化学发光体系测定铋的研究及其应用

研究了痕量Bi催化鲁米诺-邻菲啰啉-H_2O_2-Triton x-305体系产生化学发光及非离子表面活性剂敏化化学发光最佳反应条件,拟定了新的化学发光测定Bi的方法。方法最低检出限达3.7×10~(-10)g/ml,测定响应浓度范围为5×10~(-9)～10~(-5)g/ml,回收率为98.7％～103％,相对标准偏差为2.8％～3.5％之间。     

Cretaceous–Tertiary geology of the Gangdese Arc in the Linzhou area, southern Tibet

Knowledge of the Cretaceous–Tertiary history of upper crustal shortening and magmatism in Tibet is fundamental to placing constraints on when and how the Tibetan plateau formed. In the Lhasa terrane of southern Tibet, the widely exposed angular unconformity beneath uppermost Cretaceous–lower Tertiary volcanic-bearing strata of the Linzizong Formation provides an excellent geologic and time marker to distinguish between deformation that occurred before vs. during the Indo-Asian collision. In the Linzhou area, located  30 km north of the city of Lhasa, a > 3-km-thick section of the Linzizong Formation lies unconformably on Cretaceous and older rocks that were shortened by both northward- and southward-verging structures during the Late Cretaceous. The Linzizong Formation dips northward in the footwall of a north-dipping thrust system that involves Triassic–Jurassic strata and a granite intrusion in the hanging wall. U–Pb zircon geochronologic studies show that the Linzizong Formation ranges in age from 69 Ma to at least 47 Ma and that the hanging wall granite intrusion crystallized at  52 Ma, coeval with dike emplacement into footwall Cretaceous strata. ⁴⁰Ar/³⁹Ar thermochronologic studies suggest slow cooling of the granite between 49 and 42 Ma, followed by an episode of accelerated cooling to upper crustal levels beginning at  42 Ma. The onset of rapid cooling was coeval with the cessation of voluminous arc magmatism in southern Tibet and is interpreted be a consequence of either (1) Tertiary thrusting in this region or (2) regional rock uplift and erosion following removal of overthickened Gangdese arc lower crust and upper mantle or break-off of the Neo-Tethyan oceanic slab.     

靖远地区大厚度黄土地基浸水湿陷过程及土中竖向应力特征试验研究

为了研究靖远大厚度黄土在浸水条件下的水分入渗规律和自重湿陷变形特征,在中兰铁路沿线的靖远北站黄土自重湿陷场地进行了不打注水孔的现场浸水试验,监测并分析了地表及地下湿陷变形、试坑周围裂缝、含水率和土中竖向应力变化情况,对水分扩散规律、自重湿陷特性和土中竖向应力变化规律进行了研究,并对地区修正系数β0值和浸润角进行了探讨。结果表明：体积含水率变化分为浸水稳定（2个）、快速增加（1个）和缓慢增加（1个）共4个阶段;浸水过程中,水分在21m处竖向入渗加快、径向扩散减缓,湿润峰最终形态呈现为椭圆状。根据探井和钻孔含水率测试结果,推算出浸润角最大为41°。该场地黄土自重湿陷过程历经剧烈湿陷、缓慢湿陷和固结稳定3个阶段。试验结束时共计发展了13圈环状裂缝,裂缝最远处距试坑边缘26m。根据室内试验和现场测试结果,建议地区修正系数沿土层深度进行修正,0～10m内β0值取1.05,10～27 m内β0值取0.95。在地表至21 m深度范围内,地基土浸水饱和且湿陷充分,土中竖向应力沿深度呈线性增加,土中竖向应力接近饱和自重应力,21m以下的地基土未能充分湿陷,土中竖向应力逐渐减小。该研究成果可应用于中兰铁路...     

E5000型全谱直读型电弧发射光谱仪研制及其在地球化学样品分析中应用

在地球化学样品检测工作中,Ag、B、Sn等难分析元素通常采用传统的交流电弧发射光谱法(摄谱仪),随着地球化学样品数量的增加以及对检测结果质量要求的提高,该方法操作复杂、分析过程繁琐的问题与日常大量样品分析的矛盾日益突出,多道式电弧直读发射光谱也开始在行业内应用。本文基于先进的数字光源技术和CCD全谱型光谱仪技术,改进了电弧发生系统、分光系统和检测系统,将电弧激发光源与Paschen-Runge型全谱CCD光谱仪结合,研制了一款新型的台式全谱直读型电弧发射光谱仪E5000。E5000型电弧发射光谱仪通过激光定位结合程控电极技术,自动调整电极位置,提高了采谱过程的精度控制;利用CCD全谱技术获得了激发样品的全谱信息,可轻易实现光谱信号的背景扣除和干扰校正;且无需再次测定黑度,直接获得分析结果;同时结合内标法和标准加入法,可以进一步提高复杂基体样品的分析精准度。应用研制的光谱仪对水系沉积物和土壤样品进行检测,Ag、B、Sn元素的检出限分别达到了0.01μg/g、0.65μg/g、0.16μg/g,在分析水系沉积物、土壤时检测精密度基本小于10%,优于当前的摄谱法和多道电弧直读光谱法,满足了地球化学样品检测质量要求。     

古亚洲构造域侵入岩时——空演化框架

长期以来,许多著名学者提出众多模型,讨论古亚洲构造域的构造演化和造山(带)结构样式。但是,认识上的分歧很大,特别是关于主洋盆的空间位置和闭合时间。本文主要基于中国侵入岩大地构造编图(1∶250万)和研究这个侧面,参与讨论。1侵入(岩)弧,碰撞和后造山岩石组合,随时间由西向东变新,同时,主构造带走向从近东西向转为近南北向,暗示古亚洲洋的闭合最终转化为太平洋构造域。2位于主洋盆北侧的是宽阔的西伯利亚克拉通南缘的沟——弧——盆系统;位于南侧的西面为南天山被动陆缘,中部为塔里木克拉通北缘的窄的沟——弧——盆系统,东面为华北克拉通北缘的活动陆缘。3主体侵入(岩)弧的内部分散地分布着从Pt3开始的残留弧和残留oφ,被看做是主体弧的基底。4传统上认为的构造相对稳定的"地块",本文基于它们的侵入(岩)组合归为残留弧,认为不是构造上相对稳定的性质,并未采用"地块"的术语,而把它们看作洋陆转换过程中早期残余岛弧处理。5提出主洋盆的识别有三个标志,(a)洋闭合最晚,(b)或为双向俯冲(当两侧均为活动大陆边缘时),或单向俯冲(当一侧为被动陆缘,另一侧为活动陆缘时),(c)长寿命的洋以及洋闭合带常常发育地中海式残余洋发育的陆——陆碰撞早阶段。6该构造域主要发育Pt3——T的侵入(岩)弧和oφ,支持S¨engor等关于大量新生陆壳的推测,亦与大量花岗岩类为εNd(t)"+"值符合。新生陆壳的形成又暗示,长时间的洋俯冲必导致地幔的冷却,以及大量榴辉岩进入地幔,最终导致高密度的地幔下降流形成,必导致洋的闭合与随后的陆——陆碰撞,形成最初的东亚大陆。     

The Reliability of Assigned Values from the GeoPT Proficiency Testing Programme from an Evaluation of Data for Six Test Materials that have been Characterised as Certified Reference Materials

Assigned values derived from the GeoPT proficiency testing programme were compared with certified values for six certified reference materials that have been used as test materials in the GeoPT programme. Statistical analysis showed that there were few significant differences between these sets of data and that these differences had no significant impact on the GeoPT assessment when fitness‐for‐purpose criteria were taken into account.     

发动机燃烧室内壁材料热环境的气动热试验模拟技术研究

利用超声速矩形湍流导管和等离子电弧加热器模拟了发动机燃烧室内流和高超声速飞行器外壁面外流热环境,进行了平板表面冷壁热流测量和燃烧室内壁材料考核试验。结果表明:由于辐射换热的影响,在选取的两个典型来流条件下,发动机燃烧室内流热环境下的冷壁热流比外流热环境下的高出21%和40%,但是冷壁热流的增量基本相当,约为0.70~0.80MW/m²。随着冷壁热流的增加,辐射换热产生的热流增量的影响力会逐渐减小。材料考核时,相同配方的C/SiC复合材料在内流热环境下的表面温度高出约400℃,背面温度高出约90℃,这种差异对于发动机燃烧室内壁面材料考核至关重要,必须在材料考核试验中加以考虑。      

Volcanic and Scientific Activity at Kick ’em Jenny Submarine Volcano 2001–2002: Implications for Volcanic Hazard in the Southern Grenadines,Lesser Antilles

Kick em Jenny submarine volcano, ~8 km north of Grenada, has erupted at least 12 times since it was first discovered in 1939, making it the most frequently active volcano in the Lesser Antilles arc. The volcano lies in shallow water close to significant population centres and directly beneath a major shipping route, and as a consequence an understanding of the eruptive behaviour and potential hazards at the volcano is critical. The most recent eruption at Kick em Jenny occurred on December 4 2001, and differed significantly from past eruptions in that it was preceded by an intensive volcanic earthquake swarm. In March 2002 a multi-beam bathymetric survey of the volcano and its surroundings was carried out by the NOAA ship Ronald H Brown. This survey provided detailed three-dimensional images of the volcano, revealing the detailed morphology of the summit area. The volcano is capped by a summit crater which is breached to the northeast and which varies in diameter from 300 to 370 m. The depth to the summit (highest point on the crater rim) is 185 m and the depth to the lowest point inside the crater is 264 m. No dome is present within the crater. The crater and summit region of Kick em Jenny are located at the top of an asymmetrical cone which is about 1300 m from top to bottom on its western side. It lies within what appear to be the remnants of a much larger arcuate collapse structure. An evaluation of the morphology, bathymetry and eruptive history of the volcano indicates that the threat of eruption-generated tsunamis is considerably lower than previously thought, mainly because the volcano is no longer thought to be growing towards the surface. Of more major and immediate concern are the direct hazards associated with the volcano, such as ballistic ejecta, water disturbances and lowered water density due to degassing.     

δ34S isotope values of dissolved sulfate (SO4 2−) as a tracer for battery acid (H2SO4) contamination in groundwater

The application of sulfur isotope (³⁴S) values of sulfate in groundwater provided the information necessary to evaluate the source, transport and fate of battery acid and associated contaminants at the Gulf Coast Recycling (GCR) facility. The chemical and isotopic composition of groundwater beneath the (GCR) property, a battery recycling facility in east Tampa, Florida, varies more than expected for an area of comparable size. Sulfate (SO₄^2–) values, for example, range from 1.2 to 11,500 mg/L and oxygen and hydrogen isotopes do not attenuate towards the weighted annual mean. Those samples that are high in sulfate generally have a low pH, which immediately indicates battery acid (H₂SO₄) contamination as a potential source for the sulfate. The low pH and high reactivity of the sulfuric acid groundwater cause the formation of hydrogeological microenvironments due to preferential dissolution of carbonate minerals, which in turn causes enhanced recharge and groundwater flow in certain areas; thus, the extreme scatter in the data set. Because of the difficult hydrogeology it is not straightforward to delineate the point-sources of contamination and up to five potential scenarios have to be evaluated: (1) seawater intrusion, (2) upwelling of high-sulfate groundwater, (3) local dissolution of gypsum, (4) an up-gradient contaminant source to the northeast of the GCR property and (5) battery acid contamination.     

An integrated linear/non-linear flow model for the conduit-fissure-pore media in the karst triple void aquifer system

Most karstic aquifer media may be characterized as the triple-void media with highly-varied hydraulic properties, including matrix pore, fissure and conduit, in which liner flow may co-exist with non-linear flow. In this paper, an attempt is made to couple linear flow with non-linear flow in a single unified flow governing equations by introducing the concept of equivalent hydraulic conductivity (EHC) and deriving a general Darcys law for various flow. The expression of EHC in the karst conduit and fissure are also derived. The procedures of numerical implementation are demonstrated via an ideal model and a case study of karst aquifer system in the Beishan Ore Formation area, Guangxi Autonomous Region, China.