Scientific objectives and payloads of Chang’E-1 lunar satellite

China plans to implement its first lunar exploration mission Chang’E-1 by 2007. The mission objectives are

Effects of T-shape groin parameters on beach accretion

The effects of various groin parameters (length, head length and opening) and wave parameters (wave height, wave period and wave angle) on the accretion of the area protected by T-shape groins are studied in a physical model. The model studies are performed using regular waves in a basin. A numerical model which depends primarily on a CERC model is employed to examine the effects of some of the above parameters. Good agreement is found in the results of physical and numerical models. The results of a numerical model are compared with field data obtained by deep sounding measurements at Of coasts, Trabzon Province, Turkey. The finding from this study may be employed in designing T-shape groins.     

Chemical and Biological Studies of Particulate Organic Matter in the Ocean

This paper presents a review of the past decade's highlights of research on the isolation and characterisation of particulate organic matter (POM) in the world's oceans. The emphasis is on chemical studies but, in keeping with the growing interdisciplinary nature of marine science, advances in other disciplines are also discussed, particularly those in biological sciences. Increasing evidence for the importance of picoplankton, bacteria and viruses as POM constituents is highlighted, including the recent recognition of large populations of autotrophic bacteria able to harvest light for energy. The transport of POM to bottom waters was thought to be largely confined to large, rapidly sinking faecal pellets. However, recent studies have highlighted the importance of organic aggregates and flocs formed by diatoms such as Rhizosolenia and other microalgae. Ascending particles have also been discovered, many of which are lipid-rich. Several studies have shown that resuspension of bottom sediments and lateral advection of material from continental shelves can lead to anomalously high particle fluxes measured in sediment traps moored in deep water. Many new approaches for characterizing POM have emerged, such as pyrolysis gas chromatography-mass spectrometry and direct temperature-resolved mass spectrometry for analysis of higher molecular weight materials and biopolymers. Lipid biomarker techniques have also advanced, exciting new possibilities being raised by the ability to measure stable and radioactive carbon isotopes for individual compounds. The techniques of molecular biology, such as the polymerase chain reaction (PCR), are being increasingly applied to provide complementary information to more conventional microscopy and flow cytometry on the identity of organisms in the sea. The combination of these techniques with advanced chemical analysis methods promises to greatly increase our knowledge of the origins, transport and fate of organic matter in the oceans. This revised version was published online in August 2006 with corrections to the Cover Date.     

Spatio-temporal and interspecific variation in otolith trace-elemental fingerprints in a temperate estuarine fish assemblage

We tested whether estuarine fishes have site-specific differences in the concentrations of trace elements in their otoliths that can be used as ‘fingerprints’ to identify them to their estuary of origin. To evaluate the robustness of this approach, we tested whether elemental fingerprints were consistent among individuals of five species that were collected in 1996 from three temperate estuaries in southern California. We also tested whether elemental fingerprints were consistent between spring and autumn 1996 for three species in one of the sites, Carpinteria Marsh. The species evaluated comprised a mid-water-dwelling smelt (Atherinops affinis), two benthic gobies (Clevelandia ios and Ilypnus gilberti), and two flatfish (Paralichthys californicus and Hypsopsetta guttulata). The concentrations of six elements (Mn, Cu, Zn, Sr, Ba, and Pb) were determined in the otoliths using inductively coupled plasma-mass spectrometry (ICP-MS). Within estuaries, the five species exhibited strong variation in elemental concentration, indicating substantial interspecific differences in otolith environmental history. When the five fish species were considered separately, multivariate (MANOVA) and univariate (ANOVA) analyses of variance indicated that the elemental composition of otoliths differed significantly among the estuaries in four of the five species. Based on linear discriminant function analyses (DFA), differences were strong enough that trace element composition could be used to accurately assign fish to their site of origin [mean (range): 93.5% (74–100%)]. However, elemental signatures within Carpinteria Marsh were not consistent between spring and autumn 1996, and this was reflected in a substantial reduction in the accuracy of assigning fish to their true site of origin. When we compared site differences between fish species (site×species interactions), the elemental fingerprints were most similar between closely related species (e.g. the two gobies and the two flatfish) and most dissimilar between distantly related species, both phylogenetically and ecologically. Among the six elements analyzed, Sr and Ba exhibited the most inconsistent pattern among species, with significant differences in 80 and 70% of the pairwise species comparisons, respectively. The remaining four elements showed ≥70% consistency in the pattern of variation among sites for the different species. Thus, while otolith elemental fingerprinting can be a useful tool for inferring estuarine residency, such fingerprints may be temporally variable and species specific.     

Marine proteomics: generation of sequence tags for dissolved proteins in seawater using tandem mass spectrometry

Dissolved proteins in seawater samples from the Gulf of Mexico were concentrated using tangential flow ultrafiltration and methanol/chloroform/water precipitation. Following concentration and purification, two different separation methods were employed. In one method, intact proteins were separated by SDS–PAGE and digested enzymatically in-gel. In the second method, the peptides resulting from a solution proteolytic digest of the whole protein pellet mixture were separated by capillary HPLC. In both methods, the final chromatographic separation was coupled on-line with a mass spectrometer using an electrospray interface, and peptide CID spectra were collected using tandem mass spectrometry (MS). De novo sequencing of the peptide tandem mass spectra generated short amino acid sequences (peptide tags) that were used to search databases for protein class and source information. Trends of conserved sequences for two specific classes of proteins were observed: membrane/envelope proteins and enzymes. Similarity searching of peptide tags produced identification of conserved sequences from several protein homologues originating from many different species, including: long chain fatty acyl CoA synthetase, anthranilate synthase, ribulose bisphosphate carboxylase, and luminal binding protein. These results provide new insight into the sources and production mechanisms for dissolved organic matter (DOM), as there is direct evidence for dissolved proteins other than the bacterial outer membrane proteins reported by Tanoue et al. Furthermore, the data presented herein support the idea that physical protection and selective preservation are not mutually exclusive survival mechanisms, but rather these two models are dependent upon one another for explaining the survival of refractory dissolved proteins in seawater.     

Benthic fluxes of nitrogen in the tidal reaches of a turbid, high-nitrate sub-tropical river

Benthic fluxes of dissolved inorganic nitrogen (NO₃⁻ and NH₄⁺), dissolved organic nitrogen (DON), N₂ (denitrification), O₂ and TCO₂ were measured in the tidal reaches of the Bremer River, south east Queensland, Australia. Measurements were made at three sites during summer and winter. Fluxes of NO₃⁻ were generally directed into the sediments at rates of up to −225 μmol N m⁻² h⁻¹. NH₄⁺ was mostly taken up by the sediments at rates of up to −52 μmol N m⁻² h⁻¹, its ultimate fate probably being denitrification. DON fluxes were not significant during winter. During summer, fluxes of DON were observed both into (−105 μmol m⁻² h⁻¹) and out of (39 μmol m⁻² h⁻¹) the sediments. Average N₂ fluxes at all sampling sites were similar during summer (162 μmol N m⁻² h⁻¹) and winter (153 μmol N m⁻² h⁻¹). Denitrification was fed both by nitrification within the sediment and NO₃⁻ from the water column. Sediment respiration rates played an important role in the dynamics of nitrification and denitrification. NO₃⁻ fluxes were significantly related to TCO₂ fluxes (p<0.01), with a release of NO₃⁻ from the sediment only occurring at respiration rates below 1000 μmol C m⁻² h⁻¹. Rates of denitrification increased with respiration up to TCO₂ fluxes of 1000 μmol C m⁻² h⁻¹. At sediment respiration rates above 1000 μmol C m⁻² h⁻¹, denitrification rates increased less rapidly with respiration in winter and declined during summer. On a monthly basis denitrification removed about 9% of the total nitrogen and 16% of NO₃⁻ entering the Bremer River system from known point sources. This is a similar magnitude to that estimated in other tidal river systems and estuaries receiving similar nitrogen loads. During flood events the amount of NO₃⁻ denitrified dropped to about 6% of the total river NO₃⁻ load.     

The space-time structure of oil and gas field growth in a complex depositional system

Shortly after the discovery of an oil and gas field, an initial estimate is usually made of the ultimate recovery of the field. With the passage of time, this initial estimate is almost always revised upward. The phenomenon of the growth of the expected ultimate recovery of a field, which is known as field growth, is important to resource assessment analysts for several reasons. First, field growth is the source of a large part of future additions to the inventory of proved reserves of crude oil and natural gas in most petroliferous areas of the world. Second, field growth introduces a large negative bias in the forecast of the future rates of discovery of oil and gas fields made by discovery process models. In this study, the growth in estimated ultimate recovery of oil and gas in fields made up of sandstone reservoirs formed in a complex depositional environment (Frio strand plain exploration play) is examined. The results presented here show how the growth of oil and gas fields is tied directly to the architectural element of the shoreline processes and tectonics that caused the deposition of the individual sand bodies hosting the producible hydrocarbon.     

Sequential indicator conditional simulation and indicator kriging applied to discrimination of dolomitization in GER 63-channel imaging spectrometer data

Laboratory reflectance spectra of synthetic mixtures of the carbonate minerals calcite and dolomite were measured in the visible and near-infrared wavelength region (0.4–2.5 m) using a high-spectral resolution laboratory spectrometer. The instrument measured reflectivity with an accuracy of 0.001 m, allowing detailed resolution of the carbonate spectrum. The spectra of calcite and dolomite could be characterized by the presence of a strong absorption band centered at 2.3465 m for pure calcite and at 2.3039 m for pure dolomite. Nine mixtures of intermediate composition were analyzed demonstrating that the position of the carbonate absorption band is semilinearly related to the calcite content of the sample. Theoretically, this model allows mapping of dolomitization from high-spectral resolution remotely sensed imagery, GER 63-channel imaging spectrometer data from southern Spain were used to attempt such a mapping. First, pixels of vegetation were removed. For the remaining pixels, the wavelength center of the carbonate absorption band was detected and converted to a category of calcite fraction. The percentage of calcite for the remaining pixels was estimated using direct indicator kriging (IK) and sequential conditional indicator simulation, assuming that the calcite content could be represented as a category variable (SCIS category variable) and as a continuous variable (SCIS continuous variable). Four realizations of an SCIS (category variable) showed that on the average, 60 percent of the data was simulated in the same class and over 90 percent of the data within one class difference. A comparison with field samples showed that IK estimates of calcite content were within 20 percent accurate. The SCIS (continuous variable) does not perform as well with differences between –45% and +26% calcite; however, simulation reproduces the spatial variability better.     

Field measurements of wave overtopping at the rubble mound breakwater of Rome–Ostia yacht harbour

This paper describes a new station for full-scale measurement of wave overtopping at the Rome yacht harbour rubble mound breakwater in Ostia (Italy) and the results of the successful first measurement campaign carried out during the winter season 2003–2004. The equipment and the research activities were supported by the EU project CLASH, focusing on scale effects for wave overtopping at coastal structures. The site is characterized by a very small tidal range, a long shallow foreshore and depth-limited breaking waves which interact with a shallow sloping porous rock structure. Overtopping water is collected by a steel tank installed on the crown slab behind the parapet wall. The measurement of water level variation inside the tank by means of two pressure transducers allows the calculation of individual overtopping volumes. Incident waves, sea levels and wind are also measured. During seven independent storms, more than 400 individual overtopping events were recorded and about 86 h of valid data are available. This extensive dataset is presented, discussed and then used for comparison with two commonly used overtopping prediction formulae based on small-scale model tests showing their tendency to underestimate the prototype results. A strong correlation between the hourly mean overtopping discharge and corresponding maximum volume is also presented. The paper generally confirms the validity of the approach used in Troch et al. (2004) [Troch, P., Geeraets, J., Van de Walle, B., De Rouck, J., Van Damme, L., Allsop, W., Franco, L., 2004. Full-scale wave overtopping measurements on the Zeebrugge rubble mound breakwater. Coastal Engineering 51, 609–628] for field measurement of wave overtopping.     

电感耦合等离子体发射光谱法测定石膏矿样品中的三氧化硫

样品用稀盐酸处理,在酸性条件下石膏样品中的三氧化硫以硫酸根状态存在于待测溶液中,过滤除去酸不溶物。处理好的待测溶液可直接上等离子体发射光谱仪ICAP-6300(美国热电制造)上测定。方法的检出限为0.01%,采用本法测定国家标准物质GBW03109,GBW03109a,GBW03110,GBW03111a,结果表明标准样品测定的相对误差为-0.411%~0.274%,相对误差允许限为1.07%,能够满足分析质量要求。