Evolution of cool skin and direct air-sea gas transfer coefficient during daytime

Absorption of solar radiation within the thermal molecular sublayer of the ocean can modify the temperature difference across the cool skin as well as the air-sea gas transfer. Our model of renewal type is based on the assumption that the thermal and diffusive molecular sublayers below the ocean surface undergo cyclic growth and destruction, the heat and gas transfer between the successive burst events are performed by molecular diffusion. The model has been upgraded to include heating due to solar radiation. The renewal time is parameterized as a function of the surface Richardson number and the Keulegan number. A Rayleigh number criterion characterizes the convective instability of the cool skin under solar heating. Under low wind speed conditions, the solar heating can damp the convective instability, strongly increasing the renewal time and correspondingly decreasing the interfacial gas exchange. In the ocean, an additional convective instability caused by salinity flux due to evaporation becomes of importance in such cases. The new parameterization is compared with the cool skin data obtained in the western equatorial Pacific during the Tropical Ocean Global Atmosphere Coupled Ocean Atmosphere Response Experiment in February 1993. In combination with a model of the diurnal thermocline it describes main features of the field data both in nighttime and daytime. Under low wind speed conditions (< 5 m s^-1) diurnal variations of the sea surface temperature due to the formation of a diurnal thermocline were substantially larger than those across the cool skin. Under wind speeds > 5 m s^-1, diurnal variations of the surface temperature due to the variations of the thermal molecular sublayer become more important.     

Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.     

Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.     

紫外线模式预报方法的研究和试验

文章介绍了在T106全球谱模式中应用大气辐射传输模式预报紫外线辐射(UVR)的方法,给出了试验运行的结果.UVR强度的划分考虑了到达地表的UVR通量.参考国内、外紫外线(UV)预报服务的经验,制定了5个日光暴露的级别、相应的紫外线指数(UVI)及防护措施.1999年9月起,国家气象中心已在NOTES网上每月不定期地展示UVR预报的一些结果,2000年9月起,在Cray-C92业务操作系统上实施了连续的试验运行.     

Probability Density Functions as Botanical-Climatological Transfer Functions for Climate Reconstruction

We present a new procedure, the pdf method (pdf=probability density function), for reconstructing Quaternary climate utilizing botanical data. The procedure includes the advantages of the indicator species method by considering the fossil and modern presence and absence of taxa rather than their frequencies, thus avoiding the need for modern analog plant communities. Overcoming the problematic use of absolute limits to describe climate response ranges is the main progress of the pdf method in comparison to the indicator species method. This advantage results from estimating probability density functions (pdfs) for monthly mean January and July temperature conditional on the present day occurrence of single taxa. Gaussian distributions sufficiently approximate pdfs of many, although not all, studied taxa. On the assumption of statistical independence, the procedure calculates a joint pdf as the product of the pdfs of the individual taxa. This algorithm weights each taxon according to the extent of its climate response range expressed by its covariance structure. We interpret the maximum of the resulting pdf as the most likely climate and its confidence interval as the uncertainty range. To avoid an artificial reduction of uncertainty arising from the use of numerous similar pdfs, a preselection method is proposed based on the Mahalanobis distance between pdfs. The pdf method was applied to the Carpinus phase of a profile from Gröbern, Germany, that spans the last interglaciation (Eemian). The reconstructed most probable January and July temperatures of about 0.0°C and 18.4°C barely differ from the modern values of −0.5°C and 18.3°C.     

南向行星际磁场事件与磁暴关系的研究

利用172-182年IMP-8飞船的太阳风观测资料和相应地磁活动性指数Dst和AE,研究了43个南向行星际磁场事件期间太阳风和磁层的耦合问题. 与这43个事件对应的地磁暴是中等的和强的磁暴(Dst＜-50nT). 结果表明:(1) 在43个事件中有11个(约占25.6髎)紧随激波之后,18个处于激波下游流场中(占42髎),其余14个(占33髎)和激波没有关连. 绝大多数事件都伴有太阳风动压和总磁场强度的增加;(2) 当行星际晨昏向电场强度EI＞-4mV/m时,只引起磁亚暴,对Dst指数没有明显影响. 仅当EI＜-5mV/m时,磁亚暴和磁暴才会同时出现;(3) 太阳风动压的增加会增强能量向环电流的输入,但不是密度和速度单独起作用,而是以PK=ρV2的组合形式影响能量的输入;(4) 虽然行星际磁场(IMF)南向分量BZ对太阳风和磁层的耦合起着关键作用,但IMF的BX和BY分量相对于BZ的大小对太阳风向磁层的能量传输也有一定影响. 当BX、BY相对BZ较大时能量耦合加强.     

Screening model for volatile pollutants in dual porosity soils

This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills.     

降水云中液水含量的空基遥感

在建立不同降水云垂直结构模式的基础上，利用矢量微波辐射传扬模式进行空基云雨遥感的数值试验。结果表明：星载微波辐射计6．9GHz通道对降水云的冰层很不敏感，而对降水云校总液水含量(LWC)非常敏感；辐射亮温(Tb)随LWC呈单调变化关系；进一步考查这个频率下b的两个极化分量差△Tb(＝Tbv—Tbh)和LWC的关系发现，不同云结构(对流云和层状云)对△Tb-LWC关系影响较小。研究分析表明，6．9GHz的v,h两个通道有可能用于遥感降水云的液水总量。     

地图投影的最小二乘二元多项式拟合的误差估计

探讨了在地图投影的最小二乘二元多项式拟合中参考点的分布对拟合误差的影响,提出了一种基于矩阵的秩亏的方法来判断参考点是否在指定次数的二元多项式空间的代数曲线上,并导出在极小范数最小二乘意义下的拟合多项式的误差估计式,公式表明拟合误差和参考点的最小二乘误差无关。     

基于新型机载多角度传感器AMTIS的LAI反演

以实地测量数据为先验知识,利用AMTIS数据对顺义地区的一块小麦地进行了叶面积指数(LAI)反演实验研究,并用实地LAI数据进行了验证。通过利用实测数据作为模型参数,以及对干湿土壤分类和匹配表的调整,使反演结果和反演速度得到了提高。