Trace Elements Analysis of Geological Samples by Laser Ablation Inductively Coupled Plasma Mass Spectrometry

ＩＮＴＲＯＤＵＣＴＩＯＮＬａｓｅｒａｂｌａｔｉｏｎｉｎｄｕｃｔｉｖｅｌｙｃｏｕｐｌｅｄｐｌａｓｍａｍａｓｓｓｐｅｃｔｒｏｍｅ ｔｒｙｉｓａｎｉｎｃｒｅａｓｉｎｇｌｙｄｅｖｅｌｏｐｅｄａｎａｌｙｔｉｃａｌｔｅｃｈｎｉｑｕｅｆｏｒｓｏｌｉｄｓａｍｐｌｅａｎａｌｙｓｉｓ.ＬＡ ＩＣＰ ＭＳｏｆｆｅｒｓａｔｔｒａｃｔｉｖｅｃｈａｒａｃｔｅｒｉｓｔｉｃｓｏｆｈｉｇｈｓｅｎｓｉｔｉｖｉｔｙ ,ｌｏｗｄｅｔｅｃｔｉｏｎｌｉｍｉｔｓ,ｍｉｎｉｍａｌｓａｍｐｌｅｐｒｅｐａｒａ ｔｉｏｎ ,ｌｅｓｓｏｘｉｄｅｓｉｎｔｅｒｆｅ…     

GPS工程控制网的若干特殊问题

根据ＧＰＳ定位技术的优点，讨论了建立ＧＰＳ工程控制网在踏勘、设计、观测及数据处理方面的若干特殊问题，并提出高精度工程控制网ＧＰＳ数据处理方案。     

SPECTRUM期间目标台风移动的数值试验

在目标台风Ｙａｎｃｙ的移动过程中，选择４个时段进行预报数值试验。模式初始场系根据ＳＰＥＣＴＲＵＭ和ＴＣＭ－９０加强观测资料确定。结果表明：实际大气中目标台风移动的若干特征在模式大气中能够显示出来，如Ｙａｎｃｙ在１９９０年８月２０日００时移向的转折现象等；台风非对称结构的低频振荡是产生移向转折现象的一个重要原因。     

用地面伽玛能谱资料估计地层(体)的含铀性和资源量

本文论述用地面伽玛能谱资料估计地层(体)含铀性和资源量方法,并提出富铀富集体、铀源富集体、尤其富铀源富集体是最有利于成矿的结论。     

激光热透镜光谱法测定地质样品中微量钼的研究

作者对激光热透镜光谱法测定微量钼进行了研究．试验表明，在丙酮介质中，Ｍｏ６＋能被还原成Ｍｏ５＋并形成钼蓝同多酸，最大吸收彼长在６７０ｕｍ处，利用Ｈｅ－Ｎｅ激光器输出的６３２．８ｕｍ的激光作光源，进行微量钼的热透镜法分析测定．两酮的存在能增强热透镜信号强度。钼含量在０．０１—２．０μｇ／ｍＬ范围内与激光热透镜信号强度呈良好的线性关系，方法检出限为０．００５μｇ／ｍＬ钼，已用于地质样品中微量钼的高灵敏度测定．结果满意．     

Field compaction control studies on road bases in a new settlement area in Ghana

Summary Among the major causes for failure of roads in the tropics is inadequate compaction during construction. There is, therefore, the need to strictly control the compaction of the pavement layers if the design life of the road is to be attained; thereby eliminating large maintenance costs.This note reports on pavement compaction control studies undertaken on the road bases of service roads in a new settlement area in Ghana. These roads were to be provided with bituminous surfacing immediately after compaction. Studies concerning particle breakdown during field compaction by two contractors executing the works under the same conditions have been made, together with an assessment of contractor efficiency.It was found that the placement moisture contents varied greatly from the optimum. One contractor was compacting the gravels on the dry side of optimum, consequently achieving relatively high densities. The other contractor was compacting on the wet side and achieving lower density levels. This was still the case even after initial test sections were found to have been undercompacted.Compaction levels achieved in the crowns were generally found to be higher than those at the shoulders of the road test sections. The breakdown of coarse particles due to compaction was quite significant. There is therefore the need for highway material engineers to ensure that in addition to meeting the grading requirements, road base materials must adequately meet the requirements on weathering and mechanical strength properties.     

通过对调查数据的趋势和多变量分析确定宏观场

通过多变(相关分析)和趋势分析等统计方法对宏观调查数据进行了解释.这种方法使我们通过评定不同宏观效应叠加的程度、估计调查数据的不确定性更客观地评定烈度.通过滤波确定烈度场的区域分量,使我们消除观测中的局部变化.给出了选取适当滤波参数的准则.本文应用这一方法对发生在意大利的一次地震的调查数据进行了处理.     

兰州—天水地区三维重力反演及其地质解释

本文利用重力资料对兰州—天水地区的深部构造进行了研究。在计算中,采用Parker-Oldenbarg三维位场反演方法,反演前对重力资料进行了地形改正和中新生代沉积层校正。根据反演结果,综合分析了有关资料,认为该区为青藏块体过渡带,并且提出了陇中盆地为断块型构造盆地的新认识。     

X射线荧光光谱分析检出限问题的探讨与建议

对有关X射线荧光光谱分析低含量元素的检出限问题进行了多方面的探讨。从检出限的定义及其定义下的相对标准偏差到各种不同测量、校准与校正方法的检出限及其相对应的相对标准偏差进行计算。提出了以定义检出限的相对标准偏差为基准,对各种测量方法计算出的检出限进行重新界定,从而确认一个具有可比性的、精度一致的检出限。同时还讨论了仪器与X光管固有杂质元素谱线对该元素检出限的影响;测量仪器、测量条件与测量时间对检出限的影响;不同岩性试样对检出限的影响;检出限与测定限等问题。     

Analyses of trace elements on quartz surfaces in sulfidic mine tailings from Kristineberg (Sweden) a few years after remediation

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has been applied to determine the elemental composition of the surface layer, as well as of the first interior layer, of quartz grains from the mine tailings from Kristineberg (northern Sweden) in order to determine concentration gradients between these two layers. The quartz grains were collected from the oxidized and unoxidized zones within the tailings. The aim of this study is to assess the role of quartz surfaces as sites for the attenuation of solutes from the mine-tailings porewater. Concentrations of Cu, Ag, Sb, Pb and Bi are highest near the surface of each grain and decrease towards the interior. The surface concentration of Cu, Zn and Pb is more pronounced within the unoxidized than within the oxidized zone of the tailings. Cu exhibits a distinct concentration peak at the surface of the quartz grains below the pre-remediation oxidation front. For Zn and Ce the trend of high surface concentration is less pronounced than for Cu or Pb. Silver, Bi and As are preferably adsorbed within the uppermost layers of the oxidized zone where the pH is as high as 6.2. The conversion of intensity signals of the elements to concentration values in ppm was done by using external standards (NIST silicate glass).