Crystal Structure and Geometry-Optimization Study of N-(2-hydroxy-1-naphthaldene)-4-aminoantipyrme

N-(2-hydroxy-1-naphthaldene)-4-aminoantipyrine has been synthesized. The structure is determined by X-ray diffraction method and elemental analysis. The crystal system belongs to orthorhombic space group P(2)2(1)2(1). The geometry has been ob-tained from the density functional theory (DFT) method and the B3LYP method employing the 6-31G* basis sets. The calculated results propose that the latter is close to the experimental data. The structural parameters from the theory are close to those of the crystal and the calculated total energy of coordination is -31677.172 eV. The energy of HOMO and LUMO and the energy gap are 5.179 eV, -1.603 eV and 3.577 eV, respectively.     

基于模糊理论的时空数据模型及算法解决

针对当前时空数据模型中存在的主要问题,本文提出了一种基于模糊理论的时空数据模型.该模型从时空对象演化的角度出发,结合模糊隶属度的概念,力求精确表达对象演化的整个过程及对象之间的相互关系.在此基础上,进一步分析了该模型的数据结构以及算法解决,为时空数据模型的研究提供了新的思路.     

Study on the isotherms of the interaction between suspended particles and Cu (II) in the Huanghe River

The isotherms of the interaction between the suspended particles and Cu²⁺, and the effects of lysine and asparaginic acid on the isotherms in the Huanghe (Yellow) River were studied by applying the theory and method of interfacial stepwise ion/coordination particle exchange. We obtained a new stepped river isotherm, formed by two curves joined together with a “plateau” in the middle. The adsorption equilibrium constantsK ₁ andK ₂ were calculated by using the isothermal equation of surface stepwise ion exchange. Amino acid in small amount promotes exchange adsorption of the suspended particles with Cu²⁺. The degree of promotive action relates to the isoelectric point of amino acid. The promotive effect of lysine is bigger than that of asparaginic acid. Project 29361001 supported by NSFC.     

基于引文分析法的“点-轴系统”理论研究述评

论文采用引文分析法,对陆大道院士所著《关于“点-轴”空间结构系统的形成机理分析》一文的349篇引文进行分析,从引文数量、引文作者、发文期刊、研究案例地、学科领域、研究主题、引用动机7个方面,探究“点-轴系统”理论的研究现状。结果表明：自2002年以来,“点-轴系统”理论的引文数量整体呈上升趋势,研究主题聚焦于区域经济和旅游发展;研究案例地以省级和市级中观尺度为主,多为单一型研究区,主要集中在西北丝绸之路经济带、东北辽宁经济圈、西南藏滇川渝、东部长三角四大热点区域;引文质量普遍较高,并且具有多学科交叉应用的特点,但批判性思考和创造性提升相对较少。基于此,论文从拓展研究和实践应用2个角度对“点-轴系统”理论未来发展进行了展望,以期为相关研究提供参考。     

浅析如何在溶剂萃取机理研究中正确使用斜率法

斜率法是萃取机理研究最为常用的方法之一。尽管其理论基础和使用方法非常简单,但该方法却常常被误用,导致其非但不能有效的确定萃取机理,反而产生了误导性结论。本文以t-BAMBP萃取碱金属离子(K~+、Rb~+、Cs~+)体系为例讨论了常见的错误用法以及造成这类情况的根源问题,之后对其他萃取体系中类似错误用法进行了简要评述,表明斜率法的错误使用主要源于对萃取反应方程式的错误假定及对工作方程推导过程中引入的近似处理理解不当。最后总结了在萃取机理研究中正确使用斜率法的几点注意事项。     

新世纪版《国家普通地图集》的内容策划与结构设计

新世纪版《国家普通地图集》是国家科技基础性工作专项《国家大地图集》系列编研项目之一,它以相对平衡的程度详细表示了水系、地貌、居民地、交通、境界、土质植被等基础地理要素的空间分布。为了适应生态文明建设和新型城镇化发展的要求,增设了地表覆盖图组和城市图组,构建了普通地图集的新型结构模式,本文主要对地图集的编研理论与内容策划、选题原则与顾及因素、结构设计与图幅编排进行了探讨和研究。     

The Symbolic Wolf: A Construal Level Theory Analysis of the Perceptions of Wolves in the United States

Charismatic wildlife can be difficult to manage due to the controversies they generate among stakeholders, which may be rooted in their symbolic meaning. Using construal-level theory, we coded the images of gray wolves mentioned by respondents to a national survey (n?=?621) and an issue public survey (n?=?447) as symbolic (abstract) or corporeal (concrete). We analyzed the relationship between these representations of wolves and several perceptions that may perpetuate social conflict. Most people thought of wolves abstractly, and abstract thoughts were associated with positive feelings toward wolves and agreement with existence beliefs regarding wolves. Concrete representations were associated with identifying as a gun or property rights advocate, hunter, or farmer/rancher. Given these disparate views of wolves, engaging stakeholders through collaborative processes designed to foster a shared understanding of this species, while addressing the concerns of those groups, could be useful in reducing conflict concerning wolf management.     

藏、汉对比视角下的城市空间环境认知研究——以中国西藏日喀则市为例

以分布式认知理论为基础,采用质性研究法、数量分析法以及GIS空间分析技术,探讨日喀则市藏族、汉族居民对城市空间环境认知的异同性。研究表明,藏族对城市空间环境的认知得分高于汉族对城市空间环境的认知得分。藏族、汉族对城市空间环境的认知水平可分为高、中、低3类。认知空间呈现圈层结构与混合结构模式,可分为藏汉一致性、藏族独立以及汉族独立3种认知空间类型。影响居民对城市空间环境的认知因素有共性因素和差异性因素。景观走廊质量、宜居性、基础设施两项是藏族居民关注的主要影响因素,汉族居民更关注公共服务设施的服务能力以及对当地文化的融入感。     

A surface network based method for studying urban hierarchies by night time light remote sensing data

Urban hierarchies are closely related to economic growth, urban planning and sustainable urban development. Due to the limited availability of reliable statistical data at fine scales, most existing studies on urban hierarchy characterization failed to capture the detailed urban spatial structure information. Previous studies have demonstrated that night time light data are correlated with many urban socio-economic indicators and hence can be used to characterize urban hierarchies. This paper presents a novel method for studying urban hierarchies from night time light data. Night time light data were first conceptualized as continuous mathematical surfaces, termed night time light surfaces. From the morphology of these surfaces the corresponding surface networks were derived. Hereafter, a night time light intensity (NTLI) graph was defined to describe the morphology of the surface network. Then, structural similarity between the night time light surfaces of any two different cities was calculated via a threshold-based maximum common induced graph searching algorithm. Finally, urban hierarchies were defined on the basis of the structural similarities between different cities. Using the 2015 annual NPP-VIIRS night time light data, the urban hierarchies of 32 major cities in China were successfully examined. The results are highly consistent with the reference urban hierarchies.     

高分辨率遥感影像配准与变化检测一体化处理

为了克服高分辨率遥感影像配准与变化检测作为单独环节处理的局限,该文提出了一种基于变分理论的配准与变化检测一体化处理方法。该方法将配准误差作为一种光谱变化决策因子,变化信息以权值的方式迭代反馈给变分配准模型的解算过程。为了更准确地检测建筑物这个特定目标的真实变化,该文采用多尺度最大形态学轮廓建筑物检测指数的差异作为另外一个决策因子。最后将配准误差反映的变化和建筑物检测指数的差异这两个决策因子在D-S证据理论框架下建立概率模型进行融合处理,进而得到建筑物的变化检测结果。该文选取WorldView-2数据进行实验,实验结果表明,一体化处理思路可以有效地解决单独处理的局限,从根本上解决配准误差对变化检测结果的影响以及由于变化而使配准精度降低的问题,进而提高配准和变化检测的质量。