Improvement in the calculation of anti-Stokes energy transfer and experimental justification based on Er0.01YbxY1 - 0.01 - xVO4 crystal

The improvement on the calculation of anti-Stokes energy transfer rate is studied in the present work. The additional proportion coefficient between Stokes and anti-Stokes light intensities of quantum Raman scattering theory as compared with the classical Raman theory is introduced to successfully describe the anti-Stokes energy transfer. The theoretical formula for the improvement on the calculation of anti-Stokes energy transfer rate is derived for the first time in this study. The correctness of introducing coefficient exp{ΔE / kT} from well-known Raman scatter theory is demonstrated also. Moreover, the experimental lifetime measurement in Er_0.01Yb_xY_{1 - 0.01 - x}VO₄ crystal is performed to justify the validity of our important improvement in the original phonon-assisted energy transfer theory for the first time.     

FY-4A数据在2021年1月6—8日寒潮监测中应用

基于静止气象卫星图像解译理论和位涡理论,应用FY-4A水汽图像、干涉式大气垂直探测仪（GIIRS）产品和欧洲中心第五代大气再分析资料（ERA5）对2021年1月6—8日我国中东部地区寒潮天气进行分析。结果表明：高空冷涡和地面冷高压是影响此次寒潮天气的主要影响系统,冷空气5日08:00从贝加尔湖南部向东、向南加强发展,8日20:00 减弱;对比FY-4A/GIIRS与ERA5 850 hPa 24 h变温数据发现：两种数据反映的对流层低层冷空气东移南下特征和正负变温区域分布特征基本一致,FY-4A/GIIRS 850 hPa 24 h负变温中心和0℃等变温线的位置与ERA5数据接近,FY-4A/GIIRS 850 hPa 24 h变温中心值强度略大于ERA5。水汽图像暗区变暗附近的高层位涡的增加激发高层气旋性环流后侧下沉运动增强,干空气下沉造成了地面高压增强;500 hPa冷涡中心附近绝对涡度增加是引起冷空气增强的原因之一;冷空气急剧增强时段,中低层位涡的加大引起地面冷空气堆积,寒潮增强。FY-4A/GIIRS温度产品反映的冷空气移动特征与位涡理论对冷空气增强原因分析结果一致,说明应用FY-4A/GIIRS温度产品能够有效监测分析寒潮冷空气演变特征。     

台风“摩羯”和“利奇马”经渤海强度变化特征分析

利用FY 4水汽云图、NCEP/FNL资料、自动站资料和ERA Interim海温资料,分析入海增强台风“摩羯”（1814）和入海减弱台风“利奇马”（1909）经过渤海强度变化特征。结论如下：台风“摩羯”中心入海增强过程伴随着中高层冷空气侵入,冷空气深入“摩羯”云系中心,台风强度减弱并逐渐消亡。台风“利奇马”入海前冷空气已经侵入台风中心,台风入海后强度减弱,暖心结构变得不对称,低层有清晰的斜压特征。“摩羯”入海前渤海上空为强辐散区,“利奇马”入海前渤海上空为弱辐合场,北上前进方向出现高空辐散有利于台风加强。台风登陆前垂直风切变与台风强度反位相分布,北上后台风垂直风切变与台风强度同位相分布。“摩羯”入海后水汽通道出现断裂,其入海增强更多依赖于热力条件和动力条件。“利奇马”水汽通量和水汽通量散度源于自身环流的贡献。台风“摩羯”入海后潜热加热率激增,“利奇马”低层维持弱潜热加热直至台风消亡。     

甘肃北山地区南金山金矿床隐爆角砾岩体的发现及成矿规律研究

地质研究发现,南金山金矿区出露的下石炭统白山组上岩组的部分岩石为隐爆角砾岩,其中厚层-块状变花岗质砂砾岩为隐爆岩浆角砾岩,厚层-块状变凝灰质砂砾岩为隐爆凝灰角砾岩。隐爆角砾岩体呈近EW向带状分布,隐爆岩浆角砾岩分布于岩体中部,构成岩体的内带,隐爆凝灰角砾岩对称分布于岩体南北两侧,构成岩体的外带。经矿床地质研究,提出了新的认识,认为该矿床的形成受隐爆角砾岩体及隐爆断裂构造的控制,金矿体分布于隐爆角砾岩体外带的隐爆凝灰角砾岩及隐爆断裂中;提出了隐爆角砾岩体外带成矿、对称成矿和双层成矿等3条矿体分布规律。采用EH-4连续电导率成像仪进行了深部地球物理测量,测量结果验证了隐爆角砾岩体控矿及其成矿规律。     

La3+ 离子掺杂钨酸铅单晶的微结构缺陷

钨酸铅晶体是一种非化学计量化合物,缺陷丰富,蕴含着利用掺杂产生新效应和开发新功能的广泛可能性。探讨了不同浓度La3 掺杂对于钨酸铅晶体发光性能的影响,如热释光、X射线激发发光、光致发光等。La3 掺杂有效地抑制了陷阱中心,使发光受到强烈的抑制,在高浓度掺杂的钨酸铅中,激发机制有所改变,通过XPS测试的结果分析了不同浓度La3 掺杂机制。低浓度掺杂中,La3 取代Pb2 ,形成缺陷复合体[2(La3Pb ).-(VPb)″];高浓度掺杂晶体中,La3 离子不但占据Pb2 位置,而且也会占据W6 位置(La3W ),产生La3 的自补偿机制,形成La3 的自补偿对[(La3W )-(La3Pb ).]-(VO)..或缺陷聚集体[3(LaP3b ).-(La3W )]。     

含部分晶须的钛酸锂的制备及其性能表征

L i4T i5O12是一种循环性能好、有很好的充放电平台、理论比容量较大、不与电解液反应的新型负极材料,研究探索以偏钛酸和碳酸锂为主要原料制备含部分晶须的尖晶石型晶型L i4T i5O12的一种方法。通过此工艺在1 000℃煅烧8 h后在样品中约20%的晶须出现,晶须的直径≤0.5μm,晶须的长度约为7μm。     

铵(氮)在岩石和矿物中地球化学行为研究进展

地壳中的氮大都以NH4 储存在矿物中.由于成岩时含氮有机物质的分解作用,氮广泛分布在沉积岩和低级变质岩中;在岩浆岩和变质岩中,氮主要以NH4 存在于含钾硅酸盐(长石和云母类)中;岩浆岩的δ(15N)值和氮浓度明显地不同于沉积物和变沉积岩,主要是由于有机物的缺乏.具有明显铵含量的火成岩主要是含钾矿物的深成岩.因而NH4 可以作为一个"示踪元素"而用于成矿作用等方面的研究.文章还提出了未来的研究方向.     

The REM Adjoint System and Its 4DVar Data Assimilation Experiments

The Regional Eta-coordinate Model(REM) has performed well in forecasting heavy rainfalls in China in recent years.A four-dimensional variational assimilation system(4DVar) is developed to improve the forecast skill of the REM.The tangent linear model and adjoint model codes are written according to thecode to coderule,and the establishment of the REM adjoint modeling system is introduced in detail in this paper.The tangent linear and adjoint models of the REM are validated against the observational data,...     

Analysis of the Decadal and Interdecadal Variations of the East Asian Winter Monsoon as Simulated by 20 Coupled Models in IPCC AR4

Using the output data of 20 coupled climate models used in IPCC AR4 and observational data from NCEP, the capability of the models to simulate the boreal winter climatology of the East Asian sea level pressure, 850-hPa wind, and surface air temperature; the decadal variations of the East Asian winter mon- soon (EAWM) intensity and EAWM-related circulation, and the interdecadal variations of EAWM-related circulation are systematically evaluated. The results indicate that 16 models can weakly simulate the declin- ing trend of the EAWM in the 1980s. More than half of the models produce relatively reasonable decadal variations of the EAWM-related circulation and the interdecadal di?erences of EAWM-related circulation between the boreal winters of 1960-1985 and 1986-1998, including the weakened Siberian high, Aleutian low, and East Asian trough, the enhanced Arctic oscillation and North Pacific oscillation, and a deepened polar vortex. It is found that the performance of the multi-selected-model ensemble in reproducing the spatial dis- tribution of the variations is encouraging, although the variational amplitudes are generally smaller than the observations. In addition, it is found that BCCR_BCM2.0, CGCM3.1_T63, CNRM_CM3, CSIRO_MK3.0, GISS-ER, INM_CM3.0, and MRI_CGCM2.3.2 perform well in every aspect     

Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana

The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the ⁸⁷Sr/⁸⁶Sr, δ¹³C_DIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.