Kurzzeit-Toxizitätstests zur Messung der Toxizität von Chemikalien gegenüber Belebtschlamm

Short-term Toxicity Tests for the Measurement of Toxicity of Chemicals Towards Activated Sludge. To avoid severe damage to the activated sludge of a wastewater treatment plant it is necessary to control the sludge activity by means of biological test systems. Especially the short-term respiration assay and the dehydrogenase assay with resazurin as a redox-dye seem to be appropriate for this monitoring program. The practical performance of both test systems was optimized in some essential points. With the help of several reference substances both monitoring systems were tested for practical use as short-term toxicity tests. The results of the investigations showed that the inhibitory concentrations measured in both test systems were partially very different. In monitoring experiments with laboratory-scale wastewater treatment plants it could be shown that a positive correlation between respiration activity and dehydrogenase activity is not always given. Furthermore, a pH-dependent toxicity could be demonstrated for several substituted phenols.     

模糊区域拓扑关系模型

拓扑关系是地理信息系统中空间要素之间最基本也是最重要的关系之一，是进行绝大多数空间查询和分析的基础。非模糊空间要素之间的拓扑关系在一般拓扑学等理论的基础上已有相关的模型和描述，并在实践中得到广泛的应用，如何建立模糊空间要素这间的拓扑关系是建立模糊要素地理信息系统的基础。该文在模糊扑扑学的基础上提出了模糊区域的定义，建立了用于分析模糊区域之间拓扑关系的理论和模型，提出了4*4-intersection模型拓扑关系矩阵，并分析了不同拓扑关系矩阵对于非模糊区域之间、模糊区域之间建立拓扑关系的区别和联系，最后采和不同公式对模糊区域之间的关系进行了系统的描述。     

4D seismic time-lapse monitoring of an active cold vent,northern Cascadia margin

Two single-channel seismic (SCS) data sets collected in 2000 and 2005 were used for a four-dimensional (4D) time-lapse analysis of an active cold vent (Bullseye Vent). The data set acquired in 2000 serves as a reference in the applied processing sequence. The 4D processing sequence utilizes time- and phase-matching, gain adjustments and shaping filters to transform the 2005 data set so that it is most comparable to the conditions under which the 2000 data were acquired. The cold vent is characterized by seismic blanking, which is a result of the presence of gas hydrate in the subsurface either within coarser-grained turbidite sands or in fractures, as well as free gas trapped in these fracture systems. The area of blanking was defined using the seismic attributes instantaneous amplitude and similarity. Several areas were identified where blanking was reduced in 2005 relative to 2000. But most of the centre of Bullseye Vent and the area around it were seen to be characterized by intensified blanking in 2005. Tracing these areas of intensified blanking through the three-dimensional (3D) seismic volume defined several apparent new flow pathways that were not seen in the 2000 data, which are interpreted as newly generated fractures/faults for upward fluid migration. Intensified blanking is interpreted as a result of new formation of gas hydrate in the subsurface along new fracture pathways. Areas with reduced blanking may be zones where formerly plugged fractures that had trapped some free gas may have been opened and free gas was liberated.     

准中4区块侏罗系头屯河组滩坝及风暴沉积特征

在准噶尔盆地中部(简称准中)4区块侏罗系岩心观察的基础上,考虑粒度分析、薄片镜下观察及古气候恢复成果,认为该区头屯河组沉积时期发育滨浅湖滩坝沉积;以典型风暴沉积构造的识别为基础,提出一种与滩坝相伴生出现的新的风暴岩类型——滨浅湖风暴岩,并建立理想垂向序列模型,自下至上依次为:递变、块状层段(Sa),平行层段、冲洗交错层段(Sb),波状层段(Sc);断续纹层段(Sd)和滨浅湖泥岩段(Se).该类风暴岩发育在正常浪基面之上的滨浅湖地区,与半深湖风暴岩相比,更易遭受后期波浪改造而难以完整保存;因其发育的平面位置不同,滨浅湖风暴岩序列顶底的沉积物可以是氧化色调的滨浅湖泥坪沉积物或是正常的滨浅湖滩坝沉积物.滨浅湖风暴岩的提出完善了滨浅湖滩坝沉积体系,为研究区古地理、古气候特征的恢复提供线索,为滩坝的成因和沉积环境研究提供思路,对准噶尔盆地隐蔽油气藏的勘探具有一定指导意义.     

新显色剂四-(3-磺基-4-氯苯基)卟啉分光光度法测定微量铜

研究了新显色剂四-(3-磺基-4-氯苯基)卟啉在微酸性介质中,表面活性剂OP与CPC存在下测定微量铜的显色反应。络合物在波长420 nm处有最大吸收峰,摩尔吸光度系数为3.44×105L·mol-1cm-1,用双峰双波长光度法测定摩尔吸光系数为6.72×105L·mol-1·cm-1,铜含量在0.5~4.5μg/25 m L范围内符合比耳定律。方法应用于矿样中微量铜的测定,结果令人满意。     

哀牢山南段长安金矿地质特征及找矿方法研究

长安金矿位于哀牢山成矿带南段,是该成矿带上新近发现的又一大型金矿床。该区为哀牢山地体边缘地壳增生带,主要由深变质岩系组成,区内构造断裂发育,对岩浆活动和成矿作用有显著影响。本文总结了长安金矿的地质特征,并以该区的控矿断裂F6为主要研究目标,以地层岩性电性特征作为约束条件,分别展开了磁法、激电、瞬变电磁和大地电磁等综合物探手段的试验研究。研究结果表明,磁法对于该矿找矿效果不明显,瞬变电磁和大地电磁测深反演的电阻率低阻体,准确界定了控矿断裂F6的位置、倾向、断距以及深部延伸情况,通过激电异常可大致判断矿体的位置。所以在长安金矿区下一步的深部隐伏矿勘查中,结合瞬变电磁、激电、大地电磁等地球物理方法,辅以土壤化探异常进行约束,可以达到快速有效找矿之目的。     

New insights on the origin of troctolites from the breakaway area of the Godzilla Megamullion (Parece Vela back‐arc basin): The role of melt‐mantle interaction on the composition of the lower crust

The troctolites and olivine‐gabbros from the Dive 6 K‐1147 represent the most primitive gabbroic rocks collected at the Godzilla Megamullion, a giant oceanic core complex formed at an extinct spreading segment of the Parece Vela back‐arc basin (Philippine Sea). Previous investigations have shown that these rocks have textural and major elements mineral compositions consistent with a formation through multistage interaction between mantle‐derived melts and a pre‐existing ultramafic matrix. New investigations on trace element mineral compositions basically agree with this hypothesis. Clinopyroxenes and plagioclase have incompatible element signatures similar to that of typical‐MORB. However, the clinopyroxenes show very high Cr contents (similar to those of mantle clinopyroxene) and rim having sharply higher Zr/REE ratios with respect to the core. These features are in contrast with an evolution constrained by fractional crystallization processes, and suggest that the clinopyroxene compositions are controlled by melt‐rock interaction processes. The plagioclase anorthite versus clinopyroxene Mg#[Mg/(Mg + Fe^Tot)] correlation of the Dive 6 K‐1147 rocks shows a trend much steeper than those depicted by other oceanic gabbroic sections. Using a thermodynamic model, we show that this trend is reproducible by fractionation of melts assimilating 1 g of mantle peridotite per 1 °C of cooling. This model predicts the early crystallization of high Mg# clinopyroxene, consistent with our petrological observation. The melt‐peridotite interaction process produces Na‐rich melts causing the crystallization of plagioclase with low anorthite component, typically characterizing the evolved gabbros from Godzilla Megamullion.     

含油气岩系中含铵矿物研究现状与前景

研究表明,在含油气岩系中,当有机质发生热演变而成熟、并逐渐向烃类转变的整个过程中,氮主要以NH+₄的形式释放出来而进入孔隙流体与周围介质 (成岩矿物 )相互作用,最重要的机制是NH+₄可取代粘土矿物 (如伊利石,I/S混层矿物等 )层间的K+而参与成岩作用,形成含铵矿物,这一过程中氮的地球化学性质发生了重要变化,含铵矿物中固定 -NH4的富集状况与有机质成熟度及烃类运移有关。通过研究成岩和油气生成、运移、聚集过程中氮的岩石地球化学行为及其控制因素,可将固定 -NH₄作为有机质成熟度和油气运移路径的一种新的、有意义的示踪剂。     

自然湿地甲烷排放模拟研究——模型的修正与验证

以稻田甲烷排放模型(CH4MOD)框架为基础,基于稻田同自然湿地产甲烷底物、植物生长过程以及土壤氧化还原电位变化过程之间的差异,对模型进行了修改,建立自然湿地甲烷排放模型(CH4MODwetland)。利用三江平原淡水沼泽和若尔盖高原泥炭沼泽的甲烷排放观测数据对模型进行了验证。结果表明:模型可以有效地模拟三江平原沼泽甲烷排放的季节和年际变化特征,但是在若尔盖高原模拟效果欠佳;模拟和观测的甲烷排放季节总量在两地均有良好的一致性,线性相关系数R2为0.96(n=7,显著性水平p0.001);模拟值和实测值之间的均方根误差,平均偏差和模型效率分别为14.1%,-6.7%和0.95。