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21.
对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。 相似文献
22.
LUO Kai-li LI Bao-sheng ZHU Yi-zhi JIN He-ling ZHANG David Dian YAN Man-cun LI Hou-xin YAO Chun-xia ZHANG Yu-hongf . Department of Geography South China Normal University Guangzhou P. R. China . State Key Labor 《中国地理科学(英文版)》2001,11(4):336-342
About 70years ago,Frenc卜卜alaeohdoglst回LL sc卜dars al卜ome and a卜road卜ave successively con-HARD de Chardin P.et al.Initiated the Quaternary ducted large amount ofwork on the Later Quaternarygeologlcal research In the >alawusu River Basin of strata(TEILHARD,1924; YUAN,1978; LI,1987;desert region of Northern China and established th,ZHENG,1989; SUN et al,1996; LI et al,1993),Salawusu Formation门EILHARD,1924).Sine,then,palaeobiology… 相似文献
23.
A. R. King K. Schenker U. Kolb M. B. Davies 《Monthly notices of the Royal Astronomical Society》2001,321(2):327-332
We show that the usual picture of supersoft X-ray binary evolution as driven by conservative thermal time-scale mass transfer cannot explain the short orbital periods of RX J0537.7–7034 (3.5 h) and 1E 0035.4–7230 (4.1 h). Non-conservative evolution may produce such periods, but requires very significant mass loss, and is highly constrained. 相似文献
24.
1 INTRODUCTIONGlobal change research involves much geo-objectsand geo-process, such as climate and environmentalchange, substance and energy cycling, land-use/land-cover change (LUCC), interactivity between human and nature, etc.. So it need cooperation frommany research communities including international research programs groups such as IGBP (InternationalGeosphere-Biosphere Programme IPCC (Intergovemmental Panel on Climate Change), IHDP (InternationalHuman Dimension Program o… 相似文献
25.
C.J. Mooney W.R.J. Rolleston F.P. Keenan P.L. Dufton D.L. Pollacco H.R. Magee 《Monthly notices of the Royal Astronomical Society》2001,326(3):1101-1109
We present a model-atmosphere analysis for the bright ( V ∼13) star ZNG-1, in the globular cluster M10. From high-resolution ( R ∼40 000) optical spectra we confirm ZNG-1 to be a post-asymptotic giant branch (post-AGB) star. The derived atmospheric parameters are T eff =26 500±1000 K and log g =3.6±0.2 dex . A differential abundance analysis reveals a chemical composition typical of hot post-AGB objects, with ZNG-1 being generally metal poor, although helium is approximately solar. The most interesting feature is the large carbon underabundance of more than 1.3 dex. This carbon deficiency, along with an observed nitrogen enhancement relative to other elements, may suggest that ZNG-1 evolved off the AGB before the third dredge-up occurred. Also, iron depletions observed in other similar stars suggest that gas–dust fractionation in the AGB progenitor could be responsible for the observed composition of these objects. However, we need not invoke either scenario since the chemical composition of ZNG-1 is in good agreement with abundances found for a Population II star of the same metallicity. 相似文献
26.
从香蕉(Musa AAA)组织培养繁殖后代中,选育出特长果指香蕉新品系“93-1”,主要特点为植株表现中矮秆(216 cm),茎粗中等(67.1 cm),苗期叶色浓绿,叶形椭圆形,叶形比(长/宽)1.91,叶尖急尖,叶基凹陷呈耳垂状;果穗7~12梳,平均8.07梳/穗,穗长81.6 cm,单穗重22.8 kg,单果重213.5 g,果指数123.4条/穗,果指特长(25.8 cm);可溶性固形物含量21.8%;全生育期321d(春植)至368 d(夏植),约44片叶。“93-1”适宜在广东雷州半岛及海南岛栽培种植。 相似文献
27.
M. J. Carson J. C. Davies E. Daw R. J. Hollingworth V. A. Kudryavtsev T. B. Lawson P. K. Lightfoot J. E. McMillan B. Morgan S. M. Paling M. Robinson N. J. C. Spooner D. R. Tovey 《Astroparticle Physics》2004,21(6):667-687
Simulations of the neutron background for future large-scale particle dark matter detectors are presented. Neutrons were generated in rock and detector elements via spontaneous fission and (α,n) reactions, and by cosmic-ray muons. The simulation techniques and results are discussed in the context of the expected sensitivity of a generic liquid xenon dark matter detector. Methods of neutron background suppression are investigated. A sensitivity of 10−9–10−10 pb to WIMP-nucleon interactions can be achieved by a tonne-scale detector. 相似文献
28.
Tao Kiang Yong-Feng Wu Xing-Fen Zhu Dunsink Observatory Dublin Institute for Advanced Studies Dublin Ireland Center for Astrophysics University of Science Technology of China Hefei 《中国天文和天体物理学报》2004,4(3):209-220
Rhombic cell analysis as outlined in the first paper of the present seriesis applied to samples of varying depths and liming luminosities of the IRAS/PSCzCatalogue. Numerical indices are introduced to summarize essential information.Because of the discrete nature of the analysis and of the space distribution of galax-ies, the indices for a given sample must be regarded as each having an irreduciblescatter. Despite the scatter, the mean indices show remarkable variations acrossthe samples. The underlying factor for the variations is shown to be the limitingluminosity rather than the sampling depth. As samples of more and more luminousgalaxies are considered over a range of some 2.5 magnitudes (a factor of some 75in space density), the morphology of the filled and empty regions defined by thegalaxies degrades steadily towards insignificance, and the degrading is faster for thefilled than the empty region. 相似文献
29.
Abstract Petrological, oxygen isotope and 40Ar/39Ar studies were used to constrain the Tertiary metamorphic evolution of the lower tectonic unit of the Cyclades on Tinos. Polyphase high-pressure metamorphism reached pressures in excess of 15 kbar, based on measurements of the Si content in potassic white mica. Temperatures of 450–500° C at the thermal peak of high-pressure metamorphism were estimated from critical metamorphic assemblages, the validity of which is confirmed by a quartz–magnetite oxygen isotope temperature of 470° C. Some 40Ar/39Ar spectra of white mica give plateau ages of 44–40 Ma that are considered to represent dynamic recrystallization under peak or slightly post-peak high-pressure metamorphic conditions. Early stages in the prograde high-pressure evolution may be documented by older apparent ages in the high-temperature steps of some spectra. Eclogite to epidote blueschist facies mineralogies were partially or totally replaced by retrograde greenschist facies assemblages during exhumation. Oxygen isotope thermometry of four quartz–magnetite pairs from greenschist samples gives temperatures of 440–470° C which cannot be distinguished from those deduced for the high-pressure event. The exhumation and overprint is documented by decreasing ages of 32–28 Ma in some greenschists and late-stage blueschist rocks, and ages of 30–20 Ma in the lower temperature steps of the Ar release patterns of blueschist micas. Almost flat parts of Ar–Ar release spectra of some greenschist micas gave ages of 23–21 Ma which are assumed to represent incomplete resetting caused by a renewed prograde phase of greenschist metamorphism. Oxygen isotope compositions of blueschist and greenschist facies minerals show no evidence for the infiltration of a δ18O-enriched fluid. Rather, the compositions indicate that fluid to rock ratios were very low, the isotopic compositions being primarily controlled by those of the protolith rocks. We assume that the fundamental control catalysing the transformation of blueschists into greenschists and the associated resetting of their isotopic systems was the selective infiltration of metamorphic fluid. A quartz–magnetite sample from a contact metamorphic skarn, taken near the Miocene monzogranite of Tinos, gave an oxygen isotope temperature of 555° C and calculated water composition of 9.1%. The value of δ18O obtained from this water is consistent with a primary magmatic fluid, but is lower than that of fluids associated with the greenschist overprint, which indicates that the latter event cannot be directly related to the monozogranite intrusion. 相似文献
30.
We briefly describe an advanced 3D gas dynamical model developed for the simulation of theenvironment of active cometary nuclei.
The model canhandle realistic nucleus shapes and alternative physical models for the gas and dust production mechanism.The
inner gas coma structure is computed by solving self-consistently(a) near to the surface the Boltzman Equation(b) outside
of it, Euler or Navier-Stokes equations.The dust distribution is computed from multifluid ``zero-temperature' Euler equations,extrapolated
with the help of a Keplerian fountain model.The evolution of the coma during the nucleus orbital and spin motion,is computed
as a succession of quasi-steady solutions. Earlier versions of the model using simple,``paedagogic' nuclei have demonstrated
that the surface orographyand the surface inhomogeneity contribute similarly to structuring the near-nucleusgas and dust coma,casting
a shadow on the automatic attribution of such structures to ``active areas'.The model was recently applied to comet P/Halley,
for whichthe nucleus shape is available. In the companion paper of this volume,we show that most near-nucleus dust structuresobserved
during the 1986 Halley flybys are reproduced, assuming that the nucleus is strictly homogeneous. Here, we investigate the
effect of shape perturbations and homogeneityperturbations. We show that the near nucleus gas coma structure is robust vis-a-vissuch
effects. In particular, a random distribution of active and inactive areaswould not affect considerably this structure, suggesting that such areas,even if present, could not be easily identified on images
of the coma. 相似文献