均为ＣＯ２流体，而在麻粒岩相的表壳岩和角闪岩系中Ｈ２Ｏ流体逐渐增加。上述变质岩系剖面的组成和特点符合大陆下地壳的定义，可能代表了包括最下部地壳在内的华北地块太古宙克拉通型大陆下地壳。据此本文建立了我国第一条克拉通型大陆下地壳剖面，并讨论其地质意义以及相关的问题     

新疆第四纪盐类矿产的形成和控制因素——兼论“高山深盆”成盐模式

根据袁见齐教授“高山深盆”成盐模式,探讨新疆天山对第四纪盐类矿床的形成和控制作用,阐述了天山地貌、气候、水文特征与盐类矿产的分布规律和特征。认为“高山深盆”并非一定是四周环山的深盆,可以是某一高山与其间深盆或两侧盆地的有机组合。高山的屏障作用造成了垂直的气候分带,在潮湿多雨的山区利于成盐组份的析出并迁移到干旱少雨的闭流深盆中,形成盐类矿床。