A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.     

蚌埠市地理信息系统应用探讨

阐述了GIS系统的设计原则,建设方案,揭示了GIS系统功能模块的效能,利用Map控件建立信息管理系统,最后探讨了GIS系统在应用领域的发展前景。     

数字化测图中指向箭头的设计

提出在数字化测图的外业编码数据采集过程中,对于未能连线的方向给与一个指向箭头,以便于在内业的地形图编辑中,根据指向箭头进行连线,提高连线率,减小外业作图工作量,提高工作效率。     

GPS-RTK联合全站仪的野外数据采集

对于地形测绘和其它环境条件复杂的地区,用常规方法进行数据采集比较困难,传统的测绘方法越来越不能满足测量效率和成本的要求,但采用GPS RTK与全站仪联合作业,使RTK与全站仪优势互补,在保证测量精度的前提下,可大幅度提高测量速度和效率。     

GPS CORS系统中NTRIP传输技术的应用研究

NTRIP是一种播发实时差分定位改正信息的IP协议。本文讨论了NTRIP的组成、工作原理,并给出一个应用实例。     

The Tau Model for Data Redundancy and Information Combination in Earth Sciences: Theory and Application

Many decision-making processes in the Earth sciences require the combination of multiple data originating from diverse sources. These data are often indirect and uncertain, and their combination would call for a probabilistic approach. These data are also partially redundant with each other or with all others taken jointly. This overlap in information arises due to a variety of reasons—because the data arises from the same geology, because they originate from the same location or the same measurement device, etc. The proposed tau model combines partially redundant data, each taking the form of a prior probability for the event being assessed to occur given that single datum. The parameters of that tau model measure the additional contribution brought by any single datum over that of all previously considered data; they are data sequence-dependent and also data value-dependent. Data redundancy depends on the sequence in which the data is considered and also on the data values themselves. However, for a given sequence, averaging the tau model parameters over all possible data values leads to exact analytical expressions and corresponding approximations and inference avenues. Information on multiple-point connectivity of permeability arrives from core data, well-test data and seismic data which are defined over varying supports with complex redundancy between these information sources. In order to compute these tau weights for determining connectivity, one needs a model of data redundancy, here expressed as a vectorial training image (Ti) constructed using a prior conceptual knowledge of geology and the physics of data measurement. From such a vectorial Ti, the tau weights can be computed exactly. Neglecting data redundancy leads to an over-compounding of individual data information and the possible risk of making extreme decisions.     

Developing a SPASE Query Language

The advent of the Virtual Observatory has begun an evolution in the space physics data environment. A number of nascent and discipline specific Virtual Observatories have started to emerge with an emphasis on data search and retrieval. As this new data environment takes shape an emphasis will be placed on interdisciplinary communication in attempts to address large scale and global problems. To this end we formulate the development of a query language to facilitate Virtual Observatory to Virtual Observatory communication. Furthermore, we outline the goals of such a language, how it would work and how existing community efforts can be leveraged to speed the development of this query language.

Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.     

A way to synchronize models with seismic faults for earthquake forecasting: Insights from a simple stochastic model

Numerical models are starting to be used for determining the future behaviour of seismic faults and fault networks. Their final goal would be to forecast future large earthquakes. In order to use them for this task, it is necessary to synchronize each model with the current status of the actual fault or fault network it simulates (just as, for example, meteorologists synchronize their models with the atmosphere by incorporating current atmospheric data in them). However, lithospheric dynamics is largely unobservable: important parameters cannot (or can rarely) be measured in Nature. Earthquakes, though, provide indirect but measurable clues of the stress and strain status in the lithosphere, which should be helpful for the synchronization of the models.The rupture area is one of the measurable parameters of earthquakes. Here we explore how it can be used to at least synchronize fault models between themselves and forecast synthetic earthquakes. Our purpose here is to forecast synthetic earthquakes in a simple but stochastic (random) fault model. By imposing the rupture area of the synthetic earthquakes of this model on other models, the latter become partially synchronized with the first one. We use these partially synchronized models to successfully forecast most of the largest earthquakes generated by the first model. This forecasting strategy outperforms others that only take into account the earthquake series. Our results suggest that probably a good way to synchronize more detailed models with real faults is to force them to reproduce the sequence of previous earthquake ruptures on the faults. This hypothesis could be tested in the future with more detailed models and actual seismic data.     

Nature minéralogique et rôle nutritionnel des argiles de sols céréaliers en région subhumide à semi-aride (Tunisie)

The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca⁺⁺, Mg⁺⁺ and K⁺ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006).