全风化花岗岩化学及矿物成份在全土和粘粒中的不同表征

对全风化花岗岩化学和矿物成份的测试常用全土和粘粒部分(粒径2减少了近50%,K2O含量也降低,而Al2O3、Fe2O3和H2O+都明显升高。粘粒中氧化物相对含量升高者居多;全岩矿物成份以石英、粘土矿物和长石为主,粘粒中埃洛石和高岭石占大多数,其次为伊利石;粒度成份、化学成份和矿物含量相关性比较明显的是:石英和角砾正相关,和砂粒负相关,长石和砂粒正相关,粘土矿物含量和Al2O3、烧失量(LOI)和埃洛石含量正相关。     

吉黑东部花岗岩类的副矿物组合特征

吉黑东部花岗岩类分布广泛,形成历史漫长,岩石类型齐全.按成因类型划分,以I型为主,A型次之,S型较少,M型极少.各类型花岗岩副矿物组成具有明显特点,因此可以利用副矿物和其组合特征作为划分花岗岩成因类型的判别标志.     

四川盆地西部富钾卤水水文地球化学特征及其成因意义探讨

四川盆地西部宫钾卤水以深层卤水形式赋存于地下４０００余ｍ的中三叠统雷口坡组四段（Ｔ２ｌ４）盐系的碳酸盐岩储层中。富钾卤水与海水不同浓缩阶段相比，其中含Ｋ＋含量异常高，构成液态钾矿资源；Ｂｒ－、Ｉ－、Ｂ（３＋）、Ｌｉ＋等稀有组分也远超过综合利用工业品位，为优质化工原料水。富钾卤水为沉积变质和钾盐溶滤的复合成因，具有固夜态找钾的指示意义。本文为四川盆地固液态找钾提供了有价值的线索。     

Distribution of platinum-group elements in the Platreef at Overysel,northern Bushveld Complex: a combined PGM and LA-ICP-MS study

Detailed mineralogical and laser ablation-inductively coupled plasma-mass spectrometry studies have revealed the physical manifestation of the platinum-group elements (PGE) within the Platreef at Overysel, northern Bushveld Complex, South Africa. The PGE in the Platreef were originally concentrated in an immiscible sulfide liquid along with semi-metals such as Bi and Te. As the sulfide liquid began to crystallize, virtually all the Os, Ir, Ru and Rh partitioned into monosulfide solid solution (mss), which on further cooling, exsolved to form pyrrhotite and pentlandite with Os, Ir and Ru remaining in solid solution in both phases with Rh prefentially partitioning into pentlandite. Platinum, some Pd and Au were concentrated in the residual sulfide liquid after mss crystallization, and were then concentrated in an immiscible late stage melt along with semi metals, which was expelled to the grain boundaries during crystallization of intermediate solid solution (iss) to form Pt and Pd tellurides and electrum around the margins of the sulfide grains. Tiny droplets of this melt trapped in the crystallizing mss and iss cooled to form Pt–Bi–Te microinclusions in all sulfide phases, whilst the excess Pd was accommodated in solid solution in pentlandite. Minor redistribution and recrystallization by hydrothermal fluids occurred around xenoliths and at the very base of the mineralized zone within the footwall, however, the overall lack of secondary alteration coupled with the volatile-poor nature of the gneissic footwall have allowed the preservation of what may be the most ‘primary’ style of Platreef mineralization. The lack of PGM inclusions within early liquidus phases suggests very early sulfur saturation in the Platreef, lending support to theories involving S saturation occurring prior to intrusion of the Platreef, possibly within a staging chamber.     

华南下寒武统镍钼矿层中铜铅锌矿物的发现及意义

华南扬子地块是我国古热水沉积成矿作用最为发育的地区之一,其热水沉积特性最早引起我国学者的关注。华南下寒武统黑色岩系中赋存多个与热水沉积成矿作用相关的大型、超大型重晶石矿床与N i-Mo-U-V多金属富集层。进一步研究分布在华南扬子地块黑色岩系中的金属、非金属矿床成因及其地球化学特征,对认识华南乃至全球晚震旦—早寒武世生物与环境演化有着十分重要的意义。本文对华南下寒武统镍-钼富集层矿石进行电子探针研究,识别出黄铜矿、黝铜矿等铜的独立矿物;闪锌矿等锌的独立矿物;方铅矿、白铅矿等铅的独立矿物。研究表明,在镍-钼矿石中这些矿物的发现为镍-钼矿层是热水沉积作用产物提供了直接的矿物学证据。     

碎屑岩自生粘土矿物的沉淀作用及其对储层的影响——以川西坳陷上三叠统须家河组砂岩为例

粘土矿物是影响碎屑岩储层物性的重要因素.本文以川西坳陷孝泉-新场-合兴场地区上三叠统须家河组砂岩为例,应用铸体薄片、普通薄片、X射线衍射分析和扫描电镜分析,研究了在成岩过程中自生粘土矿物的沉淀作用及其对储层的影响.结果表明自生绿泥石对储层原生孔隙的保存和次生孔隙的发育有利,自生高岭石的含量反映了次生孔隙的发育程度,而伊利石对储层的影响是负面的.     

海南文昌地区第四系沉积物特征及其地质意义

海南省文昌市东部沿海一带是华南地区第四系发育较为典型的地区之一,其分布受新生代晚期形成的新构造格局的控制。通过对第四系沉积物特征、粒度分析、重矿物锆石采用激光剥蚀等离子体质谱(LA-ICP-MS)技术进行年龄测定,并选用206Pb/238U年龄做谐和年龄频谱图。认为该区第四系松散沉积具有不完全相同的物源。八所组与烟墩组的沉积物源区具有一定的相似性,北海组的沉积物源区明显不同于八所组和烟墩组。这种物源的差异性可能直接导致了第四系成矿作用的不同。     

横断山不同成因类型花岗岩类岩石中黑云母的标型特征

本文研究了横断山区不同成因类型花岗岩类岩石中黑云母的化学成分、微量元素、结构和物理性质等。结合花岗岩类岩石的成因类型,将黑云母分为三个亚种:富镁黑云母(MF=1.3—1.5)、镁黑云母(MF=1—1.3)和富铁黑云母(MF=0.5-1)。     

Micro-environmental controls on biomineralization: superficial processes of apatite and calcite precipitation in Quaternary soils, Roussillon, France

Calcium hydroxyapatite and calcite precipitates around bacteria were observed in 2-week-old alluvial topsoil (Roussillon area, SE France). This observation prompted a laboratory study of Ca²⁺ and PO₄³⁻ incorporation into hydroxyapatite and Ca²⁺ into calcite mediated by bacteria using similar topsoil material, but free from apatite and calcite. Subsamples were prepared using three different grain sizes, and experiments were undertaken using sucrose and different contents of Ca²⁺ and PO₄³⁻. Mineralization experiments proceeded over 5 days. Calcium and PO₄³⁻ sorption onto clay influenced the Ca/P ratio in the solutions. Hydroxyapatite and calcite precipitation only occurred in unsterilized samples. The presence of clay minerals promoted biomineralization.     

我国西北夏季风边界千年尺度变化的证据--来自盐池和猪野泽盐类矿物分析结果

我国夏季风西北缘是响应长尺度气候变化最为敏感的区域之一, 但夏季风边界变化与千年尺度气候变化之间的关系尚不明确, 相关研究仍缺乏足够证据。夏季风西北缘湖泊沉积物中盐类矿物种类与含量的时空变化, 有助于推测气候变化特征。盐池和猪野泽分别位于祁连山北麓的河西走廊中段和东段, 是研究长时间尺度亚洲夏季风影响区西北边界变化的关键区域。研究全新世千年尺度下, 夏季风西北边界的变化对夏季风西北缘气候变化过程的影响, 对明确季风边缘区千年尺度季风变化机制, 预测未来长尺度气候变化有重要意义。因此, 本文选择盐池古湖泊盐池剖面(YC), 猪野泽青土湖01、02剖面(QTH01、QTH02)等三个剖面, 开展全新世千年尺度下, 亚洲季风西北边界地区湖泊沉积物盐类矿物时空变化对比研究。结果显示:QTH01、QTH02剖面盐类矿物以碳酸盐为主, 硫酸盐类矿物仅零星出现, 而YC剖面硫酸盐类矿物含量相对较高, 同时出现了氯化物型矿物, 全新世气候特征整体较猪野泽更为干旱。末次冰期和早全新世, 三个剖面受季风输送水汽影响明显, 碳酸盐类矿物能较好沉积, 季风边界在这一时期向北扩张, 推进到祁连山中段地区;中全新世QTH01、QTH02剖面受夏季风影响减弱, 湖泊退缩, 碳酸盐类矿物含量达到峰值, YC剖面则表现出极端干旱的气候特征, 硫酸盐类矿物因“盐效应”含量下降, 此时夏季风西北部水汽输送边界位于石羊河流域和盐池流域之间;晚全新世盐池和猪野泽均以风成沉积为主, 气候干旱, 碳酸盐类矿物难以保存, 硫酸盐和氯化物矿物含量出现高值, 说明夏季风西北边界进一步向南迁移。综上所述, 盐类矿物含量变化能良好反应夏季风西北缘全新世气候变化特征, 同时证明, 在全新世千年尺度上, 夏季风西北边界在盐池流域和石羊河流域之间存在变化。