Assessment of Heavy Metal Contamination of Wetland Soils from a Typical Aquatic–Terrestrial Ecotone in Haihe River Basin,North China

Surface soils were collected in the aquatic–terrestrial ecotone (ATE) of Yongnianwa wetland, downstream of Haihe River basin of North China in June of 2007. Samples were subjected to a total digestion technique before they were analyzed for total concentrations of Cr, Cu, Ni, Pb, and Zn to investigate their pollution levels in the ATE. The contamination index, integrated contamination index, geoaccumulation index, toxic units, and sum of toxic units were adopted to assess the heavy metal contamination levels and ecotoxicity, respectively. The results showed all the selected element concentrations in upland soils of the ecotone were relatively higher than those in the lowland soils. No Cr pollution was observed in all soil samples, but almost all samples were slightly polluted by Cu, Ni, Pb, and Zn except for Site 1. The contamination indexes and geoaccumulation indexes consistently presented no contamination for Site 1 and slight contamination for other sites. The ΣTUs increased from lowland to upland, but the whole level of toxicity in this ecotone was relatively low.     

Assimilation of carbonate country rock by the parent magma of the Panzhihua Fe-Ti-V deposit（SW China）：Evidence from stable isotopes

The Panzhihua intrusion in southwest China is part of the Emeishan Large Igneous Province and host of a large Fe-Ti-V ore deposit.During emplacement of the main intrusion,multiple generations of mafic dykes invaded carbonate wall rocks,producing a large contact aureole.We measured the oxygen-isotope composition of the intrusions,their constituent minerals,and samples of the country rock.Magnetite and plagioclase from Panzhihua intrusion haveδ¹⁸O values that are consistent with magmatic equilibrium, and formed from magmas withδ¹⁸O values that were 1-2‰higher than expected in a mantle-derived magma.The unmetamorphosed country rock has highδ¹⁸O values,ranging from 13.2‰（sandstone） to 24.6-28.6‰（dolomite）.The skarns and marbles from the aureole have lowerδ¹⁸O andδ¹³C values than their protolith suggesting interaction with fluids that were in exchange equilibrium with the adjacent mafic magmas and especially the numerous mafic dykes that intruded the aureole.This would explain the alteration ofδ¹⁸O of the dykes which have significantly higher values than expected for a mantle-derived magma.Depending on the exactδ¹⁸O values assumed for the magma and contaminant, the amount of assimilation required to produce the elevatedδ¹⁸O value of the Panzhihua intrusion was between 8 and 13.7 wt.%,assuming simple mixing.The exact mechanism of contamination is unclear but may involve a combination of assimilation of bulk country rock,mixing with a melt of the country rock and exchange with CO₂-rich fluid derived from decarbonation of the marls and dolomites.These mechanisms,particularly the latter,were probably involved in the formation of the Fe-Ti-V ores.     

云凝结核浓度对不同弗罗德数下形成的地形云和降水的影响

云凝结核(CCN)对云和降水的影响除与其物理化学性质密切相关外,还受到气象条件的影响,但此类研究较少。文中基于WRF中尺度数值模式,引入了表征大气层流速、层结稳定度和地形关系的湿弗罗德(Fw)数,研究揭示了CCN浓度的变化对不同Fw下形成的地形云和降水的影响。研究表明,当Fw≤1,接近临界流时,地形阻挡起主要作用,地形抬升和重力波作用主要发生在迎风坡一侧,主要形成层状云和向上游传播的浅对流波状云,降水主要发生在靠近山顶的迎风坡一侧。在此种情况下,CCN浓度升高对地形云和降水影响较小,当CCN浓度由100 cm~(-3)增至1000 cm~(-3)时,云滴含水量增大,但雨水含量减小,说明云粒子向降水粒子的转化效率降低,CCN浓度升高抑制了暖雨过程。但在云发展后期,云滴被上升气流带至高层形成过冷云滴,与雪粒子发生碰并形成霰粒子,使冰相物理过程有所增强。CCN浓度升高可导致20 h累积降水量减少10—15 mm,约减小7%—8%;当Fw1时,CCN浓度升高会导致20 h地形云累积降水量减小超过50%,最大达到96%,导致地形云几乎不产生降水,而且降水量峰值位置向山顶后移动5—10 km。研究表明,降水显著减小的原因不仅与CCN浓度升高有关,过山气流产生的背风坡焚风效应也起了非常重要的作用。由于CCN浓度升高形成了大量云滴粒子,使雨滴形成效率显著降低,不能形成降雨的大量云滴被强过山气流快速带至下游背风坡区,由于背风坡下坡气流的绝热加热形成的焚风效应很显著,导致云滴和雨滴快速蒸发,使降水显著减小。这一结果可以解释在落基山脉、以色列及中国华山发现的地形降水减小30%—50%的现象,说明气象环境条件在气溶胶影响降水中起重要作用,污染气溶胶与背风坡焚风效应产生的叠加效应可造成地形云降水显著减小。     

“碧利斯”(0604)暴雨过程不同类型降水云微物理特征分析

本文利用"碧利斯"(0604)暴雨增幅过程高分辨率的数值模拟资料, 将降水分成对流降水和层云降水, 对比分析了不同类型降水云微物理特征和过程的差异, 探讨了不同类型降水对暴雨增幅的贡献, 结果指出:(1)暴雨增幅前, 降水基本为层云降水, 对流降水只存在于零星的几个小区域, 暴雨增幅发生时段, 对流降水所占比例较暴雨增幅前有显著增加, 平均降水强度达层云降水强度的3倍多。(2)暴雨增幅时段, 云系发展更加旺盛, 云中各种水凝物含量较增幅前明显增加, 其中, 对流和层云降水区云中水凝物含量均有一定程度增长, 但对流降水区增加更显著;而无论增幅前还是增幅时段, 对流降水区云中水凝物含量均要明显大于层云降水区, 并且两者的这种差异随着地面降水强度的增强而增大。(3)暴雨增幅前后, 对流降水区雨滴的两个主要来源最终均可以追踪到云水, 通过云水与大的液相粒子(雨滴)和大的固相粒子(雪)之间、以及大的固相粒子(雪和霰)之间的相互作用和转化, 造成雨滴增长, 并最终形成地面降水, 而层云降水区中与雨滴形成相关的上述主要云微物理过程明显变弱, 但层云降水区中暴雨增幅时段的上述过程又要强于增幅前, 说明层云降水对暴雨增幅也有一定贡献。     

区域气候模式中云量参数化方案的研究

首先统计并分析了模式区域内夏季平均的云量分布状况，然后在一有限区域模式中，引进了云－辐射计算模式。比较了３种不同的云量参数化方案，最后提出了一种考虑了大气相对湿度、垂直运动速度的本模式的云量参数化方案，并简要介绍了模式引入不同方案后的模拟结果。模拟结果表明，本模式的方案模拟的云量分布及气候要素场都与实况最接近，说明这一机制反映了云在气候系统中的反馈作用。不同的区域模式宜用不同的云量参数化方案。云量     

Contamination of marine biogenic habitats and effects upon associated epifauna

Habitat-forming organisms are frequently used as biomonitors in marine environments due to a widespread ability to accumulate toxic contaminants. Few studies, however, have considered the consequences of these accumulated contaminants on the abundant and diverse fauna associated with these habitats. In this review, we summarize research which has investigated the contamination of biogenic habitats (including seagrasses, macroalgae, ascidians, sponges and bivalve reefs) and the impact of this contamination on the habitat use, feeding behaviour and survival of associated epifauna. In many cases, ecological impacts upon epifauna are not simply predicted by levels of contamination in their habitat, but are determined by the foraging, feeding and reproductive behaviours of the inhabiting organisms. Thus, a thorough understanding of these ecological processes is essential in order to understand the effects of contaminants upon epifaunal communities. The scope of biomonitoring studies which assess the contamination of biogenic habitats should be expanded to include an assessment of potential effects upon associated epifauna. When combined with manipulative field experiments such an approach would greatly assist in our understanding of indirect effects of contaminants in these important benthic habitats.     

Parameterisation of surface radiation flux at an Antarctic site

During the Antarctic summer 1994/95 the values of downward and upward flux densities of both solar and terrestrial radiation were recorded at 1200 m for a period of 1 month on the Reeves Nevè Glacier (lat 74°39′S, long 161°35′E), near the Italian base of Terra Nova Bay. The relations proposed by Swinbank [Swinbank, W.C., 1963. Long-wave radiation from clear skies. Q. J. R. Meteorol. Soc. 89, 339–348], Idso and Jackson [Idso, S.B., Jackson, R.D., 1969. Thermal radiation from the atmosphere. J. Geophys. Res. 74, 5397–5403] and Deacon [Deacon, E.L., 1970. The derivation of Swinbank's long-wave radiation formula. Q. J. R. Meteorol. Soc. 96, 313–319] associating the long-wave atmospheric radiation flux only to the air temperature at screen level were tested in extreme Antarctic climatological condition. A relation between the long-wave radiation flux and both screen air temperature and cloud cover fraction in accordance to the height of the cloud base was defined using the Kasten and Czeplak relationship that relates the solar radiation flux and the cloud cover index. The study of the incoming short-wave radiation flux from the clear sky and that reflected by the surrounding snow cover allowed for highlighting the role of surface geometry on the albedo measurements.     

Cloud drop spectra at different levels and with respect to cloud thickness and rain

Measurements on drop size were made in cumulus clouds over Pune (inland region) during the summer monsoon seasons. In this paper, the measurements of the cloud drop spectra made in non-raining clouds at different levels and for different thickness have been studied. Also, those on the days with rain and with no rain (the rain being observed within the clouds) have been compared. The average spectra broadened with height. The concentration of drops >50 μm (N_L), liquid water content (LWC), mean volume diameter (MVD) and dispersion increased with height. The concentration of drops <20 μm (N_S) and total concentration (N_T) decreased with height. The spectra were broader, while N_S and N_T are smaller and the other parameters are greater for thicker clouds as compared to those for thinner. The spectra were broader, while N_S and N_T are smaller and the other parameters are greater on the days with rain with respect to those on the days with no rain. The distributions were bimodal at higher levels, for thicker clouds and on the days with rain, while they were unimodal at lower levels, for thinner clouds and on the days with no rain. The variations of the cloud drop spectra, preceding rain, at initial stage of rain and following rain are discussed.     

Rehabilitation of industrial areas: case histories from England and Germany

 Contaminated and possibly hazardous ground represents a problem in all of the industrialized countries of the world. The investigation of a site that is suspected of being contaminated differs somewhat from a routine site investigation. Sampling of soils, groundwater and gas-producing material may be required. Various precautions may be necessary in doing this and operatives may have to wear protective clothing. Four case histories have been chosen to illustrate different aspects of the rehabilitation of abandoned contaminated land, namely, investigation, assessment, ground treatment and redevelopment. The first comes from Leeds in West Yorkshire, England, and outlines how a site investigation was undertaken and the nature of the contamination present, together with a note on the suggested redevelopment. The remaining three case histories are taken from the heavily industrialized district of the Ruhr in Germany, where extensive mining of coal and associated industries were developed from the mid-19th century onwards. The first considers the site of the former Graf Moltke mine near Essen. In this instance, the somewhat novel methods of data assessment and ground treatment are dealt with. The Mont Cenis site at Herne-Sodingen is one of the more notable old mining/industrial sites undergoing redevelopment in the state of North Rhine Westphalia. Hence, the case history concentrates of this aspect of rehabilitation. This involves not only the construction of new and interesting structures but an attempt to reduce energy consumption in an attempt to effect the concept of sustainable development of an urban area. The last example deals with the abandoned site of the Minister Achenbach mine at Lünen, where the ground conditions were further complicated by the presence of old bomb craters that had been filled with a variety of materials. In addition, because of the suspected presence of former foundation structures in the ground an electromagnetic survey was carried out across part of the site, the areas of high conductivity suggesting their presence. Received: 15 September 1999 · Accepted: 14 March 2000     

震前云下增温异常及其时段特征

利用卫星热红外图像资料做地震短临预报, 主要依据的是地表大气增温异常在卫星图像上的亮温反映。 但在阴云密布的天气条件下, 这种预报方法却受到了限制, 因为卫星无法探测到地面或水面是否有增温异常。 通过气象资料分析, 得知云层或其他气象条件引起的降温并不能改变震前地表温度增加的趋势。 某些地震之前虽然震中及其附近地区天空阴云密布, 地面增温幅度却可高达十几度。 云下增温曲线可划分为3个时段(即A、 B、 C段), 其中A段与C段分别为增温前与震后的温度变化曲线, 多与日照时间呈正相关关系, 特别是A段的这种关系更具普遍性。 然而, 反映震前地面增温特征的B段却与日照时间没有明显的相关性, 可见这种持续增温、 与云量无关的波状增温等都主要不是由日照或气象条件引起的, 而是一种与地下应力作用、 气体释放、 瞬变电场等有关的震兆现象。 因此, 提高对云下增温的系统观测能力, 是改善热红外地震预报的有效途径。